Innovative γ rays irradiated styrene butadiene rubber/reclaimed waste tire rubber blends: a comparative study using mechano-chemical and microwave devulcanizing methods
Abstract
Waste tire rubber was comparatively devulcanized by using two-roll mill mechano-chemical and microwave techniques at room temperature. The former technique was performed utilizing tetramethylthiuram disulfide and mercaptobenzothiazole disulfide. The developed devulcanized elastomer was characterized by scanning electron microscopy, chemical soluble fraction indication, and cross-link density determination. The blend was mixed in two roll mills by replacing a portion of virgin styrene-butadiene rubber (SBR) in a common formulation with the devulcanized waste rubber (DWR) product at various ratios, namely 10, 20 and 50 wt%. The morphological micrographs confirmed marked improvement in compatibility between both rubbery materials. The tensile strength and elastic modulus examinations of the fabricated blends ensured successful substitution of the virgin SBR with DWR. The abrasion resistance of SBR proved unaffected by blending with DWR. The compounded blends were subjected to γ rays at different radiation doses elevated up to 200 kGy and comparatively mechanically investigated.
Research funding: The authors would like to thank the financial support from Academy of Scientific Research, Cairo, Egypt for funding this paper as a part of project no. 1439.
References
[1] Adhikari B, De D, Maiti S. Prog. Polym. Sci. 2000, 25, 909–948.10.1016/S0079-6700(00)00020-4Suche in Google Scholar
[2] Hofmann W. Rubber Technology Handbook. Hanser: New York, 1989. Gomes MM. Introdução aos polímeros, elastômeros e borrachas. Rubberpedia: Portal da indústria da borracha [Acesso 2007 Ago 21]. Disponível em: www.rubberpedia.com.Suche in Google Scholar
[3] Novotny DS, Marsh RL, Masters FC, Tally DN. Microwave Devulcanization of Rubber. US patent 4104205, 1978.Suche in Google Scholar
[4] Tyler KA, Cerny GL. Method of Reducing Pollution in Microwave Devulcanization Process. Google Patents, 1984.Suche in Google Scholar
[5] Hunt JR, Hall D. Process for Reclaiming Elastomeric Waste. Google Patents, 1994.Suche in Google Scholar
[6] Hunt JR, Hunt JL. Continuous Vacuum Microwave Rubber Crumb Reclamation Unit. Google Patents, 1996.Suche in Google Scholar
[7] Thostenson E, Chou T-W. Compos. Part A Appl. Sci. Manuf. 1999, 30, 1055–1071.10.1016/S1359-835X(99)00020-2Suche in Google Scholar
[8] Mingos D, Baghurst D. In Microwave-Enhanced Chemistry, Kingston HM, Haswell St. J, Eds., ACS: Washington, DC, 1997, p 33.Suche in Google Scholar
[9] De D, Das A, De D, Dey B, Debnath SC, Roy BC. Eur. Polym. J. 2006, 42, 917–927.10.1016/j.eurpolymj.2005.10.003Suche in Google Scholar
[10] Mohaved SO, Ansarifar A, Nezhad SK, Atharyfar S. Poly. Degrad. Stab. 2015, 111, 114–123.10.1016/j.polymdegradstab.2014.11.003Suche in Google Scholar
[11] De D, De D. Mater. Sci. Appl. 2011, 2, 486.Suche in Google Scholar
[12] Aoudia K, Azem S, Aït Hocine N, Gratton M, Pettarin V, Seghar S. Waste Manage. 2017, 60, 471–481.10.1016/j.wasman.2016.10.051Suche in Google Scholar
[13] Zang Y-H, Muller R, Froelich D. Polymer 1989, 30, 2060–2062.10.1016/0032-3861(89)90294-2Suche in Google Scholar
[14] Isayev A, Kim S, Levin VY. Rubber Chem. Technol. 1997, 70, 194–201.10.5254/1.3538424Suche in Google Scholar
[15] Li Y, Zhao S, Wang Y. J. Polym. Res. 2012, 19, 9864.10.1007/s10965-012-9864-ySuche in Google Scholar
[16] Scuracchio C, Bretas R, Isayev AI. J. Elastom. Plast. 2004, 36, 45–75.10.1177/0095244304039913Suche in Google Scholar
[17] Yashin V, Isayev A. Polymer 2004, 45, 6083–6094.10.1016/j.polymer.2004.06.029Suche in Google Scholar
[18] Movahed SO, Ansarifar A, Zohuri G, Ghaneie N, Kermany Y. J. Elastom. Plast. 2016, 48, 122–144.10.1177/0095244314557975Suche in Google Scholar
[19] Movahed SO, Ansarifar A, Karbalaee S, Far SA. Prog. Rubber Plast. Recycling Technol. 2015, 31, 87–116.10.1177/147776061503100202Suche in Google Scholar
[20] De D, De D, Singharoy G. Polym. Eng. Sci. 2007, 47, 1091–1100.10.1002/pen.20790Suche in Google Scholar
[21] Molanorouzi M, Mohaved SO. Polym. Degrad. Stab. 2016, 128, 115–125.10.1016/j.polymdegradstab.2016.03.009Suche in Google Scholar
[22] Kumnuantip C, Sombatsompop N. Mater. Lett. 2003, 57, 3167–3174.10.1016/S0167-577X(03)00019-3Suche in Google Scholar
[23] Makarov V, Drozdovski V. Re-use of the Amortized Trunks and Waste of Rubber Products Manufacture. Chemistry: Leningard, 1986.Suche in Google Scholar
[24] Makarov VM, Drozdovskiĭ V. Reprocessing of Tyres and Rubber Wastes: Recycling From the Rubber Products Industry. Ellis Horwood, 1991.Suche in Google Scholar
[25] Luo M, Liao X, Liao S, Zhao Y. J. Appl. Polym. Sci. 2013, 129, 2313–2320.10.1002/app.38954Suche in Google Scholar
[26] Duhaime J, Baker WE. Plast. Rubber Compos. Process. Appl. 1991, 15, 87–93.10.1007/BF02273840Suche in Google Scholar
[27] Corley BE, Radusch H-J. J. Macromol. Sci. Part B Phys. 1998, 37, 265–273.10.1080/00222349808220471Suche in Google Scholar
[28] Zurina M, Ismail H, Ratnam C. Polym. Degrad. Stabil. 2006, 91, 2723–2730.10.1016/j.polymdegradstab.2006.04.010Suche in Google Scholar
[29] Hassan MM, Aly RO, El-Ghandour AH, Abdelnaby HA. J. Elastom. Plast. 2013, 45, 77–94.10.1177/0095244312445523Suche in Google Scholar
[30] Karabork F, Akdemir A. J. Appl. Polym. Sci. 2015, 132, 42419(1–9).10.1002/app.42419Suche in Google Scholar
[31] Karger-Kocsis J, Mészáros L, Bárány T. J. Mater. Sci. 2013, 48, 1–38.10.1007/s10853-012-6564-2Suche in Google Scholar
[32] Zanchet A, Carli LN, Giovanela M, Brandalise RN, Crespo JS. Mater. Des. 2012, 39, 437–443.10.1016/j.matdes.2012.03.014Suche in Google Scholar
[33] Garcia PS, Sousa de FDB, Lima de JA. Polym. Lett. 2015, 9, 1015–1026.10.3144/expresspolymlett.2015.91Suche in Google Scholar
©2020 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Material properties
- The effect of unidirectional shear flow-induced orientation on foaming properties of polypropylene
- An investigation on electro-induced shape memory performances of CE/EP/CB/SCF composites applied for deployable structure
- Nanocomposite film with green synthesized TiO2 nanoparticles and hydrophobic polydimethylsiloxane polymer: synthesis, characterization, and antibacterial test
- Preparation and assembly
- Binary solvent systems for durable self-adhesive conductive hydrogels
- Development of surface properties of ultra-high-molecular-weight polyethylene film using side-chain crystalline block copolymers
- Highly porous, fast responding acrylamide hydrogels through emulsion polymerization using coconut oil
- Engineering and processing
- Multizone barrel temperature control of the eccentric rotor extrusion process
- The influence of mold temperature on thermoset in-mold forming
- Innovative γ rays irradiated styrene butadiene rubber/reclaimed waste tire rubber blends: a comparative study using mechano-chemical and microwave devulcanizing methods
- Experimental study on influence of molding parameters on self-reinforcement characteristics of polymer co-injection molding
Artikel in diesem Heft
- Frontmatter
- Material properties
- The effect of unidirectional shear flow-induced orientation on foaming properties of polypropylene
- An investigation on electro-induced shape memory performances of CE/EP/CB/SCF composites applied for deployable structure
- Nanocomposite film with green synthesized TiO2 nanoparticles and hydrophobic polydimethylsiloxane polymer: synthesis, characterization, and antibacterial test
- Preparation and assembly
- Binary solvent systems for durable self-adhesive conductive hydrogels
- Development of surface properties of ultra-high-molecular-weight polyethylene film using side-chain crystalline block copolymers
- Highly porous, fast responding acrylamide hydrogels through emulsion polymerization using coconut oil
- Engineering and processing
- Multizone barrel temperature control of the eccentric rotor extrusion process
- The influence of mold temperature on thermoset in-mold forming
- Innovative γ rays irradiated styrene butadiene rubber/reclaimed waste tire rubber blends: a comparative study using mechano-chemical and microwave devulcanizing methods
- Experimental study on influence of molding parameters on self-reinforcement characteristics of polymer co-injection molding