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Reactions of Protonated Water Clusters with Chlorine Nitrate Revisited
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J.J. Gilligan
Veröffentlicht/Copyright:
25. September 2009
Potential reaction mechanisms of D+(D2O)n (n = 4-30) with chlorine nitrate (ClONO2) have been investigated using a fast flow reactor operated under thermal conditions. Chemical reactions are not observed to occur between D+(D2O)n and chlorine nitrate. Instead, through studies employing the heavy isotope of hydrogen, we found that the nitric acid observed in the product ion spectrum arises from a nitric acid impurity that is usually present to some degree in the methods employed to synthesize ClONO2 reactant gas. The results from this study serve to explain other conflicting reaction mechanisms reported in the literature, and which have been discussed in the context of atmospheric chemistry.
Published Online: 2009-09-25
Published in Print: 2000-10
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Artikel in diesem Heft
- Pyrolysis Nozzles Coupled to a Microwave Spectrometer with Stark Modulation for the Detection of Transients Species in a Supersonic Expansion
- Collision Model of `Fall-Off´ in Recombination Reactions
- Is there any Correlation between the Mobility and the Absorption Spectra of Solvated Electrons in Polar Solvents?
- Decomposition of the CF3CO Radical: Pressure and Temperature Dependencies of the Rate Constant
- Ultrafast Proton-Transfer and Coherent Wavepacket Motion of Electronically Excited 1,8-Dihydroxyanthraquinone in Liquid Benzyl Alcohol Solution
- Reactions of Protonated Water Clusters with Chlorine Nitrate Revisited
- Laser Phase Control of Electron-Nuclear Dynamics in Dissociative Ionization with Intense Femtosecond Pulses: Exact (non-Born-Oppenheimer) Numerical Simulations for H+2
