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Crystal Structure and Magnetic Properties of a Dinuclear Iron(III) Doubly Oxygen Bridged Schiff Base Complex

  • A. Elmali EMAIL logo , Y. Elerman , C. T. Zeyrek und I. Svoboda
Veröffentlicht/Copyright: 2. Juni 2014
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Zeitschrift für Naturforschung B
Aus der Zeitschrift Zeitschrift für Naturforschung B Band 58 Heft 5

[Fe(L)Cl]2 (L = N-(4-methylphenyl)-3-methoxy-salicylaldimimine) was synthesized and its crystal structure determined. [C30H26Cl2Fe2N2O6], triclinic, space group P 1̄ , a = 9.278(2), b = 9.4050(10), c = 10.489(2) Å , α = 64.43(2), β = 74.540(10), γ = 62.40(2)° , V = 729.1(2) Å 3, Z = 1. Two identical [Fe(L)Cl] fragments, related by an inversion center, are connected by two bridging O atoms to form a binuclear unit. The iron(III) centers are separated by 3.196(2) Å and weakly antiferromagnetically coupled (J = -10.1(1) cm-1), as derived from temperature-dependent magnetic susceptibility measurements in the range 5.1-283.5 K.

Keywords: Dinuclear Iron(III) Complex; Super-Exchange Interactions; Antiferromagnetic Coupling
Received: 2002-12-4
Published Online: 2014-6-2
Published in Print: 2003-5-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Artikel in diesem Heft

  1. Organoaluminium and -Gallium Compounds with O-Oximato Substituents
  2. Three-Membered Ring Formation by Si···N Interactions in Aminosulfenylsilanes
  3. Einkristalle des Neodym(III)-meta-Borats Nd(BO2)3 und -ortho-Borats Nd[BO3]/Single Crystals of the Neodymium(III) meta-Borate Nd(BO2)3 and ortho-Borate Nd[BO3]
  4. Synthesis and Structure of 1-{2,2-Dimethyl-4,6-dioxo-5-(1-pyridinio)-1,3- dioxan-5-yl}pyridinium Ylide: A New Route to Meldrum’s Acid Derivatives
  5. The NaCl Adduct of the Iron-Indium Compound Fe2(CO)6(μ-CO)(μ-InR)2 [R = C(SiMe3)3] – a One-Dimensional Coordination Polymer with Sodium Oxygen Bridges
  6. On Attempts to Synthesize Lanthanide Complexes of the Dianionic Fluorenyl-alkoxo Ligand [C13H8-cyclo-C6H10-O]2-. Crystal Structure of (C13H9-cyclo-C6H10-O)LaI2(DME)2
  7. Zinc (Hydrogen-β-glutamate)-chloride Hydrate [Zn (β-GluH)Cl(H2O)], a One-dimensional Coordination Polymer
  8. Preparation and Crystal Structures of Ternary Rare Earth Silver and Gold Arsenides LnAgAs2 and LnAuAs2 with Ln = La–Nd, Sm, Gd, and Tb
  9. Synthese, Kristallstruktur und spektroskopische Charakterisierung von Bis(dimethylammonium)hexachlorotitanat [Me2NH2]2[TiCl6]/ Synthesis, Crystal Structure, and Spectroscopic Characterization of Bis(dimethylammonium) Hexachlorotitanate [Me2NH2]2[TiCl6]
  10. The Effect of High Energy Milling on the Solid State Synthesis of MnFe2O4 from Mixtures of MnO-Fe2O3 and Mn3O4-Fe2O3
  11. Behaviour of Bimetallic Pt-Pd Carbon-Supported Catalysts in Methanol Electrooxidation
  12. Crystal Structure and Magnetic Properties of a Dinuclear Iron(III) Doubly Oxygen Bridged Schiff Base Complex
  13. seco-Dolastanes from the Marine Brown Alga Dictyota dichotoma (Huds.) Lamour
  14. Large Scale Synthesis of 4’-(4-Bromophenyl)-2,2’:6’,2”-terpyridine and Nature of the Mysterious Green By-product
  15. C-Substituierte Cyclame aus Cyclotetrapeptiden [1]/ C-Substituted Cyclams from Cyclotetrapeptides [1]
  16. Synthesis of the Pyrrole-Imidazole Alkaloid Sventrin from the Marine Sponge Agelas sventres
  17. Carboxylic Acid Analogues of Fosmidomycin
  18. Effective Mummification Compounds Used in Pharaonic Egypt: Reactivity on Bone Alkaline Phosphatase
  19. 2-Amino-1,3-dimethylimidazolium 2,2-Dimethyl-4,6-dioxo-1,3-dioxanide. First Structural Characterisation of the Anion of Meldrum’s Acid [1]
  20. Vibrational Spectra of the Layered Compound [(VO2)2(4,4-bipy)0.5(4,4′- Hbipy)(PO4)]·H2O
  21. A Hydrogen Bonded Aluminium Alkoxide Hydroxide Aggregate Resulting from the Exposure of Methylaluminium Dichloride to Air
  22. Zinc Bis[μ-N,N′-chlorozinc-bis(N-trimethylsilylimino- diphenylphosphoranyl)- methanediide]: A Zinc Derivative of a Geminal Carbdianion
https://doi.org/10.1515/znb-2003-0512
Schlagwörter für diesen Artikel
Dinuclear Iron(III) Complex; Super-Exchange Interactions; Antiferromagnetic Coupling

Artikel in diesem Heft

  1. Organoaluminium and -Gallium Compounds with O-Oximato Substituents
  2. Three-Membered Ring Formation by Si···N Interactions in Aminosulfenylsilanes
  3. Einkristalle des Neodym(III)-meta-Borats Nd(BO2)3 und -ortho-Borats Nd[BO3]/Single Crystals of the Neodymium(III) meta-Borate Nd(BO2)3 and ortho-Borate Nd[BO3]
  4. Synthesis and Structure of 1-{2,2-Dimethyl-4,6-dioxo-5-(1-pyridinio)-1,3- dioxan-5-yl}pyridinium Ylide: A New Route to Meldrum’s Acid Derivatives
  5. The NaCl Adduct of the Iron-Indium Compound Fe2(CO)6(μ-CO)(μ-InR)2 [R = C(SiMe3)3] – a One-Dimensional Coordination Polymer with Sodium Oxygen Bridges
  6. On Attempts to Synthesize Lanthanide Complexes of the Dianionic Fluorenyl-alkoxo Ligand [C13H8-cyclo-C6H10-O]2-. Crystal Structure of (C13H9-cyclo-C6H10-O)LaI2(DME)2
  7. Zinc (Hydrogen-β-glutamate)-chloride Hydrate [Zn (β-GluH)Cl(H2O)], a One-dimensional Coordination Polymer
  8. Preparation and Crystal Structures of Ternary Rare Earth Silver and Gold Arsenides LnAgAs2 and LnAuAs2 with Ln = La–Nd, Sm, Gd, and Tb
  9. Synthese, Kristallstruktur und spektroskopische Charakterisierung von Bis(dimethylammonium)hexachlorotitanat [Me2NH2]2[TiCl6]/ Synthesis, Crystal Structure, and Spectroscopic Characterization of Bis(dimethylammonium) Hexachlorotitanate [Me2NH2]2[TiCl6]
  10. The Effect of High Energy Milling on the Solid State Synthesis of MnFe2O4 from Mixtures of MnO-Fe2O3 and Mn3O4-Fe2O3
  11. Behaviour of Bimetallic Pt-Pd Carbon-Supported Catalysts in Methanol Electrooxidation
  12. Crystal Structure and Magnetic Properties of a Dinuclear Iron(III) Doubly Oxygen Bridged Schiff Base Complex
  13. seco-Dolastanes from the Marine Brown Alga Dictyota dichotoma (Huds.) Lamour
  14. Large Scale Synthesis of 4’-(4-Bromophenyl)-2,2’:6’,2”-terpyridine and Nature of the Mysterious Green By-product
  15. C-Substituierte Cyclame aus Cyclotetrapeptiden [1]/ C-Substituted Cyclams from Cyclotetrapeptides [1]
  16. Synthesis of the Pyrrole-Imidazole Alkaloid Sventrin from the Marine Sponge Agelas sventres
  17. Carboxylic Acid Analogues of Fosmidomycin
  18. Effective Mummification Compounds Used in Pharaonic Egypt: Reactivity on Bone Alkaline Phosphatase
  19. 2-Amino-1,3-dimethylimidazolium 2,2-Dimethyl-4,6-dioxo-1,3-dioxanide. First Structural Characterisation of the Anion of Meldrum’s Acid [1]
  20. Vibrational Spectra of the Layered Compound [(VO2)2(4,4-bipy)0.5(4,4′- Hbipy)(PO4)]·H2O
  21. A Hydrogen Bonded Aluminium Alkoxide Hydroxide Aggregate Resulting from the Exposure of Methylaluminium Dichloride to Air
  22. Zinc Bis[μ-N,N′-chlorozinc-bis(N-trimethylsilylimino- diphenylphosphoranyl)- methanediide]: A Zinc Derivative of a Geminal Carbdianion
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