Abstract
The chapter summarizes the state of knowledge about a metal transport in two-phase system. The first part of this review focuses on the distribution law and main factors determination in classical solvent extraction (solubility and polarity of the solute, as well as inter- and intramolecules interaction. Next part of the chapter is devoted to the reactive solvent extraction and the molecular modeling requiring knowledge on type of extractants, complexation mechanisms, metals ions speciation and oxidation during complexes forming, and other parameters that enable to understand the extraction process. Also the kinetic data that is needed for proper modeling, simulation and design of processes needed for critical separations are discussed. Extraction at liquid-solid system using solvent impregnated resins is partially identical as in the case of the corresponding solvent extraction, therefore this subject was also presented in all aspects of separation process (equilibrium, mechanism, kinetics).
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Artikel in diesem Heft
- CO2-based hydrogen storage: CO2 hydrogenation to formic acid, formaldehyde and methanol
- Computer analysis of potentiometric data of complexes formation in the solution
- Reactive extraction at liquid–liquid systems
- Grignard Reagents and Iron
- On-chip Wide Range Bidirectional Current Sensor for Li-ion Battery Management System
- Introduction to environmental engineering
- Subthreshold Behaviors of Nanoscale Silicon and Germanium Junctionless Cylindrical Surrounding-Gate MOSFETs