Startseite Aqueous Solution Properties, Biodegradability, and Antimicrobial Activity of some Alkylpolyglycosides Surfactants
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Aqueous Solution Properties, Biodegradability, and Antimicrobial Activity of some Alkylpolyglycosides Surfactants

  • M. M. A. El-Sukkary , N. A. Syed , Ismail Aiad , S. M. Helmy und W. I. M. El-Azab
Veröffentlicht/Copyright: 2. April 2013
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Tenside Surfactants Detergents
Aus der Zeitschrift Tenside Surfactants Detergents Band 46 Heft 5

Abstract

In the present investigation, a series of alkyl polyglycosides with alkyl chain length of C 8, 9, 10, 12 and 14 were synthesized using transacetalization method. Purity of the products was investigated using high performance liquid chromatography. Surface parameters particularly Effectiveness πcmc, Efficiency Pc20, maximum surface excess Γmax, minimum surface area Amin and HLB values are investigated, in addition to thermodynamic parameters (ΔGads and ΔGmic). Resistance to hydrolysis for the prepared compounds was investigated. The synthesized compounds were tested for their biodegradability in Nile river water according to Die-away test method and their antimicrobial activity against different strains of bacteria, yeast and fungi was investigated.

Kurzfassung

In der vorliegenden Arbeit wurde eine Reihe von Alkylpolyglycosiden mit einer Alkylkettenlänge von C 8, 9, 10, 12 und 14 mittels Umacetalisierung synthetisiert. Die Reinheit der Produkte wurde mittels Hochdruckflüssigkeitschromatographie untersucht. Zusätzlich zu den thermodynamischen Parametern (ΔGads and ΔGmic) wurden die Oberflächenparmeter, insbesondere die Effektivität (πcmc), die Adsorptionswirkung (Pc20), die Oberflächenüberschusskonzentration Γmax, die Minimumoberfläche Amin und die HLB-Werte sowie die Beständigkeit gegen Hydrolyse untersucht. Die synthetisierten Verbindungen wurden entsprechend der Die-away Testmethode auf ihre biologische Abbaubarkeit in Nilwasser und auf ihre antimikrobielle Aktivität gegen verschiedene Bakterienstämme, Hefe und Pilze untersucht.

Key words:: Alkyl polyglycosides; surface parameters; thermodynamic parameters; biodegradability; antimicrobial activity
Stichwörter:: Alkylpolyglycoside; Oberflächenparameter; thermodynamische Parameter; biologische Abbaubarkeit; antimikrobielle Aktivität
∗ W. I. M. El-Azab, Egyptian Petroleum Research Institute, Petrochemicals Department, Nasr city, 11727, Cairo, Egypt, E-Mail:

M. M. A. El-Sukkary, Prof. Dr. of organic chemistry, Petrochemicals Department, Egyptian Petroleum Research Institute, Cairo, Egypt.

N. A. Syed, Prof. Dr. of physical chemistry, Analysis and Evaluation Department, Egyptian Petroleum Research Institute, Cairo, Egypt.

Ismail Aiad, Prof. Dr. of organic chemistry, Petrochemicals Department, Egyptian Petroleum Research Institute, Cairo, Egypt.

S. M. Helmy, Associate prof. of microbiology, Microbial Chemistry Department, National research Center, Cairo, Egypt.

W. I. M. El-Azab, Researcher, Petrochemicals Department, Egyptian Petroleum Research Institute, Cairo, Egypt.

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Received: 2009-01-13
Revised: 2009-05-29
Published Online: 2013-04-02
Published in Print: 2009-09-01

© 2009, Carl Hanser Publisher, Munich

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Micelles Activated Planar Chromatographic Separation of Hydrophilic Vitamins
  7. Molecular, Surface, Thermodynamic Properties and Biodegradability of Nonionic Surfactants Based on Castor Oil
  8. Basic Science
  9. Characterization of Commercial Polysorbates Using Different Chromatographic Techniques
  10. Environmental Chemistry
  11. Synthesis of Nanocrystal TiO2 and Study of Photocatalytic Degradation Property
  12. Novel Surfactants
  13. Reversible Performance of Dodecyl Tetramethyl Guanidine Solution Induced by CO2 Trigger
  14. Physical Chemistry
  15. Synergism in Mixed Anionic–Amphoteric Surfactant Solutions: Influence of Anionic Surfactant Chain Length
  16. Phase Behavior of Microemulsions Prepared from Surfactant-like Ionic Liquids
  17. Technical Chemistry
  18. Aqueous Solution Properties, Biodegradability, and Antimicrobial Activity of some Alkylpolyglycosides Surfactants
https://doi.org/10.3139/113.110037
Schlagwörter für diesen Artikel
Alkyl polyglycosides; surface parameters; thermodynamic parameters; biodegradability; antimicrobial activity

Artikel in diesem Heft

  1. Contents/Inhalt
  2. Contents
  3. Abstracts
  4. Abstracts
  5. Application
  6. Micelles Activated Planar Chromatographic Separation of Hydrophilic Vitamins
  7. Molecular, Surface, Thermodynamic Properties and Biodegradability of Nonionic Surfactants Based on Castor Oil
  8. Basic Science
  9. Characterization of Commercial Polysorbates Using Different Chromatographic Techniques
  10. Environmental Chemistry
  11. Synthesis of Nanocrystal TiO2 and Study of Photocatalytic Degradation Property
  12. Novel Surfactants
  13. Reversible Performance of Dodecyl Tetramethyl Guanidine Solution Induced by CO2 Trigger
  14. Physical Chemistry
  15. Synergism in Mixed Anionic–Amphoteric Surfactant Solutions: Influence of Anionic Surfactant Chain Length
  16. Phase Behavior of Microemulsions Prepared from Surfactant-like Ionic Liquids
  17. Technical Chemistry
  18. Aqueous Solution Properties, Biodegradability, and Antimicrobial Activity of some Alkylpolyglycosides Surfactants
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