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Chapter 11 Binding kinetics and thermodynamics of carbon-based molecularly imprinted polymers

  • Jemmyson Romário de Jesus und Tatianny de Araujo Andrade
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Abstract

This chapter delves into the binding kinetics and thermodynamics of carbon-based molecularly imprinted polymers molecularly imprinted polymers (MIPs), exploring the critical role these studies play in understanding and optimizing MIPs. It begins by discussing the fundamental principles of molecular recognition and the dynamic interactions between MIPs and target molecules. The chapter highlights the importance of kinetic and thermodynamic analyses, which, when combined with mathematical modeling, provide a mechanistic understanding of binding processes. Important experimental techniques such as Fourier transform infrared spectroscopy Fourier transform infrared spectroscopy, surface plasmon resonance surface plasmon resonance, isothermal titration calorimetry isothermal titration calorimetry, atomic force microscopy atomic force microscopy, and nuclear magnetic resonance nuclear magnetic resonance are discussed in detail, showing their application in obtaining kinetic and thermodynamic profiles of MIPs. The integration of these experimental methods with computational simulations allows a comprehensive evaluation of carbon-based MIPs, providing important information on binding efficiency, selectivity, and the thermodynamic parameters governing analyte-polymer interactions. These parameters are crucial for optimizing the performance of MIPs in a variety of applications, including sensors, controlled release systems, and purification processes.

Abstract

This chapter delves into the binding kinetics and thermodynamics of carbon-based molecularly imprinted polymers molecularly imprinted polymers (MIPs), exploring the critical role these studies play in understanding and optimizing MIPs. It begins by discussing the fundamental principles of molecular recognition and the dynamic interactions between MIPs and target molecules. The chapter highlights the importance of kinetic and thermodynamic analyses, which, when combined with mathematical modeling, provide a mechanistic understanding of binding processes. Important experimental techniques such as Fourier transform infrared spectroscopy Fourier transform infrared spectroscopy, surface plasmon resonance surface plasmon resonance, isothermal titration calorimetry isothermal titration calorimetry, atomic force microscopy atomic force microscopy, and nuclear magnetic resonance nuclear magnetic resonance are discussed in detail, showing their application in obtaining kinetic and thermodynamic profiles of MIPs. The integration of these experimental methods with computational simulations allows a comprehensive evaluation of carbon-based MIPs, providing important information on binding efficiency, selectivity, and the thermodynamic parameters governing analyte-polymer interactions. These parameters are crucial for optimizing the performance of MIPs in a variety of applications, including sensors, controlled release systems, and purification processes.

Kapitel in diesem Buch

  1. Frontmatter I
  2. Preface V
  3. Acknowledgments
  4. Contents IX
  5. Contributing authors XIII
  6. Part 1: Fundamentals of molecular imprinting-based smart carbon nanomaterials
  7. Chapter 1 Introduction to molecular imprinting technology 1
  8. Chapter 2 Fundamentals and primer of molecular imprinting technology 27
  9. Chapter 3 Polymerization techniques of carbon-based molecularly imprinted polymers 41
  10. Chapter 4 Polymerization techniques of carbon-based molecularly imprinted polymers 53
  11. Part 2: Performance evaluation of molecular imprinting-based smart carbon nanomaterials
  12. Chapter 5 Characterization methods of carbon-based molecularly imprinted polymers 79
  13. Part 3: Applications of molecular imprinting-based smart carbon nanomaterials
  14. Chapter 6 Environmental applications of carbon-based molecularly imprinted polymers 111
  15. Chapter 7 Biomedical applications of carbon-based molecularly imprinted polymers 131
  16. Chapter 8 Analytical and industrial applications of carbon-based molecularly imprinted polymers 149
  17. Chapter 9 Sensing applications of carbon-based molecularly imprinted polymers in agriculture 189
  18. Chapter 10 Carbon-imprinted polymers for forensic applications: a game-changing tool in the crime scene 235
  19. Part 4: Case studies of molecular imprinting-based smart carbon nanomaterials
  20. Chapter 11 Binding kinetics and thermodynamics of carbon-based molecularly imprinted polymers 261
  21. Part 5: Various aspects and future prospects of molecular imprinting-based smart carbon nanomaterials
  22. Chapter 12 Green aspects of carbon-based molecularly imprinted polymers 285
  23. Chapter 13 Challenges and future prospects of carbon-based molecularly imprinted polymers 351
  24. About the editors
  25. Index 377
https://doi.org/10.1515/9783111503325-011

Kapitel in diesem Buch

  1. Frontmatter I
  2. Preface V
  3. Acknowledgments
  4. Contents IX
  5. Contributing authors XIII
  6. Part 1: Fundamentals of molecular imprinting-based smart carbon nanomaterials
  7. Chapter 1 Introduction to molecular imprinting technology 1
  8. Chapter 2 Fundamentals and primer of molecular imprinting technology 27
  9. Chapter 3 Polymerization techniques of carbon-based molecularly imprinted polymers 41
  10. Chapter 4 Polymerization techniques of carbon-based molecularly imprinted polymers 53
  11. Part 2: Performance evaluation of molecular imprinting-based smart carbon nanomaterials
  12. Chapter 5 Characterization methods of carbon-based molecularly imprinted polymers 79
  13. Part 3: Applications of molecular imprinting-based smart carbon nanomaterials
  14. Chapter 6 Environmental applications of carbon-based molecularly imprinted polymers 111
  15. Chapter 7 Biomedical applications of carbon-based molecularly imprinted polymers 131
  16. Chapter 8 Analytical and industrial applications of carbon-based molecularly imprinted polymers 149
  17. Chapter 9 Sensing applications of carbon-based molecularly imprinted polymers in agriculture 189
  18. Chapter 10 Carbon-imprinted polymers for forensic applications: a game-changing tool in the crime scene 235
  19. Part 4: Case studies of molecular imprinting-based smart carbon nanomaterials
  20. Chapter 11 Binding kinetics and thermodynamics of carbon-based molecularly imprinted polymers 261
  21. Part 5: Various aspects and future prospects of molecular imprinting-based smart carbon nanomaterials
  22. Chapter 12 Green aspects of carbon-based molecularly imprinted polymers 285
  23. Chapter 13 Challenges and future prospects of carbon-based molecularly imprinted polymers 351
  24. About the editors
  25. Index 377
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