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3. Technology of simple hydrocarbon intermediates

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Chemical Technologies and Processes
This chapter is in the book Chemical Technologies and Processes

Abstract

Plastics, thanks to their versatility, and high resource efficiency have become important materials in such branches as packaging, transportation, medicine, building and construction, etc. Although the role of recycling of various plastics in their manufacturing has been recently increasing (as a consequence of strong enhancement for circular economy, particularly in Europe), still production of monomers as substrates for plastics manufacturing is growing. It is predicted that, despite ongoing efforts to reduce, reuse, recycle and even ban plastic materials, improving living standards, population growth, and the lack of ready alternatives support the market for plastics for the next 20 years. The most important monomers produced on industrial scale belong to simple unsaturated hydrocarbons (alkanes/ olefins), called also hydrocarbon intermediates because they are substrates for further processes of organic synthesis or polymerization. A great variety of current technological approaches to olefins production was shown, i. e. steam cracking (SC), methanol-to-olefins (MTO), dehydrogenation (PDH, Catofin, Oleflex, STAR, FCDh), methathesis (OCT). The continuous improvement and development of onpurpose processes is a response to dynamic changes on feedstock market of petrochemical raw materials, consumer needs, and environmental regulations. It was emphasized that boom in dehydrogenation processes (particularly, PDH) results from shift to ethylene production in steam crackers, a gap between supply of propylene, butylenes and higher olefins compared to the continuously growing demand for their derivatives.

Abstract

Plastics, thanks to their versatility, and high resource efficiency have become important materials in such branches as packaging, transportation, medicine, building and construction, etc. Although the role of recycling of various plastics in their manufacturing has been recently increasing (as a consequence of strong enhancement for circular economy, particularly in Europe), still production of monomers as substrates for plastics manufacturing is growing. It is predicted that, despite ongoing efforts to reduce, reuse, recycle and even ban plastic materials, improving living standards, population growth, and the lack of ready alternatives support the market for plastics for the next 20 years. The most important monomers produced on industrial scale belong to simple unsaturated hydrocarbons (alkanes/ olefins), called also hydrocarbon intermediates because they are substrates for further processes of organic synthesis or polymerization. A great variety of current technological approaches to olefins production was shown, i. e. steam cracking (SC), methanol-to-olefins (MTO), dehydrogenation (PDH, Catofin, Oleflex, STAR, FCDh), methathesis (OCT). The continuous improvement and development of onpurpose processes is a response to dynamic changes on feedstock market of petrochemical raw materials, consumer needs, and environmental regulations. It was emphasized that boom in dehydrogenation processes (particularly, PDH) results from shift to ethylene production in steam crackers, a gap between supply of propylene, butylenes and higher olefins compared to the continuously growing demand for their derivatives.

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