Automated Determination of Linear Alkylbenzene Sulphonate (LAS) in Wastewater Treatment Plants Effluents Using on Line Solid-phase Extraction Followed by HPLC with Fluorescence Detection
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C. Crey-Desbiolles
Abstract
An on line SPE (solid-phase extraction) method followed by HPLC with fluorescence detection has been developed and validated for determining the LAS in inlet and outlet effluents of wastewaters treatment plants. Filtered effluent samples were on line concentrated on a small polymeric reversed phase column, then the trapped LAS are separated on a specialty polar-embedded reversed-phase column and detected by a fluorimeter. The on line SPE method with fluorescence detection showed very good repeatability (from 1.5 to 11.7% depending on the sample loading volume) and robustness with detection limits of 1.5 μg l−1 for total C10–13 LAS loading a 5 ml sample volume. This automated method is a cost-effective way to determine LAS also in routine monitoring of inlets and outlets of wastewater treatment plants allowing to optimize treatment procedures.
Kurzfassung
Eine online Festphasenextraktion (solid phase extraction; SPE) mit nachfolgender HPLC und Fluoreszenz-Detektion wurde zur Bestimmung von LAS im Zulauf und Ablauf von Kläranlagen entwickelt und validiert. Die filtrierten Abwasserproben wurden online auf einer kurzen unpolaren Säule aufkonzentriert. Danach wurden die adsorbierten LAS auf einer speziellen polaren RP-Trennsäule (polar-embedded) eluiert, getrennt und mit Fluoreszenz-Detektion nachgewiesen. Die online SPE-Methode weist eine sehr gute Wiederholbarkeit (von 1,5 bis 11,7% abhängig vom aufgegebenen Probenvolumen) und hohe Robustheit mit Nachweisgrenzen von 1,5 μg l−1 für C10–13 LAS bei 5 mL Probenvolumen auf. Diese automatisierte Methode ist eine kostengünstige Möglichkeit zur Bestimmung von LAS auch in der Routineüberwachung von Zu- und Abläufen von Kläranlagen.
References
1. HERA: Human and Environmental Risk Assessment of Ingredients of Household Cleaning Products: Report for LAS. 2004, http://www.heraproject.com.Suche in Google Scholar
2. Jensen, J.: Sci. Tot. Environ.226 (1999) 93.10.1016/S0048-9697(98)00395-7Suche in Google Scholar
3. Jensen, J., Lokke, H., Holmstrup, M., Krogh, P. H. and Elsgaard, L.: Environ. Toxicol. Chem.20 (2001) 1690.10.1002/etc.5620200810Suche in Google Scholar
4. Kloepper-Sams, P., Torfs, F., Feijtel, T. C. J. F. and Gooch, J.: Sci. Tot. Environ.185 (1996) 171.10.1016/0048-9697(95)05050-7Suche in Google Scholar
5. Schowanek, D. and David, H.: Regul. Toxicol. Pharma49 (2007) 245.10.1016/j.yrtph.2007.09.001Suche in Google Scholar
6. Fendinger, N. J., Versteeg, D. J., Weeg, E., Dyer, S. and Rapaport, R. A.: in Baker, L.A, editor. Environmental Chemistry of Lakes and Reservoirs. ACS Adv. in Chemistry Series American Chemical Society; 1994. p. 528–57.Suche in Google Scholar
7. Mieure, J. P., Waters, J., Holt, M. S. and Matthijs, E.: Chemosphere21 (1990) 251.10.1016/0045-6535(90)90397-CSuche in Google Scholar
8. Versteeg, D. J. and Rawlings, J. M.: Arch. Environ. Contam. Toxicol.44 (2003) 237.10.1007/s00244-002-2017-2Suche in Google Scholar
9. Temara, A., Carr, G., Webb, S., Versteeg, D. J. and Feijtel, T.: Mar. Pollut. Bull.42 (2001) 635.10.1016/S0025-326X(01)00061-3Suche in Google Scholar
10. Denmark Environmental Protection Agency: Environmental Project 615: Environmental and health assessment of substances in household detergents and cosmetic detergent products; 2001.Suche in Google Scholar
11. Matthijs, E., Holt, M. S., Kiewiet, A. and Rijs, G. B. J.: Environ. Toxicol. Chem.18 (1999) 2634.10.1002/etc.5620181133Suche in Google Scholar
12. Guckert, J. B., Walker, D. D. and Belanger, S. E.: Environ. Chem. Toxicol.15 (1996) 262.Suche in Google Scholar
13. European Union: Working Document on Sludge, Third Draft, 27 April 2000. Brussels, Belgium.Suche in Google Scholar
14. RegioneEmilia Romagna: Determinazione del Direttore generale ambiente, difesa del suolo e della costa n. 11046 del 29/0//2005.Suche in Google Scholar
15. Nimer, M., Ballesteros, O., Navalón, A., Crovetto, G., Verge, C., López, I., Berna, J. L. and Vílchez, J. L.: Anal. Bioanal. Chem.387 (2007) 2175.10.1007/s00216-006-1069-ySuche in Google Scholar
16. Knepper, T., Barceló, D. E. and de Voogt, P.: Comprehensive Analytical Chemistry, XL, Elsevier, Amsterdam, 2003.Suche in Google Scholar
17. Comellas, L., Portillo, J. L. and Vaquero, M. T.: J. Chromatogr. A657 (1993) 25.10.1016/0021-9673(93)83031-MSuche in Google Scholar
18. Morales-Muñoz, S., Luque-García, J. L. and Luque de Castro, M. D.: J. Chromatogr. A1026 (2004) 41.10.1016/j.chroma.2003.11.047Suche in Google Scholar PubMed
19. Lara-Martín, P. A., Gómez-Parra, A. and González-Mazo, E.: J. Chromatogr. A1114 (2006) 205.10.1016/j.chroma.2006.03.014Suche in Google Scholar PubMed
20. Helaleh, M. I. H., Al-Omair, A., Nisar, A. and Gevao, B.: J. Chromatogr. A1083 (2005) 153.10.1016/j.chroma.2005.05.085Suche in Google Scholar PubMed
21. European Union: Regulation (EC) No 648/2004 of the European Parliament and of the Council of 31 March 2004 on detergents, Off. J. Eur. Un., 8.4.2004 L 104/1.Suche in Google Scholar
22. CORILA: Manuale dei metodi analitici per il controllo ambientale di acque e sedimenti della Laguna di Venezia. Metodo 1.13.1 Tensioattivi anionici, Venezia2007, pp. 184–185.Suche in Google Scholar
23. Di Corcia, A., Marchetti, M., Samperi, R. and Marcomini, A.: Anal. Chem.63 (1991) 1179.10.1021/ac00011a023Suche in Google Scholar PubMed
24. Valsecchi, S., Lietti, E. and Polesello, S.: Notiziario dei Metodi Analitici per le Acque, Istituto di Ricerca sulle Acque, C.N.R., Roma, agosto, (2008) 2.Suche in Google Scholar
25. Polesello, S., Valsecchi, S., Cavalli, S. and Romele, L.: Laboratorio2000, aprile (2008) 40.Suche in Google Scholar
26. Croce, V., Patrolecco, L., Polesello, S. and ValsecchiS.: Chromatographia58 (2003) 145.Suche in Google Scholar
27. Liu, X., Pohl, C. A. and Weiss, J.: J. Chromatogr. A1118 (2006) 29.10.1016/j.chroma.2006.03.080Suche in Google Scholar PubMed
28. EURACHEM: EURACHEM Guide: The Fitness for Purpose of Analytical MethodsLGC Ltd., Teddington, UK, 1998.Suche in Google Scholar
© 2009, Carl Hanser Publisher, Munich
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Abstracts
- Abstracts
- Application
- Ultrasonic Assisted Finishing of Cotton with Nonionic Softener
- Effect of Oleate/Bacteria Interactions on Dolomite Separation from Phosphate Ore
- Environmental Chemistry
- Automated Determination of Linear Alkylbenzene Sulphonate (LAS) in Wastewater Treatment Plants Effluents Using on Line Solid-phase Extraction Followed by HPLC with Fluorescence Detection
- Novel Surfactants
- Effect of Calcium Ions Concentration on the Foaming Power of Anionic Surfactants
- Lauryl Trimethyl Ammoniums with New Type Counteranions
- Physical Chemistry
- Extraction of Copper(II) from Sulphate Aqueous Medium with N,N′-bis(2-hydroxy-1-naphthalideneaminoethyl)amine Polydentate Schiff Base in Aqueous Two-phase Micellar of Non-Ionic Surfactant
- Effect of Cellulase Enzyme on Cellulose Nano-topography
- Review
- Synthesis, Structural Properties and Applications of Gemini Surfactants: A Review
Artikel in diesem Heft
- Contents/Inhalt
- Contents
- Abstracts
- Abstracts
- Application
- Ultrasonic Assisted Finishing of Cotton with Nonionic Softener
- Effect of Oleate/Bacteria Interactions on Dolomite Separation from Phosphate Ore
- Environmental Chemistry
- Automated Determination of Linear Alkylbenzene Sulphonate (LAS) in Wastewater Treatment Plants Effluents Using on Line Solid-phase Extraction Followed by HPLC with Fluorescence Detection
- Novel Surfactants
- Effect of Calcium Ions Concentration on the Foaming Power of Anionic Surfactants
- Lauryl Trimethyl Ammoniums with New Type Counteranions
- Physical Chemistry
- Extraction of Copper(II) from Sulphate Aqueous Medium with N,N′-bis(2-hydroxy-1-naphthalideneaminoethyl)amine Polydentate Schiff Base in Aqueous Two-phase Micellar of Non-Ionic Surfactant
- Effect of Cellulase Enzyme on Cellulose Nano-topography
- Review
- Synthesis, Structural Properties and Applications of Gemini Surfactants: A Review
