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Preparation and Performance of Catanionic Surfactants

  • Hui-Cheng Yan , Qiu-Xiao Li , Tao Geng , Yajie Jiang und Yi Luo
Veröffentlicht/Copyright: 1. März 2013
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Tenside Surfactants Detergents
Aus der Zeitschrift Tenside Surfactants Detergents Band 49 Heft 3

Abstract

A series of catanionic surfactants based on the general formula CH3CH2(CH2)11CH2N+(CH3)3 · −OOCCH2(CH2)nCH2CH3 (n = 2, 4, 6, 8, 10) were synthesized, and measured their critical micelle concentrations (CMC) and the corresponding surface tension at CMC (γCMC). The results revealed that the surface tensions of water were decreased to 21–34 mN · m−1 when applying these surfactants at a concentration range from 10−3 to 10−4 mol · L−1. Moreover, the performance of foaming, emulsification, anti-static and rewetting of the surfactants were investigated and the results showed that both the rewetting and emulsifying ability of the prepared surfactants were much better than that of conventional surfactants. In addition, the anti-static and foaming properties were also improved at the same condition compared to that of conventional surfactants.

Kurzfassung

Eine Reihe katanionischer Tenside basierend auf der allgemeinen Formel CH3CH2(CH2)11CH2N+(CH3)3 · −OOCCH2(CH2)nCH2CH3 (n = 2, 4, 6, 8, 10) wurde synthetisiert und ihre kritischen Mizellbildungskonzentrationen (CMC) und ihre entsprechenden Oberflächenspannungen bei der CMC (γCMC) wurden bestimmt. Die Ergebnisse zeigten, dass die Oberflächenspannung von Wasser auf 21–34 mN m−1 sinkt, wenn die Konzentration der Tenside im Bereich von 10−3 bis 10−4 mol L−1 liegt. Des Weiteren wurde die Leistung der Tenside bei der Schaumbildung, die Emulsionsbildung, der Antistatik, und der Benetzung untersucht. Die Ergebnisse zeigten, dass beides, die Benetzung und die Fähigkeit der Emulsionsbildung der hergestellten Tenside deutlich besser waren als die der konventionellen Tenside. Zusätzlich wurden die antistatischen und die schaumbildenden Eigenschaften bei den gleichen Bedingungen im Vergleich zu den konventionellen Tenside verbessert.

Key words:: Catanionic surfactant; surface activity; performance; anti-static property; textile
Stichwörter:: Katanionisches Tensid; Oberflächenaktivität; Leistung; antistatische Eigenschaft; Textil
1 Prof. Qiuxiao Li, China Research Institute of Daily Chemical Industry, 34 Wenyuan Street, Taiyuan, 030001, Shanxi Province, P. R. China, Tel.: 00 86-351-4046718, Fax: 00 86-351-4040802. E-mail: ,

Hui-cheng Yan was born in 1986. He completed his B.Sc. from Xinzhou Normal University. Presently he is working for Master degree at China Research Institute of Daily Chemical Industry. His research field centered at the synthesis and investigation of quaternary ammonium with new counterions.

Qiu-xiao Li is a professor of China Research Institute of Daily Chemical Industry. His research interests are in the engineering development related to the manufacture of surfactants and in physical chemistry.

Tao Geng is a professor of China Research Institute of Daily Chemical Industry. His research interests are the synthesis and investigation of cationic surfactants.

Yajie Jiang is engineer of China Research Institute of Daily Chemical Industry. Her research interest is synthesis and investigation of novel quaternary ammonium salts.

Yi Luo is senior chemistry engineer of China Research Institute of Daily Chemical Industry.

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Received: 2011-09-23
Revised: 2012-01-22
Published Online: 2013-03-01
Published in Print: 2012-05-01

© 2012, Carl Hanser Publisher, Munich

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. 7th European Detergents Conference (EDC)
  6. Biosurfactants as Antimicrobial Ingredients for Cleaning Products and Cosmetics
  7. Scientific Results and Economic Effects from the Centre for Surfactants Based on Natural Products (SNAP)
  8. Application
  9. Preparation and Performance of Catanionic Surfactants
  10. Environmental Chemistry
  11. Acrylic Acid-Allylpolyethoxy Carboxylate Copolymer Dispersant for Calcium Carbonate and Iron(III) Hydroxide Scales in Cooling Water Systems
  12. Novel Surfactants
  13. Lyotropic Liquid Crystals Formed in Brij35/Copolymer/Water System
  14. Physical Chemistry
  15. Micellization of Alkyl Trimethyl Ammonium Bromides in Aqueous Solutions–Part 1: Critical Micelle Concentration (CMC) and Ionization Degree
  16. Review
  17. Electrical Properties of PANI/Chalcogenide Junctions Doped with Ionic Liquids Anions
  18. Synthesis
  19. Synthesis of Quaternary Derivatives of Ortho-Coco Di-Amido Toluene and Investigation of these Compounds as Cationic Bitumen Emulsifier
  20. Synthesis and Surface Activity of Guerbet Betaine Surfactants with Ethylene Oxide Groups
  21. Research Group Portrait
  22. Investigations in the Stranski-Laboratorium of the TU Berlin – Physical Chemistry of Colloidal Systems – Going Towards Complexity and Functionality
https://doi.org/10.3139/113.110184
Schlagwörter für diesen Artikel
Catanionic surfactant; surface activity; performance; anti-static property; textile

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. 7th European Detergents Conference (EDC)
  6. Biosurfactants as Antimicrobial Ingredients for Cleaning Products and Cosmetics
  7. Scientific Results and Economic Effects from the Centre for Surfactants Based on Natural Products (SNAP)
  8. Application
  9. Preparation and Performance of Catanionic Surfactants
  10. Environmental Chemistry
  11. Acrylic Acid-Allylpolyethoxy Carboxylate Copolymer Dispersant for Calcium Carbonate and Iron(III) Hydroxide Scales in Cooling Water Systems
  12. Novel Surfactants
  13. Lyotropic Liquid Crystals Formed in Brij35/Copolymer/Water System
  14. Physical Chemistry
  15. Micellization of Alkyl Trimethyl Ammonium Bromides in Aqueous Solutions–Part 1: Critical Micelle Concentration (CMC) and Ionization Degree
  16. Review
  17. Electrical Properties of PANI/Chalcogenide Junctions Doped with Ionic Liquids Anions
  18. Synthesis
  19. Synthesis of Quaternary Derivatives of Ortho-Coco Di-Amido Toluene and Investigation of these Compounds as Cationic Bitumen Emulsifier
  20. Synthesis and Surface Activity of Guerbet Betaine Surfactants with Ethylene Oxide Groups
  21. Research Group Portrait
  22. Investigations in the Stranski-Laboratorium of the TU Berlin – Physical Chemistry of Colloidal Systems – Going Towards Complexity and Functionality
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