Spectroscopic characterization and microbial degradation of engineered bio-elastomers from linseed oil
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Rakesh Das
Abstract
The microbial degradation of elastomers synthesized through the cationic polymerization reaction of linseed oil, styrene, and divinylbenzene was investigated by using the Alkaliphilus oremlandii OhILAs strain. In Fourier transform infrared (FTIR) analysis, the bound oil content in the elastomers was found to vary from 29.63 to 45.5 wt%, whereas the percentage of unreacted oil in the elastomers were in the range of 12.9–38 wt%. In 1H nuclear magnetic resonance spectrum analysis, the unreacted oil and unreacted aromatic components in the elastomers were obtained in the ranges of 13.2–39 wt% and 6.8–16 wt%, respectively. The amount of unreacted oil in the elastomers enhanced the percentage of biodegradation, which varied from 26 to 51 wt%. The biodegradation of elastomers was also confirmed by FTIR and scanning electron micrograph analyses.
Acknowledgments
The financial support jointly under the Major Research Project Scheme [F.No.36-251(2008) (SR)] from the University Grant Commission (UGC), New Delhi, India, and from the Technical Education Quality Improvement Project (TEQIP), Government of India, is greatly acknowledged.
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©2015 by De Gruyter
Artikel in diesem Heft
- Frontmatter
- Original articles
- The synthesis of styrene acrylate emulsion and its application in xerographic paper
- Effect of different photoinitiators on the properties of UV-cured electromagnetic shielding composites
- Cationic vinyl monomer-grafted polypropylene preparation and its use as a compatibilizer for polypropylene/poly(vinyl chloride) blends
- Activation energy of copper-induced thermal degradation of chitosan acetate functional groups
- The soluble copolymers of polyalkylthiophenes with different molar ratios of co-mers
- Influence of methyl methacrylate-co-glycidyl methacrylate copolymers on the compatibility, morphology and mechanical properties of poly(butylene terephthalate) and polycarbonate blends
- Mechanical properties and toughening mechanisms of epoxy/graphene nanocomposites
- A process analysis for microchannel deformation and bonding strength by in-mold bonding of microfluidic chips
- Structure and properties of low-isotacticity polypropylene elastomeric fibers prepared by sheath-core bicomponent spinning: effect of localization of high-isotacticity component near the fiber surface
- Spectroscopic characterization and microbial degradation of engineered bio-elastomers from linseed oil
Artikel in diesem Heft
- Frontmatter
- Original articles
- The synthesis of styrene acrylate emulsion and its application in xerographic paper
- Effect of different photoinitiators on the properties of UV-cured electromagnetic shielding composites
- Cationic vinyl monomer-grafted polypropylene preparation and its use as a compatibilizer for polypropylene/poly(vinyl chloride) blends
- Activation energy of copper-induced thermal degradation of chitosan acetate functional groups
- The soluble copolymers of polyalkylthiophenes with different molar ratios of co-mers
- Influence of methyl methacrylate-co-glycidyl methacrylate copolymers on the compatibility, morphology and mechanical properties of poly(butylene terephthalate) and polycarbonate blends
- Mechanical properties and toughening mechanisms of epoxy/graphene nanocomposites
- A process analysis for microchannel deformation and bonding strength by in-mold bonding of microfluidic chips
- Structure and properties of low-isotacticity polypropylene elastomeric fibers prepared by sheath-core bicomponent spinning: effect of localization of high-isotacticity component near the fiber surface
- Spectroscopic characterization and microbial degradation of engineered bio-elastomers from linseed oil
