4 Preparation of fluorinated compounds [35]
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Axel Haupt
Abstract
In principle, the starting material for the preparation of fluorides is always HF. It is either used directly for fluorination reactions or it is needed for the preparation of F2 and other fluorinating agents. For many inorganic fluorides, some special procedures have been established for their preparation, nevertheless, a few general reaction types can be derived, which are summarized in Table 4.1.
Abstract
In principle, the starting material for the preparation of fluorides is always HF. It is either used directly for fluorination reactions or it is needed for the preparation of F2 and other fluorinating agents. For many inorganic fluorides, some special procedures have been established for their preparation, nevertheless, a few general reaction types can be derived, which are summarized in Table 4.1.
Chapters in this book
- Frontmatter I
- Preface V
- Foreword VII
- Contents IX
-
Part A: Introduction to fluorine chemistry
- Introduction to fluorine chemistry 1
- 1 Sources of fluorine in nature 5
- 2 Elemental fluorine 9
- 3 Hydrogen fluoride 15
- 4 Preparation of fluorinated compounds [35] 23
- 5 Common solid-state structures of inorganic fluorides [35] 31
- 6 Properties of fluorinated compounds 35
- 7 Health and environmental aspects of fluorinated compounds 37
- 8 19F-NMR – an important analytical tool for fluorine chemists [53, 54] 43
-
Part B: Inorganic fluorine chemistry
- Inorganic fluorine chemistry 53
- 9 Main group element fluorides 55
- 10 Transition metal fluorides and rare earth metal fluorides 161
-
Part C: Organic fluorine chemistry
- Organic fluorine chemistry 281
- 11 Fluoroorganic compounds – unusual properties and versatile applications 283
- 12 General reaction types and reagents for the introduction of fluorine 301
- 13 Fluorination of aliphatic substrates 319
- 14 Fluorination of (hetero-) aromatic compounds 415
- 15 Preparation of fluorinated olefins and acetylenes 453
- 16 Solutions to study questions 479
- Bibliography 537
- Index 617
Chapters in this book
- Frontmatter I
- Preface V
- Foreword VII
- Contents IX
-
Part A: Introduction to fluorine chemistry
- Introduction to fluorine chemistry 1
- 1 Sources of fluorine in nature 5
- 2 Elemental fluorine 9
- 3 Hydrogen fluoride 15
- 4 Preparation of fluorinated compounds [35] 23
- 5 Common solid-state structures of inorganic fluorides [35] 31
- 6 Properties of fluorinated compounds 35
- 7 Health and environmental aspects of fluorinated compounds 37
- 8 19F-NMR – an important analytical tool for fluorine chemists [53, 54] 43
-
Part B: Inorganic fluorine chemistry
- Inorganic fluorine chemistry 53
- 9 Main group element fluorides 55
- 10 Transition metal fluorides and rare earth metal fluorides 161
-
Part C: Organic fluorine chemistry
- Organic fluorine chemistry 281
- 11 Fluoroorganic compounds – unusual properties and versatile applications 283
- 12 General reaction types and reagents for the introduction of fluorine 301
- 13 Fluorination of aliphatic substrates 319
- 14 Fluorination of (hetero-) aromatic compounds 415
- 15 Preparation of fluorinated olefins and acetylenes 453
- 16 Solutions to study questions 479
- Bibliography 537
- Index 617
