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Chapter 5 Transition metal oxide semiconductor materials: properties and applications

  • Shrikant , Bhooraram and Sangita Gupta
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Microfabrication and Nanofabrication
This chapter is in the book Microfabrication and Nanofabrication

Abstract

Transition metal oxide (TMO) semiconductor nanomaterials have garnered significant attention in material science research in recent years due to their unique electronic, magnetic, and optical properties, and versatile applications. This chapter provides a comprehensive overview of these materials, focusing on tunable aspects, synthesis methods, crystal structures, electronic properties, and effectiveness of TMOs in various cutting-edge technologies, including electronics, optoelectronics, energy storage, and catalysis. Functionalization of TMOs through specific chemical synthesis techniques associated with control parameters such as annealing temperature, surfactants used, reducing agents, pre and post heat treatment, atmospheric conditions, and fine tuning of their properties by doping, morphological alterations, modifying the crystal structure for targeted applications have been elaborated in this chapter. TMOs, varied by their valence number/ oxidation states, find applications in energy storage, water treatment, pigmentations, medicine, engineering sectors, and other fields of modern technological world. Introduction to specific high-performing TMO materials such as TiO2, V2O5, Ag2O, Iron oxides, SiO2, and NiO, but not limited to these, have been elaborated in this book chapter. Further, as concluding remarks, outlook on TMOs for nextgeneration applications and possible suggestions have been summarized.

Abstract

Transition metal oxide (TMO) semiconductor nanomaterials have garnered significant attention in material science research in recent years due to their unique electronic, magnetic, and optical properties, and versatile applications. This chapter provides a comprehensive overview of these materials, focusing on tunable aspects, synthesis methods, crystal structures, electronic properties, and effectiveness of TMOs in various cutting-edge technologies, including electronics, optoelectronics, energy storage, and catalysis. Functionalization of TMOs through specific chemical synthesis techniques associated with control parameters such as annealing temperature, surfactants used, reducing agents, pre and post heat treatment, atmospheric conditions, and fine tuning of their properties by doping, morphological alterations, modifying the crystal structure for targeted applications have been elaborated in this chapter. TMOs, varied by their valence number/ oxidation states, find applications in energy storage, water treatment, pigmentations, medicine, engineering sectors, and other fields of modern technological world. Introduction to specific high-performing TMO materials such as TiO2, V2O5, Ag2O, Iron oxides, SiO2, and NiO, but not limited to these, have been elaborated in this book chapter. Further, as concluding remarks, outlook on TMOs for nextgeneration applications and possible suggestions have been summarized.

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