Transesterification of Castor Oil with Methanol – Kinetic Modelling
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Payal Chaudhary
und
V. K. Gupta
Abstract
In this research work, transesterification of castor oil with methanol and sulphuric acid catalyst has been carried out in a lab reactor of capacity 500 mL at various operating conditions (reaction temperature=35–65°C, pressure=1 atm, methanol/oil ratio=6:1 and 600 rpm). The effect of reaction temperature is considered, followed by the determination of kinetics of the production of biodiesel. Experimental results have been analysed with respect to three types of reaction kinetics, namely first-order irreversible reaction, second-order irreversible reaction and reversible reaction. For each of the schemes, the activation energy and Arrhenius constants were determined. The experimental data fits very well to second-order reversible reaction kinetics. Properties of fatty acid methyl ester (biodiesel) produced from castor oil have been experimentally determined and compared with standard values as given in EN 14214 norms.
Funding statement: Funding: The authors are thankful to Ministry of Human Resources and Development, Govt. of India, New Delhi, for providing financial support to this work.
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©2015 by De Gruyter
Artikel in diesem Heft
- Frontmatter
- Research Articles
- Transesterification of Castor Oil with Methanol – Kinetic Modelling
- Hybrid Particle Swarm Optimization and Ant Colony Optimization Technique for the Optimal Design of Shell and Tube Heat Exchangers
- Determination of Enthalpy of Pyrolysis from DSC and Industrial Reactor Data: Case of Tires
- Modeling of a UASB Reactor by NARX Networks for Biogas Production
- Optimization of Biodiesel Ultrasound-Assisted Synthesis from Castor Oil Using Response Surface Methodology (RSM)
- Review
- Diglycolamide-Based Solvent Systems in Room Temperature Ionic Liquids for Actinide Ion Extraction: A Review
Artikel in diesem Heft
- Frontmatter
- Research Articles
- Transesterification of Castor Oil with Methanol – Kinetic Modelling
- Hybrid Particle Swarm Optimization and Ant Colony Optimization Technique for the Optimal Design of Shell and Tube Heat Exchangers
- Determination of Enthalpy of Pyrolysis from DSC and Industrial Reactor Data: Case of Tires
- Modeling of a UASB Reactor by NARX Networks for Biogas Production
- Optimization of Biodiesel Ultrasound-Assisted Synthesis from Castor Oil Using Response Surface Methodology (RSM)
- Review
- Diglycolamide-Based Solvent Systems in Room Temperature Ionic Liquids for Actinide Ion Extraction: A Review
