Startseite The crystal structures of 2 M1 phengite and 2 M1 muscovite
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The crystal structures of 2 M1 phengite and 2 M1 muscovite

Veröffentlicht/Copyright: 28. Juli 2010

Abstract

The crystal structures of 2 M1 phengite and 2 M1 muscovite have been refined by least-squares methods using single-crystal diffractometer data. Final discrepancy factors were unweighted R = 0.045 for 2 M1 phengite and 0.035 for 2 M1 muscovite. Both specimens have the space group C 2/c and the following cell dimensions at room temperature:

2 M1 phengite 2 M1 muscovite

a 5.2112 ± 0.0003 Å 5.1906 ± 0.0002 Å

b 9.0383 ± 0.0004 9.0080 ± 0.0003

c 19.9473 ± 0.0006 20.0470 ± 0.0006

β 95.769 ± 0.005° 95.757 ± 0.002°.

In 2 M1 muscovite tetrahedral cation-oxygen distances T1–O = T2–O = 1.643 Å show that there is no ordering of (Si,Al) over the tetrahedral site. In the structure of 2 M1 phengite, however, the corresponding values, T1–O = 1.622 and T2–O = 1.633 Å, indicate a very slight ordering. The framework of anions is distorted twice as much in 2 M1 muscovite than in 2 M1 phengite.

Published Online: 2010-7-28
Published in Print: 1971-9-1

© 2015 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München

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