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Wechselwirkungen in Molekülkristallen, 175 [1, 2]. Kristallzüchtung und Strukturbestimmung von {Cäsium-tetraphenylimido- diphosphat}-Aggregaten mit unterschiedlicher lipophiler Umhüllung durch verschiedenartig Methyl-substituierte Phenylringe sowie relativistische DFT-Modellberechnungen zu Cäsium/Cäsium-Wechselwirkungen / Interaction in M olecular Crystals, 175 [1,2]. Crystal Growth and Structure Determination of {Cesium-tetraphenylimidodiphosphate} Aggregates with Differing Lipophilic Wrapping Due to Differently Methyl-Substituted Phenyl Rings, and Relativistic DFT-Model Calculations of Cesium/Cesium Interactions
-
Hans Bock
Veröffentlicht/Copyright:
2. Juni 2014
Abstract
In alkali-tetraphenylimidodiphosphate ion aggregates, the size of the cation determines the curvature of the ligand and, therefore, whether hexameric ellipsoidal clusters or polymeric chains are formed. To further characterize the ligand spatial requirements, the phenyl rings have been methylsubstituted in 4-, 3/5-, 3/4- or 2,3-positions, their conformations structurally analyzed and correlated with the van der Waals substituent profiles. In addition, relativistic density functional theory potential curves have been calculated for the Cs⊕ ··· Cs⊕
interactions in simplified model systems.
Keywords : Cesium Tetraphenylimidodiphosphates; Methyl Substitution Effects; Polyion Aggregates; Crystal Structures
Received: 2000-12-21
Published Online: 2014-6-2
Published in Print: 2001-6-1
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung
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Artikel in diesem Heft
- A One-Dimensional Polymeric Form of the Polycation Te82+ in the Structure of Te8[Bi4Cl14]
- Preparation and Structure of Cyclic Gallium(III) and Gallium(II) 2-Amino-ethyl-amides
- New Metal-Rich Compounds NblrSi, NblrGe, and TalrSi -Synthesis, Structure, and Magnetic Properties
- Wechselwirkungen in Molekülkristallen, 174 [1, 2]. Kristallzüchtung und Strukturbestimmung verschiedenartig Methyl-substituierter Imidodiphosphorsäuretetraphenylester / Interaction in Molecular Crystals, 174 [1, 2]. Crystal Growth and Structure Determination of Differently Methyl-Substituted Tetraphenyl Imidodiphosphates
- Wechselwirkungen in Molekülkristallen, 175 [1, 2]. Kristallzüchtung und Strukturbestimmung von {Cäsium-tetraphenylimido- diphosphat}-Aggregaten mit unterschiedlicher lipophiler Umhüllung durch verschiedenartig Methyl-substituierte Phenylringe sowie relativistische DFT-Modellberechnungen zu Cäsium/Cäsium-Wechselwirkungen / Interaction in M olecular Crystals, 175 [1,2]. Crystal Growth and Structure Determination of {Cesium-tetraphenylimidodiphosphate} Aggregates with Differing Lipophilic Wrapping Due to Differently Methyl-Substituted Phenyl Rings, and Relativistic DFT-Model Calculations of Cesium/Cesium Interactions
- Fluoreliminierung aus Graphitfluorid mit Magnesium / Defluorination of Graphite Fluoride Applying Magnesium Emst-Christian Koch
- Synthesis and Crystal Structure of a Novel Polymeric Lead(II) Complex with Thiosemicarbazonato and Thiocyanate Ligands
- Dependence of the Distortion of the Square Pyramids in N, N-Dimethylethylenediammonium Pentachloroantimonate(III) on the Geometry of Hydrogen Bonds
- Synthesis and Solid-Phase Application of a 9-Xanthenyl Handle
- α-Dicarbonylmonophenylhydrazone als Nucleophile und Nachbargruppen / α-Dicarbonylmonophenylhydrazones as Nucleophiles and Neighbouring Groups
- Synthese und Eigenschaften von α Aminocarbohydroximsäure-estern / Synthesis and Properties of α-Aminocarbohydroximic Esters
- A New Synthesis of Two Naturally Occurring Dihydrobenzo[b]furan-Type Neolignans of Potential Biological Activity
Schlagwörter für diesen Artikel
Cesium Tetraphenylimidodiphosphates;
Methyl Substitution Effects;
Polyion Aggregates;
Crystal Structures
Artikel in diesem Heft
- A One-Dimensional Polymeric Form of the Polycation Te82+ in the Structure of Te8[Bi4Cl14]
- Preparation and Structure of Cyclic Gallium(III) and Gallium(II) 2-Amino-ethyl-amides
- New Metal-Rich Compounds NblrSi, NblrGe, and TalrSi -Synthesis, Structure, and Magnetic Properties
- Wechselwirkungen in Molekülkristallen, 174 [1, 2]. Kristallzüchtung und Strukturbestimmung verschiedenartig Methyl-substituierter Imidodiphosphorsäuretetraphenylester / Interaction in Molecular Crystals, 174 [1, 2]. Crystal Growth and Structure Determination of Differently Methyl-Substituted Tetraphenyl Imidodiphosphates
- Wechselwirkungen in Molekülkristallen, 175 [1, 2]. Kristallzüchtung und Strukturbestimmung von {Cäsium-tetraphenylimido- diphosphat}-Aggregaten mit unterschiedlicher lipophiler Umhüllung durch verschiedenartig Methyl-substituierte Phenylringe sowie relativistische DFT-Modellberechnungen zu Cäsium/Cäsium-Wechselwirkungen / Interaction in M olecular Crystals, 175 [1,2]. Crystal Growth and Structure Determination of {Cesium-tetraphenylimidodiphosphate} Aggregates with Differing Lipophilic Wrapping Due to Differently Methyl-Substituted Phenyl Rings, and Relativistic DFT-Model Calculations of Cesium/Cesium Interactions
- Fluoreliminierung aus Graphitfluorid mit Magnesium / Defluorination of Graphite Fluoride Applying Magnesium Emst-Christian Koch
- Synthesis and Crystal Structure of a Novel Polymeric Lead(II) Complex with Thiosemicarbazonato and Thiocyanate Ligands
- Dependence of the Distortion of the Square Pyramids in N, N-Dimethylethylenediammonium Pentachloroantimonate(III) on the Geometry of Hydrogen Bonds
- Synthesis and Solid-Phase Application of a 9-Xanthenyl Handle
- α-Dicarbonylmonophenylhydrazone als Nucleophile und Nachbargruppen / α-Dicarbonylmonophenylhydrazones as Nucleophiles and Neighbouring Groups
- Synthese und Eigenschaften von α Aminocarbohydroximsäure-estern / Synthesis and Properties of α-Aminocarbohydroximic Esters
- A New Synthesis of Two Naturally Occurring Dihydrobenzo[b]furan-Type Neolignans of Potential Biological Activity
