Synthesis and Solution Properties of New Polysiloxane Bola Surfactants Containing Carbohydrate

Xiaojun Zeng; Hanghang Wang; Yanhong Chen; Liang Wang

doi:10.3139/113.110325

Article

Synthesis and Solution Properties of New Polysiloxane Bola Surfactants Containing Carbohydrate

Xiaojun Zeng , Hanghang Wang , Yanhong Chen and Liang Wang

Published/Copyright: September 25, 2014

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From the journal Tenside Surfactants Detergents Volume 51 Issue 5

Abstract

Three polysiloxane bola surfactants containing carbohydrate (ATPS-LA) were synthesized using a two-step method. Structure characterization was performed by infrared spectroscopy (FT-IR) and proton nuclear magnetic resonance spectroscopy (¹H NMR). Their surface activities and aggregation properties in aqueous solution were investigated by surface tension measurements and transmission electron microscopy (TEM). The results indicated that these three surfactants have much higher surface activity than those of conventional hydrocarbon bola surfactants, such as sodium eicosanedioate, in aqueous solution, and they can self-assemble into spherical micelles with average diameters in the range from 100 to 600 nm.

Kurzfassung

Drei Polysiloxan-Bolatenside, die Kohlenhydrate enthalten (ATPS-LA) wurden synthetisiert in einem Zweistufenverfahren. Für die Strukturcharakterisierung wurden die FT-IR-Spektroskopie und die ¹H-NMR herangezogen. Ihre Oberflächen- und Aggregationseigenschaften wurden mit Hilfe von Messungen der Oberflächenspannung und der Transmissionselektronenmikroskopie (TEM) untersucht. Die Ergebnisse machen deutlich, dass diese drei Tenside eine sehr viel höhere Oberflächenaktivität in wässriger Lösung aufweisen als die konventionellen Kohlenwasserstoff-Bolatenside wie z.B. Natriumeicosandioat. Des Weiteren sind sie imstande, sich in Kugelmizellen mit durchschnittlichen Durchmessern zwischen 100 nm bis 600 nm zu organisieren.

Key words: Carbohydrate; bola surfactant; poly siloxane; synthesis; aggregation properties; surface tension

Stichwörter: Kohlenhydrat; Bolatensid; Polysiloxan; Synthese; Aggregationseigenschaften; Oberflächenspannung

* Correspondence address Prof. Xiaojun Zeng, School of Chemistry and Materials Engineering, Changshu Institute of Technology, No. 99, South Third Ring Road, Changshu, Jiangsu Province, 215500, P. R. China. Tel.: +86-0512-52705155, Fax: +86-0512-52705155, E-Mail: zengxiaojun@cslg.edu.cn, wl7618@126.com

Xiaojun Zeng is an associate professor at Changshu Institute of Technology. His research involves the development and industrialization of the fine chemicals.

Hanghang Wang is an undergraduate student at Changshu Institute of Technology. His research involves synthesis and application of polymeric surfactants.

Yanhong Chen is an undergraduate student at Changshu Institute of Technology. His research involves synthesis and application of polymeric surfactants.

Liang Wang completed his M.Sc. in applied chemistry from China Research Institure of Daily Chemical Industry. His research interests are the synthesis and properites of novel surfactants.

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Received: 2014-03-02

Revised: 2014-07-11

Published Online: 2014-09-25

Published in Print: 2014-09-15

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https://doi.org/10.3139/113.110325

Keywords for this article

Carbohydrate; bola surfactant; poly siloxane; synthesis; aggregation properties; surface tension