Preparation, characterization, and application of fluorinated acrylate copolymer for the conservation of stone building heritages in Putuo Zongcheng Temple, China

Zhiyong Wu; Chuang Ma; Qinghe Niu; Caiwu Wu; Ye Wang

doi:10.1515/polyeng-2023-0158

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Preparation, characterization, and application of fluorinated acrylate copolymer for the conservation of stone building heritages in Putuo Zongcheng Temple, China

Zhiyong Wu , Chuang Ma , Qinghe Niu , Caiwu Wu und Ye Wang

Veröffentlicht/Copyright: 4. Januar 2024

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Aus der Zeitschrift Journal of Polymer Engineering Band 44 Heft 2

Abstract

To prevent the weathering deterioration of stone building heritages in Putuo Zongcheng Temple, the fluorinated acrylate copolymer was prepared with methyl methacrylate, n-butyl acrylate, and 2,2,3,4,4,4-hexafluorobutyl methacrylate as monomers. The structure and surface morphology of the copolymer were described by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscope (SEM). The antiaging of the copolymer was studied by the ultraviolet aging test; the contact angle and imbibition spontaneous tests were performed to estimate the wettability alteration of the copolymer emulsion. Results show that the fluorinated copolymer with 32.54 % HFMA content possesses optimal aging resistance and superb hydrophobicity. The contact angles of coated samples range from 96.90° to 125.80°. Considering the influence of water on rock weathering, the fluorinated copolymer coating is a potential method to avoid the degrading of stone heritages.

Keywords: fluorinated acrylate copolymer; stone building heritage conservation; contact angle; ultraviolet aging test; Putuo Zongcheng Temple

Corresponding author: Chuang Ma, Department of Chemistry, Hebei Normal University for Nationalities, Chengde, 067000 China; and Universiti Malaysia Pahang Al-Sultan Abdullah, Gambang, 263000 Malaysia, E-mail: machuang0378@126.com

Funding source: School-level Fund Project of Hebei Normal University for Nationalities

Award Identifier / Grant number: (Grant No. QN2019002)

Funding source: the Natural Science Foundation of Hebei Province

Award Identifier / Grant number: (Grant No. E2019101012)

Research ethics: Not applicable.
Author contributions: ZW Methodology; CM Writing - Review & Editing; QN Writing - Original Draft; CW Visualization; YW Formal analysis. The author(s) have accepted responsibility for the entire content of this manuscript and approved its submission.
Competing interests: All other authors state no conflict of interest.
Research funding: This work was sponsored by the School-level Fund Project of Hebei Normal University for Nationalities (Grant No. QN2019002) and the Natural Science Foundation of Hebei Province (Grant No. E2019101012).
Data availability: The raw data can be obtained on request from the corresponding author.

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Received: 2023-07-04

Accepted: 2023-12-19

Published Online: 2024-01-04

Published in Print: 2024-02-26

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Schlagwörter für diesen Artikel

fluorinated acrylate copolymer; stone building heritage conservation; contact angle; ultraviolet aging test; Putuo Zongcheng Temple