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Wettability of polypropylene capillary membranes during the membrane distillation process

  • Marek Gryta EMAIL logo
Published/Copyright: November 23, 2011
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Abstract

Studies of membrane wettability in the membrane distillation process were performed with the application of hydrophobic capillary membranes made of polypropylene. Three kinds of Accurel PP membranes (Membrana GmbH, Germany) differing in the diameter of capillaries and pores as well as in the wall thickness were used. It was confirmed that membranes with lower wall thickness and larger pore size provide higher yields of the process. The studies demonstrated that the pores of used membranes located close to the external surface of capillaries are several times larger than those located inside the membrane wall. Based on air permeability measurements it was found that external surface of the membranes with such large pores was completely wetted by water after 50–80 h of membrane distillation. However, the pores located inside the wall with the diameter below 1 μm were not wetted and electrical conductivity of the obtained distillate was maintained at the level of 3–6 μS cm−1.

[1] Al-Obaidani, S., Curcio, E., Macedonio, F., Di Profio, G., Al-Hinai, H.,& Drioli, E. (2008). Potential of membrane distillation in seawater desalination: Thermal efficiency, sensitivity study and cost estimation. Journal of Membrane Science, 323, 85–98. DOI: 10.1016/j.memsci.2008.06.006. http://dx.doi.org/10.1016/j.memsci.2008.06.00610.1016/j.memsci.2008.06.006Search in Google Scholar

[2] Bonyadi, S., & Chung, T.-S. (2009). Highly porous and macrovoid-free PVDF hollow fiber membranes for membrane distillation by a solvent-dope solution co-extrusion approach. Journal of Membrane Science, 331, 66–74. DOI: 10.1016/j.memsci.2009.01.014. http://dx.doi.org/10.1016/j.memsci.2009.01.01410.1016/j.memsci.2009.01.014Search in Google Scholar

[3] El-Bourawi, M. S., Ding, Z., Ma, R., & Khayet, M. (2006). A framework for better understanding membrane distillation separation process. Journal of Membrane Science, 285, 4–29. DOI: 10.1016/j.memsci.2006.08.002. http://dx.doi.org/10.1016/j.memsci.2006.08.00210.1016/j.memsci.2006.08.002Search in Google Scholar

[4] Gryta, M. (2008). Fouling in direct contact membrane distillation process. Journal of Membrane Science, 325, 383–394. DOI: 10.1016/j.memsci.2008.08.001. http://dx.doi.org/10.1016/j.memsci.2008.08.00110.1016/j.memsci.2008.08.001Search in Google Scholar

[5] Gryta, M. (2007). Influence of polypropylene membrane surface porosity on the performance of membrane distillation process. Journal of Membrane Science, 287, 67–78. DOI: 10.1016/j.memsci.2006.10.011. http://dx.doi.org/10.1016/j.memsci.2006.10.01110.1016/j.memsci.2006.10.011Search in Google Scholar

[6] Gryta, M. (2006). Water purification by membrane distillation process. Separation Science and Technology, 41, 1789–1798. DOI: 10.1080/01496390600674950. http://dx.doi.org/10.1080/0149639060067495010.1080/01496390600674950Search in Google Scholar

[7] Gryta, M., Grzechulska-Damszel, J., Markowska, A., & Karakulski, K. (2009). The influence of polypropylene degradation on the membrane wettability during membrane distillation. Journal of Membrane Science, 326, 493–502. DOI: 10.1016/j.memsci.2008.10.022. http://dx.doi.org/10.1016/j.memsci.2008.10.02210.1016/j.memsci.2008.10.022Search in Google Scholar

[8] Karakulski, K., & Gryta, M. (2005). Water demineralization by NF/MD integrated processes. Desalination, 177, 109–119. DOI: 10.1016/j.desal.2004.11.018. http://dx.doi.org/10.1016/j.desal.2004.11.01810.1016/j.desal.2004.11.018Search in Google Scholar

[9] Karakulski, K., Gryta, M., & Sasim, M. (2006). Production of process water using integrated membrane processes. Chemical Papers, 60, 416–421. DOI: 10.2478/s11696-006-0076-y. http://dx.doi.org/10.2478/s11696-006-0076-y10.2478/s11696-006-0076-ySearch in Google Scholar

[10] Li, B., & Sirkar, K. K. (2004). Novel membrane and device for direct contact membrane distillation-based desalination process. Industrial & Engineering Chemistry Research, 43, 5300–5309. DOI: 10.1021/ie030871s. http://dx.doi.org/10.1021/ie030871s10.1021/ie030871sSearch in Google Scholar

[11] Scheirs, J. (2000). Compositional and failure analysis of polymers: A practical approach. Chichester, UK: Wiley. Search in Google Scholar

[12] Wang, J., Fan, B., Luan, Z., Qu, D., Peng, X., & Hou, D. (2008). Integration of direct contact membrane distillation and recirculating cooling water system for pure water production. Journal of Cleaner Production, 16, 1847–1855. DOI: 10.1016/j.jclepro.2007.12.004. http://dx.doi.org/10.1016/j.jclepro.2007.12.00410.1016/j.jclepro.2007.12.004Search in Google Scholar

[13] Zhang, J., Dow, N., Duke, M., Ostarcevic, E., Li, J.-D., & Gray, S. (2010). Identification of material and physical features of membrane distillation membranes for high performance desalination. Journal of Membrane Science, 349, 295–303. DOI: 10.1016/j.memsci.2009.11.056. http://dx.doi.org/10.1016/j.memsci.2009.11.05610.1016/j.memsci.2009.11.056Search in Google Scholar

[14] Zhang, M., Nguyen, Q. T., & Ping, Z. (2009). Hydrophilic modification of poly(vinylidene fluoride) microporous membrane. Journal of Membrane Science, 327, 78–86. DOI: 10.1016/j.memsci.2008.11.020. http://dx.doi.org/10.1016/j.memsci.2008.11.02010.1016/j.memsci.2008.11.020Search in Google Scholar

Published Online: 2011-11-23
Published in Print: 2012-2-1

© 2011 Institute of Chemistry, Slovak Academy of Sciences

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