Artikel
Lizenziert
Nicht lizenziert
Erfordert eine Authentifizierung
A multivariate approach to the acetylated poplar wood samples by near infrared spectroscopy
-
İpek Çelen
Veröffentlicht/Copyright:
4. Februar 2008
Abstract
Yellow poplar (Liriodendron tulipifera L.) wood flour was chemically modified with acetic anhydride at varying times and initial moisture contents at a constant temperature. All samples exhibited increasing weight gains in the range of 5–16% with increasing reaction or treatment time. The acetylated poplar wood flour was characterized by means of Fourier transform infrared spectroscopy and near infrared (NIR) spectroscopy. Principal component analysis performed on the spectral data revealed clusters according to the esterification level. Partial least squares regression models developed from NIR data were able to predict the weight gain and the percentage of reacted OH groups. The correlations show that there is a direct and linear relationship between the spectra and the weight percentage gain and, therefore, the degree of acetylation.
Keywords: acetylation; multivariate analysis; near infrared spectroscopy (NIR); partial least squares (PLS) regression; principal component analysis (PCA); weight percentage gain (WPG)
Received: 2007-4-11
Accepted: 2007-11-22
Published Online: 2008-02-04
Published in Print: 2008-03-01
©2008 by Walter de Gruyter Berlin New York
Sie haben derzeit keinen Zugang zu diesem Inhalt.
Sie haben derzeit keinen Zugang zu diesem Inhalt.
Artikel in diesem Heft
- Meetings
- Cellulose aerogels: Highly porous, ultra-lightweight materials
- Esterification of carboxylic acids on cellulosic material: Solid state reactions
- Bagasse alkaline sulfite-anthraquinone (AS/AQ) pulping and totally chlorine free (TCF) bleaching
- Effect of abnormal fibres on the mechanical properties of paper made from Norway spruce, Picea abies (L.) Karst.
- Development of fully bio-based composite: Wood/cellulose diacetate/poly(lactic acid) composite
- Crystallinity and mesoporosity of carbon produced from ligno-p-cresol and their improvement by pulverization and acid treatment
- Revisiting the mechanism of β-O-4 bond cleavage during acidolysis of lignin. Part 1: Kinetics of the formation of enol ether from non-phenolic C6-C2 type model compounds
- Study of kinetics of reaction of lignin model compounds with propylene oxide
- Two-dimensional homo- and hetero-correlation technique applied to NIR and py-MBMS spectra of wood
- UV resonance Raman spectroscopic study of photodegradation of hardwood and softwood lignins by UV laser
- A multivariate approach to the acetylated poplar wood samples by near infrared spectroscopy
- Structure elucidation of phenylethanoid glycosides from Paulownia tomentosa Steud. var. tomentosa wood
- A generalized mat consolidation model for wood composites
- Prediction and optimization of surface roughness in milling of medium density fiberboard (MDF) based on Taguchi orthogonal array experiments
- An investigation on the permeability of different wood furnish materials
- Laccase-catalyzed functionalization with 4-hydroxy-3-methoxybenzylurea significantly improves internal bond of particle boards
- Effect of thermo-mechanical refining pressure on the properties of wood fibers as measured by nanoindentation and atomic force microscopy
- Adhesive bond strength of end grain joints in softwood with varying density
- An experimental study of the effects of moisture variations and gradients in the joint area in steel-timber dowel joints
- A new image analysis algorithm for calculating percentage wood failure
- Dr. Gordon Leary
Schlagwörter für diesen Artikel
acetylation;
multivariate analysis;
near infrared spectroscopy (NIR);
partial least squares (PLS) regression;
principal component analysis (PCA);
weight percentage gain (WPG)
Artikel in diesem Heft
- Meetings
- Cellulose aerogels: Highly porous, ultra-lightweight materials
- Esterification of carboxylic acids on cellulosic material: Solid state reactions
- Bagasse alkaline sulfite-anthraquinone (AS/AQ) pulping and totally chlorine free (TCF) bleaching
- Effect of abnormal fibres on the mechanical properties of paper made from Norway spruce, Picea abies (L.) Karst.
- Development of fully bio-based composite: Wood/cellulose diacetate/poly(lactic acid) composite
- Crystallinity and mesoporosity of carbon produced from ligno-p-cresol and their improvement by pulverization and acid treatment
- Revisiting the mechanism of β-O-4 bond cleavage during acidolysis of lignin. Part 1: Kinetics of the formation of enol ether from non-phenolic C6-C2 type model compounds
- Study of kinetics of reaction of lignin model compounds with propylene oxide
- Two-dimensional homo- and hetero-correlation technique applied to NIR and py-MBMS spectra of wood
- UV resonance Raman spectroscopic study of photodegradation of hardwood and softwood lignins by UV laser
- A multivariate approach to the acetylated poplar wood samples by near infrared spectroscopy
- Structure elucidation of phenylethanoid glycosides from Paulownia tomentosa Steud. var. tomentosa wood
- A generalized mat consolidation model for wood composites
- Prediction and optimization of surface roughness in milling of medium density fiberboard (MDF) based on Taguchi orthogonal array experiments
- An investigation on the permeability of different wood furnish materials
- Laccase-catalyzed functionalization with 4-hydroxy-3-methoxybenzylurea significantly improves internal bond of particle boards
- Effect of thermo-mechanical refining pressure on the properties of wood fibers as measured by nanoindentation and atomic force microscopy
- Adhesive bond strength of end grain joints in softwood with varying density
- An experimental study of the effects of moisture variations and gradients in the joint area in steel-timber dowel joints
- A new image analysis algorithm for calculating percentage wood failure
- Dr. Gordon Leary
