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Intensification of thorium biosorption onto protonated orange peel using the response surface methodology

  • Ali A. Ghorbanpour Khamseh EMAIL logo , Younes Amini ORCID logo EMAIL logo , Mohammad Mahdi Shademan and Valiyollah Ghazanfari
Published/Copyright: March 3, 2023
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Chemical Product and Process Modeling
From the journal Chemical Product and Process Modeling Volume 18 Issue 4

Abstract

In this research work, intensifying the possibility of protonated orange peel to uptake thorium (IV) ions from aqueous solutions in a batch system was investigated and optimized using the response surface methodology. The effect of three independent process variables including thorium initial concentration, pH, and biosorbent dosage was assessed based on the central composite design. The validity of the quadratic model was verified by the coefficient of determination. The optimization results showed that the rate of thorium (IV) uptake under optimal conditions is 183.95 mg/g. The modeling results showed that the experimental data of thorium biosorption kinetics are fitted well by the pseudo-second-order model. According to the results, the biosorption process reached equilibrium after around 4 h of contact. The Langmuir isotherm describes the experimental biosorption equilibrium data well. The maximum absorption capacity of protonated orange peel for thorium adsorption was estimated by the Langmuir isotherm at 236.97 mg/g. Thermodynamic studies show that thorium adsorption on protonated orange peel is thermodynamically feasible, spontaneous, and endothermic.

Keywords: biosorption; isotherm; kinetics; protonated orange peel; response surface method; thorium
Corresponding authors: Ali A. Ghorbanpour Khamseh and Younes Amini, Nuclear Fuel Cycle Research School, Nuclear Science and Technology Research Institute, Tehran, Iran, E-mail: (A.A. Ghorbanpour Khamseh),

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2022-12-20
Accepted: 2023-02-20
Published Online: 2023-03-03

© 2023 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Research Articles
  3. MSP designing with optimal fractional PI–PD controller for IPTD processes
  4. A novel nonlinear sliding mode observer to estimate biomass for lactic acid production
  5. pH prediction for a semi-batch cream cheese fermentation using a grey-box model
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  10. Intensification of thorium biosorption onto protonated orange peel using the response surface methodology
  11. Investigating the energy, environmental, and economic challenges and opportunities associated with steam sterilisation autoclaves
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https://doi.org/10.1515/cppm-2022-0085
Keywords for this article
biosorption; isotherm; kinetics; protonated orange peel; response surface method; thorium

Articles in the same Issue

  1. Frontmatter
  2. Research Articles
  3. MSP designing with optimal fractional PI–PD controller for IPTD processes
  4. A novel nonlinear sliding mode observer to estimate biomass for lactic acid production
  5. pH prediction for a semi-batch cream cheese fermentation using a grey-box model
  6. Modeling of carbon dioxide and hydrogen sulfide pollutants absorption in wetted-wire columns with alkanolamines
  7. Pharmaceutical wastewater treatment using TiO2 nanosheets deposited by cobalt co-catalyst as hybrid photocatalysts: combined experimental study and artificial intelligence modeling
  8. Numerical simulation of fluid flow mixing in flow-focusing microfluidic devices
  9. A nonlinear autoregressive exogenous neural network (NARX-NN) model for the prediction of solvent-based oil extraction from Hura crepitans seeds
  10. Intensification of thorium biosorption onto protonated orange peel using the response surface methodology
  11. Investigating the energy, environmental, and economic challenges and opportunities associated with steam sterilisation autoclaves
  12. Short Communication
  13. Molecular dynamics simulations of water-ethanol droplet on silicon surface
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