Abstract
Cerium sulfide pigments belong to the inorganic orange and red pigments. They were developed to substitute cadmium and lead containing red and orange colored pigments, in particular in plastics. Cerium(III) sulfide exists in three allotropic modifications, but only γ-Ce2S3, which is colored dark red, is suitable for the use as a pigment. Cerium sulfide pigments are characterized by high color strength, strong hiding power and sufficient thermal stability. Their limited stability in water containing systems and in humid atmospheres is not without problems. The pigments tend to degradation in the presence of water or humidity to form hydrogen sulfide, which limits the application possibilities significantly.
References
1. Pfaff G. Inorganic pigments. Berlin/Boston: WalterdeGruyterGmbH; 2017:155.10.1515/9783110484519Suche in Google Scholar
2. Maestro P, Huguenin D. Industrial applications of rare earths: which way for the end of the century? J Alloys Comp. 1995;225:520.10.1016/0925-8388(94)07095-4Suche in Google Scholar
3. Berte J-N. In high performance pigments. Faulkner EB, Schwartz RJ, editors. Weinheim: Wiley-VCH Verlag, 2002;27.10.1002/9783527626915.ch4Suche in Google Scholar
4. Pfaff G. In Winnacker-Küchler: Chemische Technik. In: Dittmeyer R, Keim W, Kreysa G, Oberholz A, editors. Industrieprodukte. vol. 7. 5th ed. Weinheim: Wiley-VCH Verlag, 2004:354.Suche in Google Scholar
5. Julien-Pouzol M, Guittard M. Etude cristallochimique des combinaisons ternaires cuivre-terre rare soufre ou selenium, situees le long des binaires Cu2X-L2X3. Ann Chim. 1972;7:253.10.1002/chin.197236024Suche in Google Scholar
6. Mauricot R, Gressier P, Evain M, Brec R. Comparative study of some rare earth sulfides: doped g-[A]M2S3 (M = La, Ce and Nd, A = Na, K and Ca) and undoped g-M2S3 (M = La, Ce and Nd). J Alloys Comp. 1995;223:130.10.1016/0925-8388(94)01476-0Suche in Google Scholar
7. Laronze H, Demourges A, Tressaud A, Lozano L, Grannec J, Guillen F, Macaudière P, Maestro P. Preparation and characterization of alkali- and alkaline earth-based rare earth sulfides. J Alloys Comp. 1998;275:113.10.1016/S0925-8388(98)00286-2Suche in Google Scholar
8. Cutler M, Leavy J-F. Electronic transport in high-resistivity cerium sulfide. Phys Rev. 1964;133:1153.10.1103/PhysRev.133.A1153Suche in Google Scholar
9. Henderson JR, Muramoto M, Loh M, Gruber JB. Electronic structure of rare-earth sesquisulfide crystals. J Chem Phys. 1967;47:3347.10.1063/1.1712397Suche in Google Scholar
10. Kumta PN, Risbud SH. Rare-earth chalcogenides – an emerging class of optical materials. J Mater Sci. 1994;29:1135.10.1007/BF00975057Suche in Google Scholar
11. Endriss H. Aktuelle anorganische Buntpigmente. Hannover: Vincentz Verlag, 1997:150.Suche in Google Scholar
© 2020 Walter de Gruyter GmbH, Berlin/Boston