Startseite Synergistic Interactions in Mixed W/O Microemulsions of Cationic Gemini and Anionic Surfactants
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Synergistic Interactions in Mixed W/O Microemulsions of Cationic Gemini and Anionic Surfactants

  • Jinling Chai , Ningning Liu , Ning Liu , Hengming Zhang , Haihui Chai und Zhongchun Liu
Veröffentlicht/Copyright: 17. November 2014
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Tenside Surfactants Detergents
Aus der Zeitschrift Tenside Surfactants Detergents Band 51 Heft 6

Abstract

The synergic effect between cationic Gemini imidazolium surfactant [C12(Bim)2-2Br] and anionic surfactant sodium dodecyl sulfate (SDS) on the physicochemical properties of the W/O microemulsions was studied. The properties include the molar fraction of the alcohol at the interfacial layer (Xai), the molar fraction of the alcohol in the oil phase (Xao), and the Gibbs free energy change (−Δ Go → io) of transferring alcohol from the continuous oil phase to the interfacial layer. The W/O microemulsion systems contain C12(Bim)2-2Br-SDS/butan-1-ol/octane/5 % NaCl solution. The values of Xai and Xao obtained from the W/O microemulsions containing the mixed surfactants are smaller than that of the microemulsion systems containing the single surfactant C12(Bim)2-2Br or SDS, while the values of −Δ Go → io are larger. This showed the existence of synergism between [C12(Bim)2-2Br] and SDS. The effects of alcohols, alkanes and NaCl concentrations on the values of Xai, Xao and −Δ Go → io, in the W/O microemulsions stabilized by C12(Bim)2-2Br and SDS were also investigated and discussed.

Kurzfassung

Es wurde die synergistische Wirkung zwischen dem kationischen Gemini-Imidazolium-Tensid [C12(Bim)2-2Br] und dem anionischen Tensid Natriumdodecylsulfat (SDS) auf die physikochemischen Eigenschaften von W/O-Mikroemulsionen untersucht. Bei diesen Eigenschaften handelt es sich um den Molenbruch des Alkohols in der Grenzfläche (Xai), den Molenbruch des Alkohols in der Ölphase (Xao) und um die Änderung der Gibbs-Energie (−Δ Go → io) für die Überführung des Alkohols aus der kontinuierlichen Ölphase in die Grenzfläche. Die W/O-Mikroemulsionen bestehen aus C12(Bim)2-2Br–SDS/Butan-1-ol/Octan/5 %ige wässrige NaCl- Lösung. Die Xai - und Xao -Werte der Mikroemulsionen, die eine Mischung aus den beiden Tensiden enthalten, sind kleiner als die der Mikroemulsionen mit nur einem der beiden Tenside. Die −Δ Go → io -Werte sind dagegen größer. Dies zeigt, dass zwischen [C12(Bim)2-2Br] und SDS ein Synergismus vorliegt. Der Einfluss von Alkoholen, Alkanen und NaCl auf die Xai - Xao - und −Δ Go → io -Werte in W/O-Mikroemulsionen, die mit C12(Bim)2-2Br und SDS stabilisiert sind, wurde ebenfalls untersucht und diskutiert.

Key words: Synergistic interaction; microemulsion; gemini surfactants; sodium dodecyl sulfate (SDS)
Stichwörter: Synergistische Wechselwirkung; Mikroemulsion; Gemini-Tenside; Natriudodecylsulfat (SDS)
* Correspondence address, Mr. Prof. Jinling Chai, College of Chemistry, Chemical and Engineering and Material Science, Shandong Normal University, Jinan 250014, P. R. China. E-Mail:

Jin-Ling Chai, born in 1961, Shandong Province of China, is a chemistry professor. Shandong Normal University at Msc degree in 1988. In 1988–1999, he worked in department of chemistry, teaching physical chemistry. He obtained a PhD degree in 2003. Special fields of interest are Physicochemical properties and applications of surfactant aggregates.

Ningning Liu, born in 1989, Shandong Province of China, an Msc candidate of Shandong Normal University. Her interest of research is physical chemistry of surfactant solutions.

Ning Liu, born in 1988, Shandong Province of China, an Msc candidate of Shandong Normal University. Her interest of research is physical chemistry of surfactant solutions.

Heng-Ming Zhang, born in 1988, Shandong Province of China, an Msc candidate of Shandong Normal University. His interest of research is physical chemistry of surfactant solutions.

Hai-Hui Chai, born in 1988, Shandong Province of China, an Msc candidate of Shandong Normal University. Her interest of research is physical chemistry of surfactant solutions.

Zhong-Chun Liu, born in 1988, Shandong Province of China, an Msc candidate of Shandong Normal University. Her interest of research is physical chemistry of surfactant solutions.

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Published Online: 2014-11-17
Published in Print: 2014-11-17

© 2014, Carl Hanser Publisher, Munich

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Application
  4. Rapid Assessment of Glass Etching/Corrosion using the Quartz Crystal Microbalance with Dissipation Monitoring, QCM-D
  5. Micelle Based Spectrofluorimetric Determination of Chloroquine Phosphate in Commercial Formulation and Human Plasma
  6. Novel Surfactants
  7. Synthesis of Rice Bran Fatty Acids (RBFAs) Based Cationic Surfactants and Evaluation of Their Performance Properties in Combination with Nonionic Surfactant
  8. Synthesis and Properties of Guerbet Hexadecyl Sulfate
  9. Synthesis and Characterization of N-alkyl-N′-glucosylhexanediamine Surfactant
  10. Mizellar Catalysis
  11. Methanesulfonic Acid as a More Efficient Catalyst for the Synthesis of Lauraldehyde Glycerol Acetal
  12. Surfactant Assisted Enhancement of Bioremediation Rate for Hexavalent Chromium by Water Extract of Siris (Albizia lebbeck) Sawdust
  13. Physical Chemistry
  14. Synergistic Interactions in Mixed W/O Microemulsions of Cationic Gemini and Anionic Surfactants
  15. Percolative Behavior Models Based on Artificial Neural Networks for Electrical Percolation of AOT Microemulsions in the Presence of Crown Ethers as Additives
  16. Junction Characteristics System Based on Composite Organic Semiconductors: Polystyrene/Polyaniline Doped by [BMIM] [BF4] Ionic Liquid
https://doi.org/10.3139/113.110339
Schlagwörter für diesen Artikel
Synergistic interaction; microemulsion; gemini surfactants; sodium dodecyl sulfate (SDS)

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Application
  4. Rapid Assessment of Glass Etching/Corrosion using the Quartz Crystal Microbalance with Dissipation Monitoring, QCM-D
  5. Micelle Based Spectrofluorimetric Determination of Chloroquine Phosphate in Commercial Formulation and Human Plasma
  6. Novel Surfactants
  7. Synthesis of Rice Bran Fatty Acids (RBFAs) Based Cationic Surfactants and Evaluation of Their Performance Properties in Combination with Nonionic Surfactant
  8. Synthesis and Properties of Guerbet Hexadecyl Sulfate
  9. Synthesis and Characterization of N-alkyl-N′-glucosylhexanediamine Surfactant
  10. Mizellar Catalysis
  11. Methanesulfonic Acid as a More Efficient Catalyst for the Synthesis of Lauraldehyde Glycerol Acetal
  12. Surfactant Assisted Enhancement of Bioremediation Rate for Hexavalent Chromium by Water Extract of Siris (Albizia lebbeck) Sawdust
  13. Physical Chemistry
  14. Synergistic Interactions in Mixed W/O Microemulsions of Cationic Gemini and Anionic Surfactants
  15. Percolative Behavior Models Based on Artificial Neural Networks for Electrical Percolation of AOT Microemulsions in the Presence of Crown Ethers as Additives
  16. Junction Characteristics System Based on Composite Organic Semiconductors: Polystyrene/Polyaniline Doped by [BMIM] [BF4] Ionic Liquid
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