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5 Common solid-state structures of inorganic fluorides [35]
Abstract
The large majority of element fluorides has been structurally characterized by X-ray crystallographic methods. As expected, the compounds can be assigned to the wellknown lattice-types of inorganic compounds, in some cases they are derived thereof by slight structural adaptations. The most important structure types are summarized in Table 5.1.
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Abstract
The large majority of element fluorides has been structurally characterized by X-ray crystallographic methods. As expected, the compounds can be assigned to the wellknown lattice-types of inorganic compounds, in some cases they are derived thereof by slight structural adaptations. The most important structure types are summarized in Table 5.1.
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Chapters in this book
- Frontmatter I
- Preface V
- Foreword VII
- Contents IX
-
Part A: Introduction to fluorine chemistry
- Introduction to fluorine chemistry 1
- 1 Sources of fluorine in nature 5
- 2 Elemental fluorine 9
- 3 Hydrogen fluoride 15
- 4 Preparation of fluorinated compounds [35] 23
- 5 Common solid-state structures of inorganic fluorides [35] 31
- 6 Properties of fluorinated compounds 35
- 7 Health and environmental aspects of fluorinated compounds 37
- 8 19F-NMR – an important analytical tool for fluorine chemists [53, 54] 43
-
Part B: Inorganic fluorine chemistry
- Inorganic fluorine chemistry 53
- 9 Main group element fluorides 55
- 10 Transition metal fluorides and rare earth metal fluorides 161
-
Part C: Organic fluorine chemistry
- Organic fluorine chemistry 281
- 11 Fluoroorganic compounds – unusual properties and versatile applications 283
- 12 General reaction types and reagents for the introduction of fluorine 301
- 13 Fluorination of aliphatic substrates 319
- 14 Fluorination of (hetero-) aromatic compounds 415
- 15 Preparation of fluorinated olefins and acetylenes 453
- 16 Solutions to study questions 479
- Bibliography 537
- Index 617
Chapters in this book
- Frontmatter I
- Preface V
- Foreword VII
- Contents IX
-
Part A: Introduction to fluorine chemistry
- Introduction to fluorine chemistry 1
- 1 Sources of fluorine in nature 5
- 2 Elemental fluorine 9
- 3 Hydrogen fluoride 15
- 4 Preparation of fluorinated compounds [35] 23
- 5 Common solid-state structures of inorganic fluorides [35] 31
- 6 Properties of fluorinated compounds 35
- 7 Health and environmental aspects of fluorinated compounds 37
- 8 19F-NMR – an important analytical tool for fluorine chemists [53, 54] 43
-
Part B: Inorganic fluorine chemistry
- Inorganic fluorine chemistry 53
- 9 Main group element fluorides 55
- 10 Transition metal fluorides and rare earth metal fluorides 161
-
Part C: Organic fluorine chemistry
- Organic fluorine chemistry 281
- 11 Fluoroorganic compounds – unusual properties and versatile applications 283
- 12 General reaction types and reagents for the introduction of fluorine 301
- 13 Fluorination of aliphatic substrates 319
- 14 Fluorination of (hetero-) aromatic compounds 415
- 15 Preparation of fluorinated olefins and acetylenes 453
- 16 Solutions to study questions 479
- Bibliography 537
- Index 617
