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Synthesis and characterization of magnetic Ni0.3 Zn0.7 Fe2 O4/polyvinyl acetate (PVAC) nanocomposite

  • Fatemeh S. Mohammad Doulabi , Mohsen Mohsennia EMAIL logo and Shervin Taraghikhah
Published/Copyright: August 22, 2014
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Journal of Polymer Engineering
From the journal Journal of Polymer Engineering Volume 34 Issue 9

Abstract

The magnetic Ni0.3 Zn0.7 Fe2 O4 nanoparticles were expected to have wide applications in bionanoscience and electronic devices technology. In this work, Ni0.3 Zn0.7 Fe2 O4 nanoparticles were synthesized successfully by a redox chemical reaction in an aqueous solution of nickel chloride, zinc chloride and ferric chloride. Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD) and scanning electron microscopy (SEM) were used to characterize the shape, structure and size of the synthesized magnetic nanoparticles. The magnetic properties of Ni0.3 Zn0.7 Fe2 O4 nanoparticles were studied using a vibrating sample magnetometer (VSM). The XRD patterns of the synthesized nanoparticles revealed the formation of the single phase spinel structure of the synthesized materials. The synthesized Ni0.3 Zn0.7 Fe2 O4 nanoparticles were used for the preparation of Ni0.3 Zn0.7 Fe2 O4/polyvinyl acetate (PVAC) nanocomposites by an in situ emulsion polymerization method. The synthesized Ni0.3 Zn0.7 Fe2 O4 nanoparticles exhibited superparamagnetic behavior at the room temperature under an applied magnetic field. Magnetization measurements indicated that the saturation magnetization of synthesized Ni0.3 Zn0.7 Fe2 O4/PVAc nanocomposites was markedly less than that of Ni0.3 Zn0.7 Fe2 O4 magnetic nanoparticles.

Keywords: magnetic material; nanocomposite; Ni0.3 Zn0.7 Fe2 O4; spinel; VSM
Corresponding author: Mohsen Mohsennia, Institute of Nanoscience and Nanotechnology, University of Kashan, Kashan, 51167-87317, Iran, e-mail:

References

[1] Chen JP, Sorenson CM, Klabunde KJ, Hadjipanayis GC, Devlin E, Kostikas A. Phys. Rev. B. 1996, 54, 9288–9296.Search in Google Scholar

[2] Costa AC, Silva VJ, Cornejo DR, Morelli MR, Kiminami RH, Gama L. J. Magn. Magn. Mater. 2008, 320, 370–372.Search in Google Scholar

[3] El-Sayed AM. Ceram. In. 2002, 28, 363–367.Search in Google Scholar

[4] Grimal V, Autissier D, Longuet L, Pascard H, Gervais M. J. Eur. Ceram. Soc. 2006, 26, 3687–3693.Search in Google Scholar

[5] Janghorban K, Shokrollahi H. J. Magn. Magn. Mater. 2007, 308, 238–242.Search in Google Scholar

[6] Komarmeni S. J. Mater. Chem.1992, 2, 1219–1230.Search in Google Scholar

[7] Li X, Wang G. J. Magn. Magn. Mater. 2009, 321, 1276–1279.Search in Google Scholar

[8] Liu H, Xu F, Li L, Wang Y, Qiu H. React. Funct. Polym. 2009, 69, 43–47.Search in Google Scholar

[9] Mathew DS, Juang RS. Chem. Eng. J. 2007, 129, 51–65.Search in Google Scholar

[10] Matsumoto M, Miyata Y. J. Appl. Phys. 2002, 91, 9635–9645.Search in Google Scholar

[11] Mohsen-Nia M, Mohammad Doulabi FS. J. Polym. Plast. Technol. Eng. 2012, 51, 1–5.Search in Google Scholar

[12] Mohsen-Nia M, Mohammad Doulabi FS. Polym. Bull. 2011, 66, 1255–1265.Search in Google Scholar

[13] Morrison SA, Cahill CL, Carpenter EE, Calvin S, Swaminathan R, McHenry ME, Harris VG. J. Appl. Phys. 2004, 95, 6392–6405.Search in Google Scholar

[14] Popplewell J, Sakhnini L. J. Magn. Magn. Mater. 1995, 149, 72–78.Search in Google Scholar

[15] Prakash C, Baijal JS. Solid State Commun. 1984, 50, 557–559.Search in Google Scholar

[16] Shobana MK, Rajendran V, Jeyasubramanian K, Suresh Kumar N. Mater. Lett. 2007, 61, 2616–2619.Search in Google Scholar

[17] Vestal CR, Zhang ZJ. Nano Lett. 2003, 3, 1739–1743.Search in Google Scholar

[18] Wu KH, Yu CH, Chang YC, Horng DN. J. Solid State Chem. 2004, 177, 4119–4125.Search in Google Scholar

[19] Wu KH, Yu CH, Chang YC, Wang GP. J. Magn. Magn. Mater. 2004, 269, 150–155.Search in Google Scholar

Received: 2013-10-18
Accepted: 2014-7-14
Published Online: 2014-8-22
Published in Print: 2014-12-1

©2014 by De Gruyter

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https://doi.org/10.1515/polyeng-2013-0268
Keywords for this article
magnetic material; nanocomposite; Ni0.3 Zn0.7 Fe2 O4; spinel; VSM

Articles in the same Issue

  1. Frontmatter
  2. Original articles
  3. Curing kinetics of styrene-(ethylene-butylene)-styrene (SEBS) copolymer by peroxides in the presence of co-agents
  4. Synthesis and properties of novel high thermally stable polyimide-chrysotile composites as fire retardant materials
  5. Flame-resistant polymeric composite fibers based on nanocoating flame retardant: thermogravimetric study and production of α-Al2O3 nanoparticles by flame combustion
  6. Mechanical and morphological properties of high density polyethylene and polylactide blends
  7. Synthesis and characterization of magnetic Ni0.3 Zn0.7 Fe2 O4/polyvinyl acetate (PVAC) nanocomposite
  8. Effect of titanium nanofiller on the productivity and crystallinity of ethylene and propylene copolymer
  9. Mechanical properties of potassium hydroxide-pretreated Christmas palm fiber-reinforced polyester composites: characterization study, modeling and optimization
  10. Natural frequency response of laminated hybrid composite beams with and without cutouts
  11. Characterization of C2H2O4 doped PVA solid polymer electrolyte
  12. Development and characterization of homo, co and terpolyimides based on BPDA, BTDA, 6FDA and ODA with low dielectric constant
  13. Highly-filled hybrid composites prepared using centrifugal deposition
  14. Reinforcement of carboxylated acrylonitrile-butadiene rubber (XNBR) with graphene nanoplatelets with varying surface area
  15. Multiple melting behavior of poly(lactic acid)-hemp-silica composites using modulated-temperature differential scanning calorimetry
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