Startseite Development and characterization of homo, co and terpolyimides based on BPDA, BTDA, 6FDA and ODA with low dielectric constant
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Development and characterization of homo, co and terpolyimides based on BPDA, BTDA, 6FDA and ODA with low dielectric constant

  • Revathi Purushothaman EMAIL logo und I. Mohammed Bilal
Veröffentlicht/Copyright: 21. August 2014
Veröffentlichen auch Sie bei De Gruyter Brill
Manuskript einreichen Informationen für Autor*innen
Journal of Polymer Engineering
Aus der Zeitschrift Journal of Polymer Engineering Band 34 Heft 9

Abstract

Polyimides are a sophisticated family of materials, which cover an exhaustive range of high performance polymers and find applications from aerospace to microelectronics. Microelectronic applications demand low dielectric constant and high performance. Aromatic terpolyimides were synthesized by reacting 3,3′,4,4′-biphenyl tetracarboxylic dianhydride (BPDA), 3,3′,4,4′-benzophenone tetracarboxylic dianhydride (BTDA) and 4,4′-(hexafluoroisopropylidene) diphthalic anhydride (6FDA) with 4,4′-oxydianiline (ODA) by thermal imidization with the view to decrease their dielectric constant without compromising thermal properties and mechanical properties compared to their homo and copolyimides. They were characterized by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and X-ray diffraction (XRD). Their FTIR spectra established formation of polyimide by the characteristic vibrations at 1375 cm-1 (C-N stretch) and 1113 cm-1 (imide ring deformation). The TGA results showed decomposition of imides at about 515°C. The glass transition temperature (Tg) of the polymers varied from 261°C to 281°C. The XRD spectrum of BPDA/BTDA/6FDA-ODA, which contained 50% of 6FDA, showed a broadened envelope with a peak at 16.8° (2θ), illustrating a semicrystalline nature. Incorporation of 6FDA, with a bulky bridging group into the backbone of BPDA/6FDA-ODA and BPDA/BTDA/6FDA-ODA (0.25:0.25:0.5::1) caused a decrease in the dielectric constant (2.13 and 2.38, respectively). Such polyimides can find application in microelectronics such as flexible printed circuits and tape automated bonding applications.

Keywords: 4,4′-(hexafluoroisopropylidene) diphthalic anhydride; 4,4′-oxydianiline; dielectric constant; mechanical properties; terpolyimide
Corresponding author: Revathi Purushothaman, B.S. Abdur Rahman University, G.S.T. Road, Vandalur, Chennai 600 048, India, e-mail:

Acknowledgments

The authors are grateful to B.S. Abdur Rahman University for financial support. The technical support of Mr. Selvam, Anjan Chemicals, for FTIR, Dr. S. Rajendran and Dr. M. S. Pandian, Pondicherry University for XRD, Mr. Rohan Bosale, Hemetek Technologies for tensile properties, Dr. R. Vasanthakumari, B.S. Abdur Rahman University for DSC and TGA, and Dr. V. Geethaguru, Dr. M. Murugan, Mr. K. Gunasekar, Mr. T. Kannakaraj and Mr. R. Tamilselvan, B.S. Abdur Rahman University for their support in fabricating the solution casting machine and thickness measurements are greatly appreciated. Ms. H. Sofia is kindly acknowledged for correcting the English.

References

[1] Ho CW, Chance DA, Bajorek CH, Acosta RE. IBMJ. Res. Dev. 1982, 26, 286–296.Suche in Google Scholar

[2] Chao CC, Scholz KD, Leibovitz J, Cobarruiaz M, Chung CC. IEEE T. Compon. Hybr. 1989, 12, 180–184.Suche in Google Scholar

[3] Ramos MMD. Vacuum 2002, 64, 255–260.10.1016/S0042-207X(01)00332-3Suche in Google Scholar

[4] Kim MH, Lee KW. Met. Mater. Int. 2006, 12, 425–433.Suche in Google Scholar

[5] Barlow F, Lostetter A, Elshabini A. Microelectron. Reliab. 2002, 42, 1091–1099.Suche in Google Scholar

[6] Kamiya S, Furuta H, Omiya M. Surf. Coat. Technol. 2007, 202, 1084–1088.Suche in Google Scholar

[7] Noh BI, Yoon JW, Choi JH, Jung SB. Microelectron. Eng. 2011, 88, 718–723.Suche in Google Scholar

[8] Park J, Mukherjee B, Cho H, Kim S, Pyo S. Synth. Met. 2011, 161, 143–147.Suche in Google Scholar

[9] Lee C, Shul Y, Han H. J. Polym. Sci. B Polym. Phys. 2002, 40, 2190–2198.Suche in Google Scholar

[10] Yang CY, Hsu SLC, Chen JS. J. Appl. Polym. Sci. 2005, 98, 2064–2069.Suche in Google Scholar

[11] Zuo M, Xiang Q, Takeichi T. Polymer 1998, 39, 6883–6889.10.1016/S0032-3861(98)00179-7Suche in Google Scholar

[12] Tsai FY, Harding DR, Chen SH, Blanton TN. Polymer 2003, 44, 995–100.10.1016/S0032-3861(02)00787-5Suche in Google Scholar

[13] Purushothaman R, Bilal IM, Palanichamy M. J. Polym. Res. 2011, 18, 1597–1604.Suche in Google Scholar

[14] Purushothaman R. Ph.D thesis, Anna University, Chennai, India, 2011.Suche in Google Scholar

[15] Harris FW. In Polyimides, Wilson D, Stenzenberger HD, Hergenrother PM, Eds., Blackie & Son Ltd.: Glasgow and London, 1990.Suche in Google Scholar

[16] Wang X, Li YF, Zhang S, Ma T, Shao Y. Eur. Polym. J. 2006, 42, 1229–1239.Suche in Google Scholar

[17] Clair SAK, Clair STL, Winfree WP. Polym. Mater. Sci. Eng. 1988, 59, 28–33.Suche in Google Scholar

[18] Pan H, Pu H, Wan D, Jin M, Chang Z. J. Power Sources 2010, 195, 3077–3083.10.1016/j.jpowsour.2009.11.116Suche in Google Scholar

[19] Xie K, Zhang SY, Liu JG, He MH, Yang SY. J. Polym. Sci., Part A: Polym. Chem. 2001, 39, 2581–2590.Suche in Google Scholar

[20] Yen CT, Chen WC, Liaw DJ, Lu HY. Polymer 2000, 344, 7079–7087.Suche in Google Scholar

[21] Hougham G, Tesoro G, Shaw J. Macromolecules 1994, 27, 3642–3649.10.1021/ma00091a028Suche in Google Scholar

[22] Misra AC, Tesoro G, Hougham G, Pendharkar SM. Polymer 1992, 33, 1078–1082.10.1016/0032-3861(92)90025-RSuche in Google Scholar

[23] Leu TS, Wang CS. Polymer 2002, 43, 7069–7074.10.1016/S0032-3861(02)00530-XSuche in Google Scholar

[24] Brink MH, Brandom DK, Wilkes GL, McGrath JE. Polymer 1994, 35, 5018–5023.10.1016/0032-3861(94)90658-0Suche in Google Scholar

[25] Rogers ME, Brink MH, McGratht JE, Brennan A. Polymer 1993, 34, 849–855.10.1016/0032-3861(93)90373-ISuche in Google Scholar

Received: 2013-8-14
Accepted: 2014-7-6
Published Online: 2014-8-21
Published in Print: 2014-12-1

©2014 by De Gruyter

Artikel in diesem Heft

  1. Frontmatter
  2. Original articles
  3. Curing kinetics of styrene-(ethylene-butylene)-styrene (SEBS) copolymer by peroxides in the presence of co-agents
  4. Synthesis and properties of novel high thermally stable polyimide-chrysotile composites as fire retardant materials
  5. Flame-resistant polymeric composite fibers based on nanocoating flame retardant: thermogravimetric study and production of α-Al2O3 nanoparticles by flame combustion
  6. Mechanical and morphological properties of high density polyethylene and polylactide blends
  7. Synthesis and characterization of magnetic Ni0.3 Zn0.7 Fe2 O4/polyvinyl acetate (PVAC) nanocomposite
  8. Effect of titanium nanofiller on the productivity and crystallinity of ethylene and propylene copolymer
  9. Mechanical properties of potassium hydroxide-pretreated Christmas palm fiber-reinforced polyester composites: characterization study, modeling and optimization
  10. Natural frequency response of laminated hybrid composite beams with and without cutouts
  11. Characterization of C2H2O4 doped PVA solid polymer electrolyte
  12. Development and characterization of homo, co and terpolyimides based on BPDA, BTDA, 6FDA and ODA with low dielectric constant
  13. Highly-filled hybrid composites prepared using centrifugal deposition
  14. Reinforcement of carboxylated acrylonitrile-butadiene rubber (XNBR) with graphene nanoplatelets with varying surface area
  15. Multiple melting behavior of poly(lactic acid)-hemp-silica composites using modulated-temperature differential scanning calorimetry
https://doi.org/10.1515/polyeng-2013-0167
Schlagwörter für diesen Artikel
4,4′-(hexafluoroisopropylidene) diphthalic anhydride; 4,4′-oxydianiline; dielectric constant; mechanical properties; terpolyimide

Artikel in diesem Heft

  1. Frontmatter
  2. Original articles
  3. Curing kinetics of styrene-(ethylene-butylene)-styrene (SEBS) copolymer by peroxides in the presence of co-agents
  4. Synthesis and properties of novel high thermally stable polyimide-chrysotile composites as fire retardant materials
  5. Flame-resistant polymeric composite fibers based on nanocoating flame retardant: thermogravimetric study and production of α-Al2O3 nanoparticles by flame combustion
  6. Mechanical and morphological properties of high density polyethylene and polylactide blends
  7. Synthesis and characterization of magnetic Ni0.3 Zn0.7 Fe2 O4/polyvinyl acetate (PVAC) nanocomposite
  8. Effect of titanium nanofiller on the productivity and crystallinity of ethylene and propylene copolymer
  9. Mechanical properties of potassium hydroxide-pretreated Christmas palm fiber-reinforced polyester composites: characterization study, modeling and optimization
  10. Natural frequency response of laminated hybrid composite beams with and without cutouts
  11. Characterization of C2H2O4 doped PVA solid polymer electrolyte
  12. Development and characterization of homo, co and terpolyimides based on BPDA, BTDA, 6FDA and ODA with low dielectric constant
  13. Highly-filled hybrid composites prepared using centrifugal deposition
  14. Reinforcement of carboxylated acrylonitrile-butadiene rubber (XNBR) with graphene nanoplatelets with varying surface area
  15. Multiple melting behavior of poly(lactic acid)-hemp-silica composites using modulated-temperature differential scanning calorimetry
Jetzt anmelden und 20% sparen
Institutioneller Zugang
Wie funktioniert Authentifizierung?
Haben Sie eine Idee, wie wir unsere Website verbessern können?
Bitte schreiben Sie uns.
© 2025 De Gruyter Brill
Heruntergeladen am 3.12.2025 von https://www.degruyterbrill.com/document/doi/10.1515/polyeng-2013-0167/pdf
Button zum nach oben scrollen