Modeling Reaction Kinetics of Twin Polymerization via Differential Scanning Calorimetry

References

[1] S. Grund, P. Kempe, G. Baumann, A. Seifert and S. Spange, Zwillingspolymerisation: ein Weg zur Synthese von Nanokompositen, Angew. Chem. 119 (2007), no. 4, 636–640.10.1002/ange.200504327Suche in Google Scholar

[2] T. Ebert, A. Seifert and S. Spange, Twin polymerization – a new principle for hybrid material synthesis, Macromol. Rapid Commun. 36 (2015), 1623–1639, DOI: 10.1002/marc.201500182.Suche in Google Scholar PubMed

[3] S. Spange and S. Grund, Nanostructured organic–inorganic composite materials by twin polymerization of hybrid monomers, Adv. Mater. 21 (2009), 2111–2116.10.1002/adma.200802797Suche in Google Scholar

[4] T. Ebert, G. Cox, E. Sheremet, O. Gordan, D. R. T. Zahn, F. Simon, et al., Carbon/carbon nanocomposites fabricated by base catalyzed twin polymerization of a si-spiro compound on graphite sheets, Chem. Commun. (Cambrigde, U.K.) 48 (2012), 9867–9869.10.1039/c2cc34775jSuche in Google Scholar PubMed

[5] P. Kempe, T. Löschner, A. A. Auer, A. Seifert, C. Gerhard and S. Spange, Thermally induced twin polymerization of 4h-1,3,2-benzodioxasilines, Chem. Eur. J. 20 (2014), 8040–8053. Includes supporting files via http://dx.doi.org/10.1002/chem.201400038.10.1002/chem.201400038Suche in Google Scholar PubMed

[6] S. Spange, P. Kempe, A. Seifert, A. A. Auer, P. Ecorchard, H. Lang, et al., Nanocomposites with sturcture domains of 0.5 to 3 nm by polymerization of silicon spiro compounds, Angew. Chem., Int. Ed. Engl. 48 (2009), no. 44, 8254–8258.10.1002/anie.200901113Suche in Google Scholar PubMed

[7] J. Brückner, S. Thieme, F. Böttger-Hiller, I. Bauer, H. T. Grossmann, P. Strubel, et al., Carbon-based anodes for lithium sulfur full cells with high cycle stability, Adv. Funct. Mater. 24 (2014), 1284–1289.10.1002/adfm.201302169Suche in Google Scholar

[8] P. Kitschke, A. A. Auer, T. Löschner, A. Seifert, S. Spange, T. Rüffner, et al., Microporous carbon and mesoporous silica by use of twin polymerization: an integrated experimental and theoretical approach to precursor reactivity, ChemPlusChem 79 (2014), no. 7, 1009–1023.10.1002/cplu.201402029Suche in Google Scholar

[9] P. Kempe, T. Löschner, D. Adner and S. Spange, Selective ring opening of 4H-1,3,2-benzodioxasiline twin monomers, New J. Chem. 35 (2011), no. 12, 2735–2739.10.1039/c1nj20654kSuche in Google Scholar

[10] T. Löschner, A. Mehner, S. Grund, A. Seifert, A. Pohlers, A. Lange, et al., Ansatz, Herstellung, Hybridmaterialien, Zwillingspolymerisation (see: “Ein modularer Ansatz zur gezielten Herstellung nanostrukturierter Hybridmaterialien: die simultane Zwillingspolymerisation”), Angew. Chem. 124 (2012), no. 13, 3312–3315.10.1002/ange.201108011Suche in Google Scholar

[11] A. Richter, Berechnung, Spirosiliciumzwillingsmonomeren (see “Quantenchemische Berechnung zu Spirosiliciumzwillingsmonomeren”), Diploma thesis, TU Chemnitz, 09107 Chemnitz, July 2010.Suche in Google Scholar

[12] A. A. Auer, A. Richter, A. V. Berezkin, D. V. Guseva and S. Spange, Theoretical study of twin polymerization – from chemical reactivity to structure formation, Macromol. Theory Simul. 21 (2012), no. 9, 615–628.10.1002/mats.201200036Suche in Google Scholar

[13] I. Tchernook, J. Prehl and J. Friedrich, Quantum chemical investigation of the counter anion in the acid catalyzed initiation of 2,2’-spirobi[4h-1,3,2-benzodioxasiline] polymerization, Polymer 60 (2015), 241–251.10.1016/j.polymer.2015.01.042Suche in Google Scholar

[14] J. Prehl, T. Schönfelder, J. Friedrich and K. H. Hoffmann, Site dependent atom type ReaxFF for the proton-catalyzed twin polymerization, J. Phys. Chem. C 121 (2017), no. 29, 15984–15992.10.1021/acs.jpcc.7b03219Suche in Google Scholar

[15] K. H. Hoffmann and J. Prehl, Modeling the structure formation process of twin polymerization, Reac. Kinet. Mech. Cat. 123 (2018), 367–383.10.1007/s11144-017-1303-ySuche in Google Scholar

[16] M. Abd-Elghany, T. M. Klapötke, A. Elbeih and S. Zeman, Investigation of different thermal analysis techniques to determine the decomposition kinetics of ϵ-2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane with reduced sensitivity and its cured pbx, J. Anal. Appl. Pyrolysis 126 (2017), 267–274.10.1016/j.jaap.2017.05.020Suche in Google Scholar

[17] A. Fernández, M. Ruiz-Bermejoa and J. L. de la Fuente, Modelling the kinetics and structural property evolution of a versatile reaction: aqueous HCN polymerization, Phys. Chem. Chem. Phys. 20 (2018) 17353–17366, DOI: 10.1039/C8CP01662C.Suche in Google Scholar PubMed

[18] G. Gee and H. W. Melville, The kinetics of polymerization reactions, Rubber Chem. Technol. 18 (1945), no. 2, 223–235.10.5254/1.3546722Suche in Google Scholar

[19] P. J. Flory, Principles of Polymer Chemistry, Cornell University Press, Ithaca, NY, 1953.Suche in Google Scholar

[20] V. I. Irzhak, M. L. Tai, N. I. Peregudov and T. F. Irzhak, Concept of bond blocks in the kinetics of polycondensation processes, Colloid Polym. Sci. 272 (1994), 523–529.10.1007/BF00653216Suche in Google Scholar

[21] F. R. Mayo and F. M. Lewis, Copolymerization. i. A basis for comparing the behavior of monomers in copolymerization; the copolymerization of styrene and methyl methacrylate, J. Am. Chem. Soc. 66 (1944), no. 9, 1594–1601.10.1021/ja01237a052Suche in Google Scholar

[22] A. G. Mikos, C. G. Takoudis and N. A. Peppas, Kinetic modeling of copolymerization/cross-linking reactions, Macromolecules 19 (1986), 2174–2182.10.1021/ma00162a012Suche in Google Scholar

[23] F. T. Özaltin, B. Dereli, Ö. Karahan, S. Salman and V. Aviyente, Solvent effects on free-radical copolymerization of styrene and 2-hydroxyethyl methacrylate: a dft study, New J. Chem. 38 (2014), 170–178.10.1039/C3NJ00820GSuche in Google Scholar

[24] S. R. Logan, The origin and status of the arrhenius equation, J. Chem. Educ. 59 (1982), no. 4, 279–281.10.1021/ed059p279Suche in Google Scholar