Removal of crystal violet from water by poly acrylonitrile-co-sodium methallyl sulfonate (AN69) and poly acrylic acid (PAA) synthetic membranes
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Ely Cheikh S’Id
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Mohamed Degué
Abstract
The current investigation is focused on the removal of crystal violet (CV) from water by adsorption process (bach method). To achieve this purpose, specific membranes were prepared from poly acrylonitrile-co-sodium methallyl sulfonate (AN69) and poly acrylic acid (PAA) blends. The adsorption of CV onto AN69/PAA membranes was studied under various conditions: membrane composition, pH, contact time, initial concentration and temperature. To understand the effect of membrane morphology on adsorption process, scanning electronic microscopy (SEM) was employed to determine the features of section and membrane’s surface. From isotherm results, it was found that: the maximum adsorption capacity Q m was 1250 mg g−1, the Langmuir separation factor R L was lying between 0.33 and 0.76, the Freundlich intensity was higher than Unit (n = 1.25) and the adsorption process follows preferentially the Langmuir model (correlation constant R 2 = 0.99). The mechanism of adsorption is perfectly fitted by pseudo second order. The obtained results tend to confirm that the removal of dye molecules is due to the establishment of strong electrostatic interactions between cationic dye molecules and anionic membrane groups. The high adsorption capacity (1250 mg g−1) for the small dye molecules may open wide opportunities to apply these membranes in the removal of various hazardous pollutants commonly present in water.
Acknowledgments
The authors thank Nouakchott Al-Aasriya University, Mauritania for its support.
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Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: No external funding was received for this investigation.
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Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
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© 2021 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Material Properties
- Dynamic crystallization behavior of PA-12/PP-MWCNT nanocomposites: non-isothermal kinetics approach
- Effect of antiblock and slip additives on the properties of tubular quenched polypropylene film
- A local green composite study: the effect of edible oil on the morphological and mechanical properties of PBS/bentonite composite
- Effect of infill density and pattern on the specific load capacity of FDM 3D-printed PLA multi-layer sandwich
- Improving the rheological properties of water-based calcium bentonite drilling fluids using water-soluble polymers in high temperature applications
- Mechanical, thermal and morphological properties of polyoxymethylene nanocomposite for application in gears of diaphragm gas meters
- Preparation and Assembly
- Capacitive performance of electrochemically deposited Co/Ni oxides/hydroxides on polythiophene-coated carbon-cloth
- Engineering and Processing
- Nano-SiO2/hydroxyethyl cellulose nanocomposite used for 210 °C sedimentation control of petroleum drilling fluid
- Removal of crystal violet from water by poly acrylonitrile-co-sodium methallyl sulfonate (AN69) and poly acrylic acid (PAA) synthetic membranes
Artikel in diesem Heft
- Frontmatter
- Material Properties
- Dynamic crystallization behavior of PA-12/PP-MWCNT nanocomposites: non-isothermal kinetics approach
- Effect of antiblock and slip additives on the properties of tubular quenched polypropylene film
- A local green composite study: the effect of edible oil on the morphological and mechanical properties of PBS/bentonite composite
- Effect of infill density and pattern on the specific load capacity of FDM 3D-printed PLA multi-layer sandwich
- Improving the rheological properties of water-based calcium bentonite drilling fluids using water-soluble polymers in high temperature applications
- Mechanical, thermal and morphological properties of polyoxymethylene nanocomposite for application in gears of diaphragm gas meters
- Preparation and Assembly
- Capacitive performance of electrochemically deposited Co/Ni oxides/hydroxides on polythiophene-coated carbon-cloth
- Engineering and Processing
- Nano-SiO2/hydroxyethyl cellulose nanocomposite used for 210 °C sedimentation control of petroleum drilling fluid
- Removal of crystal violet from water by poly acrylonitrile-co-sodium methallyl sulfonate (AN69) and poly acrylic acid (PAA) synthetic membranes
