Artikel
Lizenziert
Nicht lizenziert
Erfordert eine Authentifizierung
Three-Membered Ring Formation by Si···N Interactions in Aminosulfenylsilanes
-
Norbert W. Mitzel
Veröffentlicht/Copyright:
2. Juni 2014
The reaction of dimethylaminosulfenylchloride Me2NSCl with trichlorosilane HSiCl3 and triethylamine gives elemental sulphur and Me2NSiCl3. The aminosulfenylsilane Me2NSSiCl3 is postulated to be an intermediate of this reaction. Ab initio calculations (MP2/6D311G(d,p)) on Me2N-S-SiH3, Me2N-S-SiH2Cl, Me2N-S-SiH2F, and Me2N-S-SiCl3 have been carried out, demonstrating the occurrence of acute valence angles at sulphur and short Si···N distances, which are indicative of NSSi three-membered rings. The strength of the Si · · · N interactions depends on the electronegativity of the substituent at silicon in anti-position to the nitrogen atom and is strongest in the anti conformer of Me2N-S-SiH2F (< NSSi 68°, Si···N 2.208 Å ). The coordination spheres of the nitrogen atoms in the Me2N-S-SiR3 molecules are steeply pyramidal, which is in contrast to the planarised N atoms in other SNMe2 compounds, such as Me2NSCl. The crystal structure of this compound has been determined, as well as that of the product of the above reaction, Me2NSiCl3. Both have planar coordination geometries at the nitrogen atoms.
Received: 2003-2-24
Published Online: 2014-6-2
Published in Print: 2003-5-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
Sie haben derzeit keinen Zugang zu diesem Inhalt.
Sie haben derzeit keinen Zugang zu diesem Inhalt.
Artikel in diesem Heft
- Organoaluminium and -Gallium Compounds with O-Oximato Substituents
- Three-Membered Ring Formation by Si···N Interactions in Aminosulfenylsilanes
- Einkristalle des Neodym(III)-meta-Borats Nd(BO2)3 und -ortho-Borats Nd[BO3]/Single Crystals of the Neodymium(III) meta-Borate Nd(BO2)3 and ortho-Borate Nd[BO3]
- Synthesis and Structure of 1-{2,2-Dimethyl-4,6-dioxo-5-(1-pyridinio)-1,3- dioxan-5-yl}pyridinium Ylide: A New Route to Meldrum’s Acid Derivatives
- The NaCl Adduct of the Iron-Indium Compound Fe2(CO)6(μ-CO)(μ-InR)2 [R = C(SiMe3)3] – a One-Dimensional Coordination Polymer with Sodium Oxygen Bridges
- On Attempts to Synthesize Lanthanide Complexes of the Dianionic Fluorenyl-alkoxo Ligand [C13H8-cyclo-C6H10-O]2-. Crystal Structure of (C13H9-cyclo-C6H10-O)LaI2(DME)2
- Zinc (Hydrogen-β-glutamate)-chloride Hydrate [Zn (β-GluH)Cl(H2O)], a One-dimensional Coordination Polymer
- Preparation and Crystal Structures of Ternary Rare Earth Silver and Gold Arsenides LnAgAs2 and LnAuAs2 with Ln = La–Nd, Sm, Gd, and Tb
- Synthese, Kristallstruktur und spektroskopische Charakterisierung von Bis(dimethylammonium)hexachlorotitanat [Me2NH2]2[TiCl6]/ Synthesis, Crystal Structure, and Spectroscopic Characterization of Bis(dimethylammonium) Hexachlorotitanate [Me2NH2]2[TiCl6]
- The Effect of High Energy Milling on the Solid State Synthesis of MnFe2O4 from Mixtures of MnO-Fe2O3 and Mn3O4-Fe2O3
- Behaviour of Bimetallic Pt-Pd Carbon-Supported Catalysts in Methanol Electrooxidation
- Crystal Structure and Magnetic Properties of a Dinuclear Iron(III) Doubly Oxygen Bridged Schiff Base Complex
- seco-Dolastanes from the Marine Brown Alga Dictyota dichotoma (Huds.) Lamour
- Large Scale Synthesis of 4’-(4-Bromophenyl)-2,2’:6’,2”-terpyridine and Nature of the Mysterious Green By-product
- C-Substituierte Cyclame aus Cyclotetrapeptiden [1]/ C-Substituted Cyclams from Cyclotetrapeptides [1]
- Synthesis of the Pyrrole-Imidazole Alkaloid Sventrin from the Marine Sponge Agelas sventres
- Carboxylic Acid Analogues of Fosmidomycin
- Effective Mummification Compounds Used in Pharaonic Egypt: Reactivity on Bone Alkaline Phosphatase
- 2-Amino-1,3-dimethylimidazolium 2,2-Dimethyl-4,6-dioxo-1,3-dioxanide. First Structural Characterisation of the Anion of Meldrum’s Acid [1]
- Vibrational Spectra of the Layered Compound [(VO2)2(4,4-bipy)0.5(4,4′- Hbipy)(PO4)]·H2O
- A Hydrogen Bonded Aluminium Alkoxide Hydroxide Aggregate Resulting from the Exposure of Methylaluminium Dichloride to Air
- Zinc Bis[μ-N,N′-chlorozinc-bis(N-trimethylsilylimino- diphenylphosphoranyl)- methanediide]: A Zinc Derivative of a Geminal Carbdianion
Artikel in diesem Heft
- Organoaluminium and -Gallium Compounds with O-Oximato Substituents
- Three-Membered Ring Formation by Si···N Interactions in Aminosulfenylsilanes
- Einkristalle des Neodym(III)-meta-Borats Nd(BO2)3 und -ortho-Borats Nd[BO3]/Single Crystals of the Neodymium(III) meta-Borate Nd(BO2)3 and ortho-Borate Nd[BO3]
- Synthesis and Structure of 1-{2,2-Dimethyl-4,6-dioxo-5-(1-pyridinio)-1,3- dioxan-5-yl}pyridinium Ylide: A New Route to Meldrum’s Acid Derivatives
- The NaCl Adduct of the Iron-Indium Compound Fe2(CO)6(μ-CO)(μ-InR)2 [R = C(SiMe3)3] – a One-Dimensional Coordination Polymer with Sodium Oxygen Bridges
- On Attempts to Synthesize Lanthanide Complexes of the Dianionic Fluorenyl-alkoxo Ligand [C13H8-cyclo-C6H10-O]2-. Crystal Structure of (C13H9-cyclo-C6H10-O)LaI2(DME)2
- Zinc (Hydrogen-β-glutamate)-chloride Hydrate [Zn (β-GluH)Cl(H2O)], a One-dimensional Coordination Polymer
- Preparation and Crystal Structures of Ternary Rare Earth Silver and Gold Arsenides LnAgAs2 and LnAuAs2 with Ln = La–Nd, Sm, Gd, and Tb
- Synthese, Kristallstruktur und spektroskopische Charakterisierung von Bis(dimethylammonium)hexachlorotitanat [Me2NH2]2[TiCl6]/ Synthesis, Crystal Structure, and Spectroscopic Characterization of Bis(dimethylammonium) Hexachlorotitanate [Me2NH2]2[TiCl6]
- The Effect of High Energy Milling on the Solid State Synthesis of MnFe2O4 from Mixtures of MnO-Fe2O3 and Mn3O4-Fe2O3
- Behaviour of Bimetallic Pt-Pd Carbon-Supported Catalysts in Methanol Electrooxidation
- Crystal Structure and Magnetic Properties of a Dinuclear Iron(III) Doubly Oxygen Bridged Schiff Base Complex
- seco-Dolastanes from the Marine Brown Alga Dictyota dichotoma (Huds.) Lamour
- Large Scale Synthesis of 4’-(4-Bromophenyl)-2,2’:6’,2”-terpyridine and Nature of the Mysterious Green By-product
- C-Substituierte Cyclame aus Cyclotetrapeptiden [1]/ C-Substituted Cyclams from Cyclotetrapeptides [1]
- Synthesis of the Pyrrole-Imidazole Alkaloid Sventrin from the Marine Sponge Agelas sventres
- Carboxylic Acid Analogues of Fosmidomycin
- Effective Mummification Compounds Used in Pharaonic Egypt: Reactivity on Bone Alkaline Phosphatase
- 2-Amino-1,3-dimethylimidazolium 2,2-Dimethyl-4,6-dioxo-1,3-dioxanide. First Structural Characterisation of the Anion of Meldrum’s Acid [1]
- Vibrational Spectra of the Layered Compound [(VO2)2(4,4-bipy)0.5(4,4′- Hbipy)(PO4)]·H2O
- A Hydrogen Bonded Aluminium Alkoxide Hydroxide Aggregate Resulting from the Exposure of Methylaluminium Dichloride to Air
- Zinc Bis[μ-N,N′-chlorozinc-bis(N-trimethylsilylimino- diphenylphosphoranyl)- methanediide]: A Zinc Derivative of a Geminal Carbdianion
