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Influence of thermal treatment on the properties and intermolecular interactions of epoxidized natural rubber-salt systems

  • Nurul Fatahah Asyqin Zainal , Hairunnisa Ramli , Margarethe Fritz , Volker Abetz ORCID logo and Chin Han Chan ORCID logo EMAIL logo
Published/Copyright: August 24, 2021
Pure and Applied Chemistry
From the journal Pure and Applied Chemistry Volume 93 Issue 10

Abstract

The influence of thermal treatment on the thermal stability, thermal properties, dielectric properties and intermolecular interaction of binary epoxidized natural rubber (ENR)-salt systems, which may be a candidate for solid polymer electrolytes (SPEs) was investigated. Solubility of salt in ENR enhances, which may be due to the disruption of the lightly-crosslinked microgel under heat treatment. The increase in the ionic conductivities of the thermally treated ENR SPEs at constant salt content is correlated to the higher glass transition temperatures, development of percolation network and higher extent of intermolecular interactions between ENR and charged entities in this study.

Keywords: Centenary of macromolecules; dielectric properties; epoxidized natural rubber; glass transition temperature; intermolecular interaction; IUPAC Polymer Division; macrogel; microgel; thermal treatment
Corresponding author: Chin Han Chan, Faculty of Applied Sciences, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia, e-mail:

Article note: A collection of invited papers from members of the IUPAC Polymer Division Celebrating a Centenary of Macromolecules.

Funding source: Ministry of Education Malaysia

Award Identifier / Grant number: 600-RMI/RAGS 5/3 (145/2014)

Acknowledgements

The authors would like to thank Ms. Nurul Syahidah Hussin for the FTIR, TGA, DSC and IS experimental data.

  1. Research funding: The paper was supported by the Ministry of Education Malaysia under the project of Research Acculturation Grant Scheme (RAGS) (600-RMI/RAGS 5/3 (145/2014)) grant.

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Published Online: 2021-08-24
Published in Print: 2021-10-26

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Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Preface
  4. Celebrating a centenary of macromolecules
  5. Invited papers
  6. Hermann Staudinger – Organic chemist and pioneer of macromolecules
  7. On cellulose spatial organization and interactions as unraveled by diffraction and spectroscopic methods throughout the 20th century
  8. Dielectric properties of processed cheese
  9. Drawing inspiration from nature to develop anti-fouling coatings: the development of biomimetic polymer surfaces and their effect on bacterial fouling
  10. Mitigating the charge trapping effects of D-sorbitol/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) polymer blend contacts to crystalline silicon
  11. Influence of thermal treatment on the properties and intermolecular interactions of epoxidized natural rubber-salt systems
  12. Leveraging diversity and inclusion in the polymer sciences: the key to meeting the rapidly changing needs of our world
  13. Preface
  14. The virtual conference on chemistry and its applications, VCCA-2020, 1–31 August 2020
  15. Conference papers
  16. Effect of non-competitive inhibitors of aminopeptidase N on viability of human and murine tumor cells
  17. Evaluation of the catalytic activity of graphene oxide and zinc oxide nanoparticles on the electrochemical sensing of T1R2-Rebaudioside A complex supported by in silico methods
  18. Maximizing student learning through the use of demonstrations
  19. Molecular spaces and the dimension paradox
  20. Reaction of •OH with CHCl=CH-CHF2 and its atmospheric implication for future environmental-friendly refrigerant
  21. In silico study of the synergistic anti-tumor effect of hybrid topoisomerase-HDAC inhibitors
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https://doi.org/10.1515/pac-2020-0904
Keywords for this article
Centenary of macromolecules; dielectric properties; epoxidized natural rubber; glass transition temperature; intermolecular interaction; IUPAC Polymer Division; macrogel; microgel; thermal treatment

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Preface
  4. Celebrating a centenary of macromolecules
  5. Invited papers
  6. Hermann Staudinger – Organic chemist and pioneer of macromolecules
  7. On cellulose spatial organization and interactions as unraveled by diffraction and spectroscopic methods throughout the 20th century
  8. Dielectric properties of processed cheese
  9. Drawing inspiration from nature to develop anti-fouling coatings: the development of biomimetic polymer surfaces and their effect on bacterial fouling
  10. Mitigating the charge trapping effects of D-sorbitol/poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) polymer blend contacts to crystalline silicon
  11. Influence of thermal treatment on the properties and intermolecular interactions of epoxidized natural rubber-salt systems
  12. Leveraging diversity and inclusion in the polymer sciences: the key to meeting the rapidly changing needs of our world
  13. Preface
  14. The virtual conference on chemistry and its applications, VCCA-2020, 1–31 August 2020
  15. Conference papers
  16. Effect of non-competitive inhibitors of aminopeptidase N on viability of human and murine tumor cells
  17. Evaluation of the catalytic activity of graphene oxide and zinc oxide nanoparticles on the electrochemical sensing of T1R2-Rebaudioside A complex supported by in silico methods
  18. Maximizing student learning through the use of demonstrations
  19. Molecular spaces and the dimension paradox
  20. Reaction of •OH with CHCl=CH-CHF2 and its atmospheric implication for future environmental-friendly refrigerant
  21. In silico study of the synergistic anti-tumor effect of hybrid topoisomerase-HDAC inhibitors
  22. Structural and electronic properties of Cu4O3 (paramelaconite): the role of native impurities
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