Corrosion study of 430 stainless steel with cobalt electrodeposited obtained from the recycling of Li-ion batteries

Hosane A. Taroco; Sicele L. A. Gonçalves; Eric M. Garcia; Cristiane G. Taroco; Julio O. F. Melo; Amauri G. Souza

doi:10.1515/ijmr-2022-0263

Artikel

Corrosion study of 430 stainless steel with cobalt electrodeposited obtained from the recycling of Li-ion batteries

Hosane A. Taroco , Sicele L. A. Gonçalves , Eric M. Garcia , Cristiane G. Taroco , Julio O. F. Melo und Amauri G. Souza

Veröffentlicht/Copyright: 16. November 2022

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Aus der Zeitschrift International Journal of Materials Research Band 113 Heft 12

Abstract

In this paper an interesting alternative for recycling of Li-ion battery cathode and and improving the corrosion resistance of 430 stainless steel is presented. The spent cathode composition has molecular formula approximately LiCoO₂. The cobalt electrodeposition onto 430 SS was performed using the cobalt bath obtained by spent LiCoO₂ lixiviation. In air atmosphere and high temperatures the metallic cobalt is transformed into a Co₃O₄ layer that acts as protection against chromium volatilization. This was confirmed by energy-dispersive X-ray spectroscopy and scanning eletron microscopy measurements. Electrochemical impedance spectroscopy measurements, in 0.5 M H₂SO₄ after thermal treatment at 600, 700 and 800 °C show that the cobalt electrodeposition is efficient in mitigating the effects of corrosion when 430 stainless steel is subjected to high temperatures.

Keywords: Cobalt; Corrosion; Electrodeposition; Li-ion batteries; Recycling

Corresponding author: Eric M. Garcia, University of São João Del Rei – Sete Lagoas Campus / DECEB, Sete Lagoas-MG, 35701-970, Brazil, E-mail: eric@ufsj.edu.br

Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: This work was supported by CNPq, Federal University of São João Del Rei UFSJ/Sete Lagoas/DECEB, Multicenter Graduate Program in Chemistry (PPGMQ) and Minas Gerais Chemistry Network (Rede Mineira de Química).
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2022-06-03

Accepted: 2022-07-13

Published Online: 2022-11-16

Published in Print: 2022-12-16

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Artikel in diesem Heft

https://doi.org/10.1515/ijmr-2022-0263

Schlagwörter für diesen Artikel

Cobalt; Corrosion; Electrodeposition; Li-ion batteries; Recycling