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Acetylene selective hydrogenation: a technical review on catalytic aspects

  • Maryam Takht Ravanchi

    Maryam Takht Ravanchi holds a PhD in chemical engineering. She is a researcher at Petrochemical Research and Technology Company (NPC-RT). Her recent research activities focus on acetylene selective hydrogenation, CO2 utilization, and paraffin dehydrogenation. To date, she has published about 50 scientific papers in national and international journals and presented more than 50 papers at national and international conferences. Moreover, she has published four national patents and seven books.

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    , Saeed Sahebdelfar

    Saeed Sahebdelfar holds a PhD in chemical engineering. He is the head of the Catalysis Research Group at NPC-RT. His research interests include catalysts for hydrogenation-dehydrogenation reactions, chemical fixation of CO2, reactor design, and environmental engineering. He has more than 20 years of experience in the petrochemical industry. To date, he has published or presented more than 100 scientific papers in national and international journals and at national and international conferences.

    und Samane Komeili

    Samane Komeili obtained her PhD in chemical engineering from Iran University of Science and Technology in 2016. She is interested in process modeling and heterogeneous catalysts. Recently, she has done research on the design and application of supported metal catalysts in the fields of selective hydrogenation and selective catalytic reduction. Her special focus is on the synthesis of zeolite and aluminate as the catalyst support. To date, she has published seven scientific papers.

Veröffentlicht/Copyright: 16. März 2017
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Abstract

The catalytic selective hydrogenation of multiunsaturated hydrocarbons, especially in pyrolysis products, to corresponding mono-olefins is a widely exploited way for the large-scale production of polymer-grade olefins as well as fuel upgrading. Thermodynamic and/or kinetic parameters could be effective for selective operation. The latter is primarily influenced by catalyst formulation, including promoters, support type, and metal dispersion and distribution. The solution to achieve an economically attractive commercial implementation lies in defining the optimal catalyst design and operating conditions. The theoretical and practical aspects of catalysis for the selective hydrogenation of acetylene to ethylene are reviewed and the potential new ways to improve catalyst formulation are examined.

About the authors

Maryam Takht Ravanchi

Maryam Takht Ravanchi holds a PhD in chemical engineering. She is a researcher at Petrochemical Research and Technology Company (NPC-RT). Her recent research activities focus on acetylene selective hydrogenation, CO2 utilization, and paraffin dehydrogenation. To date, she has published about 50 scientific papers in national and international journals and presented more than 50 papers at national and international conferences. Moreover, she has published four national patents and seven books.

Saeed Sahebdelfar

Saeed Sahebdelfar holds a PhD in chemical engineering. He is the head of the Catalysis Research Group at NPC-RT. His research interests include catalysts for hydrogenation-dehydrogenation reactions, chemical fixation of CO2, reactor design, and environmental engineering. He has more than 20 years of experience in the petrochemical industry. To date, he has published or presented more than 100 scientific papers in national and international journals and at national and international conferences.

Samane Komeili

Samane Komeili obtained her PhD in chemical engineering from Iran University of Science and Technology in 2016. She is interested in process modeling and heterogeneous catalysts. Recently, she has done research on the design and application of supported metal catalysts in the fields of selective hydrogenation and selective catalytic reduction. Her special focus is on the synthesis of zeolite and aluminate as the catalyst support. To date, she has published seven scientific papers.

References

Ahn IY, Lee JH, Kum SS, Moon SH. Formation of C4 species in the deactivation of a Pd/SiO2 catalyst during the selective hydrogenation of acetylene. Catal Today 2007; 123: 151–157.10.1016/j.cattod.2007.02.011Suche in Google Scholar

Augustyna WG, McCrindle RI, Coville NJ. The selective hydrogenation of acetylene on palladium-carbon nano-structured catalysts. Appl Catal A G 2010; 388: 1–6.10.1016/j.apcata.2010.07.038Suche in Google Scholar

Bazzazzadegan H, Kazemeini M, Rashidi AM. A high performance multi-walled carbon nanotube-supported palladium catalyst in selective hydrogenation of acetylene-ethylene mixtures. Appl Catal A G 2011; 399: 184–190.10.1016/j.apcata.2011.03.055Suche in Google Scholar

Benavidez AD, Burton PD, Nogales JL, Jenkins AR, Ivanov SA, Miller JT, Karim AM, Datye AK. Improved selectivity of carbon-supported palladium catalysts for the hydrogenation of acetylene in excess ethylene. Appl Catal A G 2014; 482: 108–115.10.1016/j.apcata.2014.05.027Suche in Google Scholar

Bond GC. Metal catalyzed reactions of hydrocarbons, USA: Springer, 2005.Suche in Google Scholar

Borodzinski A. Hydrogenation of acetylene-ethylene mixtures on a commercial palladium catalyst. Catal Lett 1999; 63: 35–42.10.1023/A:1019052618049Suche in Google Scholar

Borodzinski A, Bond GC. Selective hydrogenation of ethyne in ethene-rich streams on palladium catalysts. Part 1: effect of changes to the catalyst during reaction. Catal Rev 2006; 48: 91–144.10.1080/01614940500364909Suche in Google Scholar

Borodziński A, Bond GC. Selective hydrogenation of ethyne in ethene-rich streams on palladium catalysts. Part 2: steady*state kinetics and effects of palladium particle size, carbon monoxide and promoters. Catal Rev 2008; 50: 379–469.10.1080/01614940802142102Suche in Google Scholar

Bos ANR, Westerterp KR. Mechanism and kinetics of the selective hydrogenation of ethyne and ethane. Chem Eng Proc-Proc Int 1993; 32: 1–7.10.1016/0255-2701(93)87001-BSuche in Google Scholar

Burton PD, Boyle TJ, Datye AK. Facile surfactant-free synthesis of Pd nanoparticles for heterogeneous catalysts. J Catal 2011; 280: 145–149.10.1016/j.jcat.2011.03.022Suche in Google Scholar

Chen WS, Wei KM. Single-stage treatment in selective hydrogenation of acetylene over CDS type of Pd-Ag/Al2O3 catalyst. Can J Chem Eng 2004; 82: 1217–1224.10.1002/cjce.5450820609Suche in Google Scholar

Chinayon S, Mekasuwandumrong O, Praserthdam P, Panpranot J. Selective hydrogenation of acetylene over Pd catalysts supported on nanocrystalline α-Al2O3 and Zn-modified α-Al2O3. Catal Commun 2008; 9: 2297–2302.10.1016/j.catcom.2008.03.032Suche in Google Scholar

Coq B, Figueras F. Bimetallic palladium catalysts: influence of the co-metal on the catalyst performance. J Mol Catal A Chem 2001; 173: 117–134.10.1016/S1381-1169(01)00148-0Suche in Google Scholar

Doyle AM, Shaikhutdinov SK, Jackson SD, Freund HJ. Hydrogenation on metal surfaces: why are nanoparticles more active than single crystals. Angew Chem 2003; 42: 5240–5243.10.1002/anie.200352124Suche in Google Scholar

Duca D, Frusteri F, Parmaliana A, Deganello G. Selective hydrogenation of acetylene in ethylene feed-stocks on Pd catalysts. Appl Catal A G 1996; 146: 269–284.10.1016/S0926-860X(96)00145-7Suche in Google Scholar

Duca D, Arena F, Parmaliana A, Deganello G. Hydrogenation of acetylene in ethylene rich feed-stocks: comparison between palladium catalysts supported on pumice and alumina. Appl Catal A G 1998; 172: 207–216.10.1016/S0926-860X(98)00123-9Suche in Google Scholar

Esmaeili E, Rashidi AM, Khodadadi AA, Mortazavi Y, Rashidzadeh M. The role of tin-promoted Pd/MWNTs via the management of carbonaceous species in selective hydrogenation of high concentration acetylene. Appl Surf Sci 2012; 263: 513–522.10.1016/j.apsusc.2012.09.095Suche in Google Scholar

Esmaeili E, Rashidi AM, Khodadadi AA, Mortazavi Y, Rashidzadeh M. SMFs-supported Pd nano-catalysts in selective acetylene hydrogenation: pore structure-dependent deactivation mechanism. J Energ Chem 2013; 22: 717–725.10.1016/S2095-4956(13)60095-9Suche in Google Scholar

Esmaeili E, Rashidi AM, Khodadadi AA, Mortazavi Y, Rashidzadeh M. Palladium-tin nano-catalysts in high concentration acetylene hydrogenation: a novel deactivation mechanism. Fuel Process Technol 2014; 120: 113–122.10.1016/j.fuproc.2013.12.015Suche in Google Scholar

Giannikos A, Petrolekas P, Pliangos C, Frenzel A, Vayenas CG, Piitter H. Electrochemical promotion of Pd for the hydrogenation of C2H2. Ionics 1998; 4: 161–169.10.1007/BF02375941Suche in Google Scholar

Gigola CE, Aduriz HR, Bondaruik P. Particle size effect in the hydrogenation of acetylene under industrial conditions. Appl Catal 1986; 27: 133–144.10.1016/S0166-9834(00)81052-0Suche in Google Scholar

Guczi L. Bimetallic nano-particles: featuring structure and reactivity. Catal Today 2005; 101: 53–64.10.1016/j.cattod.2005.01.002Suche in Google Scholar

Hong J, Chu W, Chen M, Wang X, Zhang T. Preparation of novel titania supported palladium catalysts for selective hydrogenation of acetylene to ethylene. Catal Commun 2007; 8: 593–597.10.1016/j.catcom.2006.08.010Suche in Google Scholar

Huang W, McCormick JR, Lobo RF, Chen JG. Selective hydrogenation of acetylene in the presence of ethylene on zeolite-supported bimetallic catalysts. J Catal 2007a; 246: 40–51.10.1016/j.jcat.2006.11.013Suche in Google Scholar

Huang W, Pyrz W, Lobo RF, Chen JG. Selective hydrogenation of acetylene in the presence of ethylene on K+-β-zeolite supported Pd and Pd-Ag catalysts. Appl Catal A G 2007b; 333: 254–263.10.1016/j.apcata.2007.09.017Suche in Google Scholar

Huang W, Lobo RF, Chen JG. Characterization of Na+-β-zeolite supported Pd and Pd Ag bimetallic catalysts using EXAFS, TEM and flow reactor. J Mol Catal A Chem 2008; 283: 158–165.10.1016/j.molcata.2007.12.017Suche in Google Scholar

Huang W, Lobo RF, Chen JG. Effects of zeolite structures, exchanged cations, and bimetallic formulations on the selective hydrogenation of acetylene over zeolite-supported catalysts. Catal Lett 2009; 130: 380–385.10.1007/s10562-009-9957-3Suche in Google Scholar

Huoli Z, Yuanyi Y, Wei D, Shuliang L, Haibo Y, Yuanyuan J. Size-controlled Pd nanoparticles supported on α-Al2O3 as heterogeneous catalyst for selective hydrogenation of acetylene. Chin J Chem Eng 2014; 22: 516–521.10.1016/S1004-9541(14)60070-7Suche in Google Scholar

Jafari A, Saadatjou N, Sahebdelfar S. Influence of chemical treatments of activated carbon support on the performance and deactivation behaviour of promoted Ru catalyst in ammonia synthesis. Int J Hydrogen Energy 2015; 40: 3659–3671.10.1016/j.ijhydene.2015.01.071Suche in Google Scholar

Jin Y, Datye AK, Rightor E, Gulotty R, Waterman W, Smith M, Holbrook M, Maj J, Blackson J. The influence of catalyst restructuring on the selective hydrogenation of acetylene to ethylene. J Catal 2001; 203: 292–306.10.1006/jcat.2001.3347Suche in Google Scholar

Kang JH, Shin EW, Kim WJ, Park JD, Moon SH. Selective hydrogenation of acetylene on Pd/SiO2 catalysts promoted with Ti, Nb and Ce oxides. Catal Today 2000; 63: 183–188.10.1016/S0920-5861(00)00458-2Suche in Google Scholar

Kang JH, Shin EW, Kim WJ, Duk Park J, Moon SH. Selective hydrogenation of acetylene on TiO2-added Pd catalysts. J Catal 2002; 208: 310–320.10.1006/jcat.2002.3583Suche in Google Scholar

Khan NA, Shaikhutdinov S, Freund HJ. Acetylene and ethylene hydrogenation on alumina supported Pd-Ag model catalysts. Catal Lett 2006; 108: 158–164.10.1007/s10562-006-0041-ySuche in Google Scholar

Kim WJ, Moon SH. Modified Pd catalysts for the selective hydrogenation of acetylene. Catal Today 2012; 185: 2–16.10.1016/j.cattod.2011.09.037Suche in Google Scholar

Kim WJ, Shin EW, Kang JH, Moon SH. Performance of Si-modified Pd catalyst in acetylene hydrogenation: catalyst deactivation behavior. Appl Catal A G 2003; 251: 305–313.10.1016/S0926-860X(03)00367-3Suche in Google Scholar

Kim WJ, Kang JH, Ahn IY, Moon SH. Deactivation behavior of a TiO2-added Pd catalyst in acetylene hydrogenation. J Catal 2004a; 226: 226–229.10.1016/j.jcat.2004.05.017Suche in Google Scholar

Kim WJ, Kang JH, Ahn IY, Moon SH. Effect of potassium addition on the properties of a TiO2-modified Pd catalyst for the selective hydrogenation of acetylene. Appl Catal A G 2004b; 268: 77–82.10.1016/j.apcata.2004.03.025Suche in Google Scholar

Kim SK, Lee JH, Ahn IY, Kim WJ, Moon SH. Performance of Cu-promoted Pd catalysts prepared by adding Cu using a surface redox method in acetylene hydrogenation. Appl Catal A G 2011; 401: 12–19.10.1016/j.apcata.2011.04.048Suche in Google Scholar

Kim E, Shin EW, Bark CW, Chang I, Yoon WJ, Kim WJ. Pd catalyst promoted by two metal oxides with different reducibilities: properties and performance in the selective hydrogenation of acetylene. Appl Catal A G 2014: 471; 80–83.10.1016/j.apcata.2013.11.036Suche in Google Scholar

Komeili S, Takht Ravanchi M, Rahimi Fard M, Taeb A. Effect of Ni-modified alpha alumina on the textural properties as a catalyst support. In: 8th International Chemical Engineering Congress (IChEC 2014), Kish Island, Iran, 24–27 February 2014.Suche in Google Scholar

Komeili S, Takht Ravanchi M, Taeb A. The influence of alumina phases on the performance of the Pd-Ag/Al2O3 catalyst in tail-end selective hydrogenation of acetylene. Appl Catal A G 2015; 502: 287–296.10.1016/j.apcata.2015.06.013Suche in Google Scholar

Komeili S, Takht Ravanchi M, Taeb A. Influence of calcination parameters on the properties of alumina as a catalyst support. Sci Iran C 2016a; 23: 1128–1135.10.24200/sci.2016.3883Suche in Google Scholar

Komeili S, Taeb A, Takht Ravanchi M, Rahimi Fard M. The properties of nickel aluminate nano-particles prepared by sol-gel and impregnation methods. Res Chem Intermed 2016b; 42: 7909–7921.10.1007/s11164-016-2568-xSuche in Google Scholar

Komhom S, Mekasuwandumrong O, Praserthdam P, Panpranot J. Improvement of Pd/Al2O3 catalyst performance in selective acetylene hydrogenation using mixed phases Al2O3 support. Catal Commun 2008a; 10: 86–91.10.1016/j.catcom.2008.07.039Suche in Google Scholar

Komhom S, Peaserthdam P, Mekasuwandumrong O, Panperanot J. Effect of support crystallization size and the reduction temperature on the properties of Pd/α-Al2O3 catalyst in selective acetylene hydrogenation. React Kinet Catal Lett 2008b; 92: 233–241.10.1007/s11144-008-5304-8Suche in Google Scholar

Kontapakdee K, Panpranot J, Praserthdam P. Effect of Ag addition on the properties of Pd-Ag/TiO2 catalysts containing different TiO2 crystalline phases. Catal Commun 2007; 8: 2166–2170.10.1016/j.catcom.2007.03.003Suche in Google Scholar

Kovnir K, Armbruster M, Teschner D, Venkov TV, Szentmiklosi L, Jentoft FC, Knop-Gericke A, Grin Y, Schlogl R. In situ surface characterization of the intermetallic compound Pd-Ga: a highly selective hydrogenation catalyst. Surf Sci 2009; 603: 1784–1792.10.1016/j.susc.2008.09.058Suche in Google Scholar

Lamb RN, Ngamsom B, Trimm DL, Gong B, Silveston PL, Praserthdam P. Surface characterization of Pd-Ag/Al2O3 catalysts for acetylene hydrogenation using an improved XPS procedure. Appl Catal A G 2004; 268: 43–50.10.1016/j.apcata.2004.03.041Suche in Google Scholar

Lee JH, Kim SK, Ahn IY, Kim WJ, Moon SH. Performance of Pd-Ag/Al2O3 catalysts prepared by the selective deposition of Ag onto Pd in acetylene hydrogenation. Catal Commun 2011; 12: 1251–1254.10.1016/j.catcom.2011.04.015Suche in Google Scholar

Lee JH, Kim SK, Ahn IY, Kim WJ, Moon SH. Performance of Ni-added Pd-Ag/Al2O3 catalysts in the selective hydrogenation of acetylene. Kor J Chem Eng 2012; 29: 169–172.10.1007/s11814-011-0170-xSuche in Google Scholar

Leviness S, Nair V, Weiss AH. Acetylene hydrogenation selectivity control on Pd-Cu/Al2O3 catalysts. J Mol Catal 1984; 25: 131–140.10.1016/0304-5102(84)80037-1Suche in Google Scholar

Liu RJ, Crozier PA, Smith CM, Hucul DA, Blackson J, Salaita G. Metal sintering mechanisms and regeneration of palladium/alumina hydrogenation catalysts. Appl Catal A G 2005; 282: 111–121.10.1016/j.apcata.2004.12.015Suche in Google Scholar

Liu X, Li Y, Lee JW, Hong CY, Mou CY, Jang BWL. Selective hydrogenation of acetylene in excess ethylene over SiO2 supported Au-Ag bimetallic catalyst. Appl Catal A G 2012a; 439–440: 8–14.10.1016/j.apcata.2012.06.030Suche in Google Scholar

Liu X, Mou CY, Lee S, Li Y, Secrest J, Jang BWL. Room temperature O2 plasma treatment of SiO2 supported Au catalysts for selective hydrogenation of acetylene in the presence of large excess of ethylene. J Catal 2012b; 285: 152–159.10.1016/j.jcat.2011.09.025Suche in Google Scholar

Mashkovskii IS, Tkachenko OP, Baeva GN, Stakheev AY. New high selectivity hydrogenation catalysts prepared from bimetallic acetate complexes. Kinet Catal 2009; 50: 768–774.10.1134/S0023158409050206Suche in Google Scholar

Mashkovsky IS, Baeva GN, Stakheev A, Vargaftik MN, Kozitsyna N, Moiseev I. Novel Pd-Zn/C catalyst for selective alkyne hydrogenation: evidence for the formation of Pd-Zn bimetallic alloy particles. Mendeleev Commun 2014; 24: 355–357.10.1016/j.mencom.2014.11.015Suche in Google Scholar

McCue AJ, Anderson JA. Recent advances in selective acetylene hydrogenation using palladium containing catalysts. Front Chem Sci Eng 2015; 9: 142–153.10.1007/s11705-015-1516-4Suche in Google Scholar

McCue AJ, McRitchie CJ, Shepherd AM, Anderson JA. Cu/Al2O3 catalysts modified with Pd for selective acetylene hydrogenation. J Catal 2014; 319: 127–135.10.1016/j.jcat.2014.08.016Suche in Google Scholar

McKenna FM, Anderson JA. Selectivity enhancement in acetylene hydrogenation over diphenyl sulphide-modified Pd/TiO2 catalysts. J Catal 2011; 281: 231–240.10.1016/j.jcat.2011.05.003Suche in Google Scholar

McLeod AS, Blackwell R. Monte Carlo simulation of the selective hydrogenation of acetylene. Chem Eng Sci 2004; 59: 4715–4721.10.1016/j.ces.2004.07.086Suche in Google Scholar

Medlin JW, Allendorf MD. Theoretical study of the adsorption of acetylene on the (111) surfaces of Pd, Pt, Ni, and Rh. J Phys Chem B 2003; 107: 217–223.10.1021/jp026555tSuche in Google Scholar

Mekasuwandumrong O, Wongwaranon N, Panpranot J, Praserthdam P. Effect of Ni-modified α-Al2O3 prepared by sol-gel and solvothermal methods on the characteristics and catalytic properties of Pd/α-Al2O3 catalysts. Mater Chem Phys 2008; 111: 431–437.10.1016/j.matchemphys.2008.04.042Suche in Google Scholar

Menezes WG, Altmann L, Zielasek V, Thiel K, Bäumer M. Bimetallic Co-Pd catalysts: study of preparation methods and their influence on the selective hydrogenation of acetylene. J Catal 2013; 300: 125–135.10.1016/j.jcat.2012.12.023Suche in Google Scholar

Mohundro EL. Overview on C2 and C3 selective hydrogenation in ethylene plants. In: 15th Ethylene Produces Conference, New Orleans, LA, March–April 2003.Suche in Google Scholar

Molchanov VV, Chesnokov VV, Buyanov RA, Zaitsev NA, Zaikovskii VI. New catalysts of the metal-filamentary carbon type: from fundamental research to technology. Kinet Catal 2005; 46: 660–668.10.1007/s10975-005-0121-9Suche in Google Scholar

Molnar A, Sarkany A, Varga M. Hydrogenation of carbon-carbon multiple bonds: chemo-, regio- and stereo-selectivity. J Mol Catal A Chem 2001; 173: 185–221.10.1016/S1381-1169(01)00150-9Suche in Google Scholar

Mostoufi N, Ghoorchian A, Sotudeh-Gharebagh R. Hydrogenation of acetylene: kinetic studies and reactor modeling. Int J Chem React Eng 2005; 3: A14.10.2202/1542-6580.1215Suche in Google Scholar

Osswald J. Active-site isolation for the selective hydrogenation of acetylene: the Pd-Ga and Pd-Sn inter-metallic compounds. Ph.D. dissertation. Technischen Universität Berlin, 2006.Suche in Google Scholar

Pachulski A, Schodel R, Claus P. Performance and regeneration studies of Pd-Ag/Al2O3 catalysts for the selective hydrogenation of acetylene. Appl Catal A G 2011; 400: 14–24.10.1016/j.apcata.2011.03.019Suche in Google Scholar

Panpranot J, Nakkararuang L, Ngamsom B, Praserthdam P. Synthesis, characterization and catalytic properties of Pd and Pd-Ag catalysts supported on nano-crystalline TiO2 prepared by the solvothermal method. Catal Lett 2005; 103: 53–58.10.1007/s10562-005-6502-xSuche in Google Scholar

Panpranot J, Kontapakdee K, Praserthdam P. Selective hydrogenation of acetylene in excess ethylene on micron-sized and nano-crystalline TiO2 supported Pd catalysts. Appl Catal A G 2006; 314: 128–133.10.1016/j.apcata.2006.08.024Suche in Google Scholar

Ponec V. Alloy catalysts: the concepts. Appl Catal A G 2001; 222: 31–45.10.1016/S0926-860X(01)00828-6Suche in Google Scholar

Praserthdam P, Phatanasri S, Meksikarin J. Activation of acetylene selective hydrogenation catalysts using oxygen containing compounds. Catal Today 2000a; 63: 209–213.10.1016/S0920-5861(00)00461-2Suche in Google Scholar

Praserthdam P, Phatanasri S, Meksikarin J. Activation of Pd-Ag catalyst for selective hydrogenation of acetylene via nitrous oxide addition. React Kinet Catal Lett 2000b; 70: 125–131.10.1023/A:1010323002181Suche in Google Scholar

Praserthdam P, Ngamsom B, Bogdanchikova N, Phatanasri S, Pramotthana M. Effect of the pretreatment with oxygen and/or oxygen-containing compounds on the catalytic performance of Pd-Ag/Al2O3 for acetylene hydrogenation. Appl Catal A G 2002; 230: 41–51.10.1016/S0926-860X(01)00993-0Suche in Google Scholar

Rahimpour MR, Dehghani O, Gholipour MR, Shokrollahi Yancheshmeh MS, Seifzadeh Haghighi S, Shariati A. A novel configuration for Pd/Ag/α-Al2O3 catalyst regeneration in the acetylene hydrogenation reactor of a multi feed cracker. Chem Eng J 2012; 198–199: 491–502.10.1016/j.cej.2012.06.005Suche in Google Scholar

Riyapan S, Boonyongmaneerat Y, Mekasuwandumrong O, Yoshida H, Fujita SI, Arai M, Panpranot J. Improved catalytic performance of Pd/TiO2 in the selective hydrogenation of acetylene by using H2-treated sol-gel TiO2. J Mol Catal A Chem 2014; 383–384: 182–187.10.1016/j.molcata.2013.12.003Suche in Google Scholar

Riyapan S, Boonyongmaneerat Y, Mekasuwandumrong O, Praserthdam P, Panpranot J. Effect of surface Ti3+ on the sol-gel derived TiO2 in the selective acetylene hydrogenation on Pd/TiO2 catalysts. Catal Today 2015; 245: 134–138.10.1016/j.cattod.2014.07.017Suche in Google Scholar

Saadatjou N, Jafari A, Sahebdelfar S. Synthesis and characterization of Ru/Al2O3 nano-catalyst for ammonia synthesis. Iran J Chem Chem Eng 2015; 34: 1–9.Suche in Google Scholar

Sangkhum T, Mekasuwandumrong O, Praserthdam P, Panpranot J. Effect of Fe-modified α-Al2O3 on the properties of Pd/α-Al2O3 catalysts in selective acetylene hydrogenation. React Kinet Catal Lett 2009; 97: 115–123.10.1007/s11144-009-0010-8Suche in Google Scholar

Sárkány A. Formation of C4 oligomers in hydrogenation of acetylene over Pd/Al2O3 and Pd/TiO2 catalysts. React Kinet Catal Lett 2001; 74: 299–307.10.1023/A:1017945313041Suche in Google Scholar

Sárkány A, Horváth A, Beck A. Hydrogenation of acetylene over low loaded Pd and Pd-Au/SiO2 catalysts. Appl Catal A G 2002; 229: 117–125.10.1016/S0926-860X(02)00020-0Suche in Google Scholar

Sarkany A, Geszti O, Safran G. Preparation of Pd shell-Au core/SiO2 catalyst and catalytic activity for acetylene hydrogenation. Appl Catal A G 2008; 350: 157–163.10.1016/j.apcata.2008.08.012Suche in Google Scholar

Shao L, Zhang W, Armbrster M, Teschner D, Girgsdies F, Zhang B, Timpe O, Friedrich M, Schlçgl R, Su DS. Nano-sizing inter-metallic compounds onto carbon nano-tubes: active and selective hydrogenation catalysts. Angew Chem Int Ed 2011; 50: 10231–10235.10.1002/anie.201008013Suche in Google Scholar PubMed

Sheth PA, Neurock M, Smith CM. First-principles analysis of the effects of alloying Pd with Ag for the catalytic hydrogenation of acetylene-ethylene mixtures. J Phys Chem B 2005; 109: 12449–12466.10.1021/jp050194aSuche in Google Scholar PubMed

Shin EW, Kang JH, Kim WJ, Park JD, Moon SH. Performance of Si-modified Pd catalyst in acetylene hydrogenation: the origin of the ethylene selectivity improvement. Appl Catal A G 2002; 223: 161–172.10.1016/S0926-860X(01)00758-XSuche in Google Scholar

Stammbach MR, Thomas DJ, Trimm DL, Wainwright MS. Hydrogenation of ethyne over an ion-exchanged copper on silica catalyst. Appl Catal 1990; 58: 209–217.10.1016/S0166-9834(00)82290-3Suche in Google Scholar

Takht Ravanchi M, Sahebdelfar S. Palladium as a catalyst for selective hydrogenation: fundamentals and applications, 1st ed., Germany: LAP Lambert Academic Publishing, 2015.Suche in Google Scholar

Takht Ravanchi M, Sahebdelfar S. Pd-Ag/Al2O3 catalyst: stages of deactivation in tail-end acetylene selective hydrogenation. Appl Catal A G 2016; 525: 197–203.10.1016/j.apcata.2016.07.014Suche in Google Scholar

Takht Ravanchi M, FadaeeRayeni S, Rahimi Fard M. Selective hydrogenation of acetylene in the presence of ethylene on Pd-Ag/α-Al2O3 catalyst. In: 8th International Chemical Engineering Congress (IChEC 2014), Kish Island, Iran, 24–27 February 2014a.Suche in Google Scholar

Takht Ravanchi M, Sahebdelfar S, Rahimi Fard M, FadaeeRayeni S. Deactivation behaviour for Pd-Ag/α-Al2O3 catalyst in acetylene selective hydrogenation process. In: XXI International Conference on Chemical Reactors (CHEMREACTOR-21), Delft, Netherlands, 22–25 September 2014b.Suche in Google Scholar

Takht Ravanchi M, FadaeeRayeni S, Rahimi Fard M. An egg-shell Pd-Ag/α-Al2O3 catalyst for tail-end acetylene selective hydrogenation. Iran J Chem Eng 2014c; 11: 42–54.Suche in Google Scholar

Takht Ravanchi M, Rahimi Fard M, FadaeeRayeni S. Effect of liquid-phase reduction on catalytic performance of Pd-Ag/Al2O3 in acetylene selective hydrogenation. In: Achema Congress, Frankfurt am Main, Germany, 15–19 June 2015a.Suche in Google Scholar

Takht Ravanchi M, Rahimi Fard M, FadaeeRayeni S, Yaripour F. Effect of calcination conditions on crystalline structure and pore size distribution for a meso-porous alumina. Chem Eng Commun 2015b; 202: 493–499.10.1080/00986445.2013.850577Suche in Google Scholar

Takht Ravanchi M, FadaeeRayeni S, Rahimi Fard M. The effect of calcination temperature on physicochemical properties of alumina as a support for acetylene selective hydrogenation catalyst. Res Chem Intermed 2016a; 42: 4797–4811.10.1007/s11164-015-2320-ySuche in Google Scholar

Takht Ravanchi M, Sahebdelfar S, Rahimi Fard M, FadaeeRayeni S, Bigdeli P. Pd-Ag/α-Al2O3 catalyst deactivation in acetylene selective hydrogenation process. Chem Eng Technol 2016b; 39: 301–310.10.1002/ceat.201400526Suche in Google Scholar

Takht Ravanchi M, Sahebdelfar S, Rahimi Fard M. Influence of support structural characteristics on long-term performance of Pd-Ag/α-Al2O3 catalyst for tail-end acetylene selective hydrogenation. Int J Chem React Eng 2016c; 14: 1035–1046.10.1515/ijcre-2015-0209Suche in Google Scholar

Toebes ML, Dillen JA, de Jong KP. Synthesis of supported palladium catalysts. J Mol Catal A Chem 2001; 173: 75–98.10.1016/S1381-1169(01)00146-7Suche in Google Scholar

Tribolet P, Kiwi-Minsker L. Palladium on carbon nano-fibers grown on metallic filters as novel structured catalyst. Catal Today 2005; 105: 337–343.10.1016/j.cattod.2005.06.035Suche in Google Scholar

Trimm DL, Liu IOY, Cant NW. The selective hydrogenation of acetylene over a Ni/SiO2 catalyst in the presence and absence of carbon monoxide. Appl Catal A G 2010; 374: 58–64.10.1016/j.apcata.2009.11.030Suche in Google Scholar

Tyurina LA, Nikolaev SA, Gurevich SA, Kozhevin VM, Smirnov VV, Zanaveskin KL. Selective hydrogenation of acetylene on nano-sized catalysts. Catal Ind 2009; 1: 179–183.10.1134/S2070050409030027Suche in Google Scholar

Valcarcel A, Clotet A, Ricart JM, Illas F. Comparative theoretical study of the structure and bonding of propyne on the Pt(1 1 1) and Pd(1 1 1) surfaces. Chem Phys 2005; 309: 33–39.10.1016/j.chemphys.2004.02.024Suche in Google Scholar

Vincent MJ, Gonzalez RD. A Langmuir-Hinshelwood model for a hydrogen transfer mechanism in the selective hydrogenation of acetylene over a Pd/γ-Al2O3 catalyst prepared by the sol-gel method. Appl Catal A G 2001; 217: 143–156.10.1016/S0926-860X(01)00586-5Suche in Google Scholar

Volpe MA, Rodriguez P, Gigola CE. Preparation of Pd-Pb/α-Al2O3 catalysts for selective hydrogenation using PbBu4: the role of metal-support boundary atoms and the formation of a stable surface complex. Catal Lett 1999; 61: 27–32.10.1023/A:1019087814472Suche in Google Scholar

Wehrli JT, Thomas DJ, Wainwright MS, Trimm DL, Cant NW. Selective hydrogenation of propyne over an ion-exchanged copper on silica catalyst. Appl Catal 1990; 66: 199–208.10.1016/S0166-9834(00)81638-3Suche in Google Scholar

Wehrli JT, Thomas DJ, Wainwright MS, Trimm DL, Cant NW. Selective hydrogenation of propyne over supported copper catalysts: influence of support. Appl Catal 1991; 70: 253–262.10.1016/S0166-9834(00)84168-8Suche in Google Scholar

Wehrli JT, Thomas DJ, Wainwright MS, Trimm DL, Cant NW. Selective hydrogenation of C4-acetylenes over an ion-exchanged copper on silica catalyst. Stud Surf Sci Catal 1993; 75: 2289–2292.10.1016/S0167-2991(08)64282-2Suche in Google Scholar

Wilhite BA, McCready MJ, Varma A. Kinetics of phenyl acetylene hydrogenation over Pt/γ-Al2O3 catalyst. Ind Eng Chem Res 2002; 41: 3345–3350.10.1021/ie0201112Suche in Google Scholar

Wongwaranon N, Mekasuwandumrong O, Praserthdam P, Panpranot J. Performance of Pd catalysts supported on nano-crystalline α-Al2O3 and Ni-modified α-Al2O3 in selective hydrogenation of acetylene. Catal Today 2008; 131: 553–558.10.1016/j.cattod.2007.10.036Suche in Google Scholar

Yan X, Wheelea J, Jang B, Lin WY, Zhao B. Stable Au catalysts for selective hydrogenation of acetylene in ethylene. Appl Catal A G 2014; 487: 36–44.10.1016/j.apcata.2014.08.039Suche in Google Scholar

Yarulin AE, Crespo Quesada RM, Egorova EV, Kiwi Minsker LL. Structure sensitivity of selective acetylene hydrogenation over the catalysts with shape controlled palladium nanoparticles. Kinet Catal 2012; 53: 253–261.10.1134/S0023158412020152Suche in Google Scholar

Zea H, Lester K, Datye AK, Rightor E, Gulotty R, Waterman W, Smith M. The influence of Pd-Ag catalyst restructuring on the activation energy for ethylene hydrogenation in ethylene-acetylene mixtures. Appl Catal A G 2005; 282: 237–245.10.1016/j.apcata.2004.12.026Suche in Google Scholar

Zhang Q, Li J, Liu X, Zhu Q. Synergetic effect of Pd and Ag dispersed on Al2O3 in the selective hydrogenation of acetylene. Appl Catal A G 2000; 197: 221–228.10.1016/S0926-860X(99)00463-9Suche in Google Scholar

Zhang Y, Diao W, Williams CT, Monnier JR. Selective hydrogenation of acetylene in excess ethylene using Ag- and Au-Pd/SiO2 bimetallic catalysts prepared by electroless deposition. Appl Catal A G 2014; 469: 419–426.10.1016/j.apcata.2013.10.024Suche in Google Scholar

Zhao L, Wei Z, Zhu M, Dai B. Catalytic performance of a Ti added Pd/SiO2 catalyst for acetylene hydrogenation. J Ind Eng Chem 2012; 18: 45–48.10.1016/j.jiec.2011.11.076Suche in Google Scholar

Zhou T, Jang K, Jang BWL. Ionic liquid and plasma effects on SiO2 supported Pd for selective hydrogenation of acetylene. Catal Today 2013; 211: 147–155.10.1016/j.cattod.2013.02.008Suche in Google Scholar

Received: 2016-8-24
Accepted: 2017-2-7
Published Online: 2017-3-16
Published in Print: 2018-2-23

©2018 Walter de Gruyter GmbH, Berlin/Boston

Heruntergeladen am 16.12.2025 von https://www.degruyterbrill.com/document/doi/10.1515/revce-2016-0036/html
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