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12 General reaction types and reagents for the introduction of fluorine
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Axel Haupt
Abstract
In the following section, the most important reaction types for the preparation of fluoroorganic compounds are discussed. This also includes an introduction to common reagents as well as a general evaluation of their suitability in terms of accessibility, reactivity and selectivity.
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Abstract
In the following section, the most important reaction types for the preparation of fluoroorganic compounds are discussed. This also includes an introduction to common reagents as well as a general evaluation of their suitability in terms of accessibility, reactivity and selectivity.
Sie haben derzeit keinen Zugang zu diesem Inhalt.
Kapitel in diesem Buch
- Frontmatter I
- Preface V
- Foreword VII
- Contents IX
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Part A: Introduction to fluorine chemistry
- Introduction to fluorine chemistry 1
- 1 Sources of fluorine in nature 5
- 2 Elemental fluorine 9
- 3 Hydrogen fluoride 15
- 4 Preparation of fluorinated compounds [35] 23
- 5 Common solid-state structures of inorganic fluorides [35] 31
- 6 Properties of fluorinated compounds 35
- 7 Health and environmental aspects of fluorinated compounds 37
- 8 19F-NMR – an important analytical tool for fluorine chemists [53, 54] 43
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Part B: Inorganic fluorine chemistry
- Inorganic fluorine chemistry 53
- 9 Main group element fluorides 55
- 10 Transition metal fluorides and rare earth metal fluorides 161
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Part C: Organic fluorine chemistry
- Organic fluorine chemistry 281
- 11 Fluoroorganic compounds – unusual properties and versatile applications 283
- 12 General reaction types and reagents for the introduction of fluorine 301
- 13 Fluorination of aliphatic substrates 319
- 14 Fluorination of (hetero-) aromatic compounds 415
- 15 Preparation of fluorinated olefins and acetylenes 453
- 16 Solutions to study questions 479
- Bibliography 537
- Index 617
Kapitel in diesem Buch
- Frontmatter I
- Preface V
- Foreword VII
- Contents IX
-
Part A: Introduction to fluorine chemistry
- Introduction to fluorine chemistry 1
- 1 Sources of fluorine in nature 5
- 2 Elemental fluorine 9
- 3 Hydrogen fluoride 15
- 4 Preparation of fluorinated compounds [35] 23
- 5 Common solid-state structures of inorganic fluorides [35] 31
- 6 Properties of fluorinated compounds 35
- 7 Health and environmental aspects of fluorinated compounds 37
- 8 19F-NMR – an important analytical tool for fluorine chemists [53, 54] 43
-
Part B: Inorganic fluorine chemistry
- Inorganic fluorine chemistry 53
- 9 Main group element fluorides 55
- 10 Transition metal fluorides and rare earth metal fluorides 161
-
Part C: Organic fluorine chemistry
- Organic fluorine chemistry 281
- 11 Fluoroorganic compounds – unusual properties and versatile applications 283
- 12 General reaction types and reagents for the introduction of fluorine 301
- 13 Fluorination of aliphatic substrates 319
- 14 Fluorination of (hetero-) aromatic compounds 415
- 15 Preparation of fluorinated olefins and acetylenes 453
- 16 Solutions to study questions 479
- Bibliography 537
- Index 617
