Potentiometric Selectivity Coefficients of Ion-Selective Electrodes
Highlights from Pure and Applied Chemistry
Potentiometric Selectivity Coefficients of Ion-Selective Electrodes
Part II. Inorganic Anions (IUPAC Technical Report)
by Y. Umezawa, K. Umezawa, P. Bühlmann, N. Hamada, H. Aoki, J. Nakanishi, M. Sato, K. P. Xiao, and Y. Nishimura
Pure and Applied Chemistry, Vol. 74, No. 6, pp. 923-994 (2002)
Part III. Organic Ions (IUPAC Technical Report)
by Y. Umezawa, P. Bühlmann, K. Umezawa, and N. Hamada
Pure and Applied Chemistry, Vol. 74, No. 6, pp. 995-1099 (2002)
An earlier IUPAC data compilation of potentiometric selectivity coefficients, K(A,B)pot, for ion-selective electrodes (ISEs) was published in 1979 (Pure Appl. Chem. 51, 1913-1980 [1979]). It covered data reported from 1966 to 1977 and was later followed by another extensive compilation of such data in a handbook from CRC Press (Y. Umezawa [ed.], Handbook of Ion-Selective Electrodes: Selectivity Coefficients, CRC Press, Boca Raton, FL [1990]). The latter covered most of the K(A,B)pot data reported from 1966 to 1988. An updated compilation produced in 1998 was limited to a number of particularly selective ionophores (P. Bühlmann et al., Chem. Rev. 98, 1593-1687 [1998]). Very recently, a data compilation of selectivity coefficients for ionophore-based cation-selective electrodes was published as part I of this series (Pure Appl. Chem.72, 1851-2082 [2000]).
These two most recent reports compile the latest K(A,B)pot data for liquid-membrane ISEs for inorganic-anions (part II) and organic ions (part III) based on neutral and charged ionophores, reported between 1989 and the end of 1998. Moreover, this new compilation also contains some older data that had not been included in the CRC handbook. The presented K(A,B)pot data are listed together with the methods and conditions for their determinations; also tabulated are response slopes, linear concentration (activity) ranges, chemical compositions, and ionophore structures for the corresponding ISE membranes. Selectivity coefficients can be measured with different methods that fall into two main groups, namely (1) mixed solution methods, and (2) separate solution methods. The details of the definition of each method have been briefly discussed in the first part of this series.
© 2014 by Walter de Gruyter GmbH & Co.
Artikel in diesem Heft
- Contents
- What Lies Ahead for the Union
- PEDECIBA–Programa de DEsarrollo de CIencias BAsicas
- Scientific and Technical Information
- Macromolecular Nomenclature and Terminolo
- Aligning the Revised Red and Blue Books and Preparing for IUPAC Preferred Names
- The Address is www.iupac.org
- Dana Knox Receives the Franzosini Award
- New SIT Software Makes Speciation Calculations Easier
- Recommendations for NMR Measurements of High pK Values and Equilibrium Constants in Strongly Basic Solutions
- Performance Evaluation Criteria for Preparation and Measurement of Macroand Microfabricated Ion-Selective Electrodes
- New Solubility Data Projects
- Concepts and Structure for Requests in Clinical Laboratories
- Properties and Units for Transfusion Medicine and Immunohaematology
- Global Use of the C-NPU Concept System for Properties in Toxicology
- Definitions Relating to Stereochemically Asymmetric Polymerizations (IUPAC Recommendations 2001)
- Potentiometric Selectivity Coefficients of Ion-Selective Electrodes
- Provisional Recommendations
- The Science of Sweeteners
- Ionic Poylmerization
- Green Chemistry in Africa
- Vermeer's Camera: Uncovering the Truth Behind the Masterpieces
- Bioinformatics 2002: North-South Networking
- CHEMRAWN XIV Follows Up With Green Chemistry Activities
- Functional π-Electron Systems
- Organic Synthesis
- Solubility Phenomena–Application for Environmental Improvement
- Physical Organic Chemistry
- 11th International Conference on Polymer Characterization (POLYCHAR-11) 6-10 January 2003, Denton, Texas, USA
- 6th Annual UNESCO School & IUPAC Conference on Polymer Properties 14-17 April 2003, Mpumalanga, South Africa
- International Symposium on Ionic Polymerization 30 June-4 July 2003, Boston, USA
- 22nd Discussion Conference of P.M.M. on Spectroscopy of Partially Ordered Macromolecular Systems 21–24 July 2003, Prague, Czech Republic
- Calendar of IUPAC Sponsored Conferences
Artikel in diesem Heft
- Contents
- What Lies Ahead for the Union
- PEDECIBA–Programa de DEsarrollo de CIencias BAsicas
- Scientific and Technical Information
- Macromolecular Nomenclature and Terminolo
- Aligning the Revised Red and Blue Books and Preparing for IUPAC Preferred Names
- The Address is www.iupac.org
- Dana Knox Receives the Franzosini Award
- New SIT Software Makes Speciation Calculations Easier
- Recommendations for NMR Measurements of High pK Values and Equilibrium Constants in Strongly Basic Solutions
- Performance Evaluation Criteria for Preparation and Measurement of Macroand Microfabricated Ion-Selective Electrodes
- New Solubility Data Projects
- Concepts and Structure for Requests in Clinical Laboratories
- Properties and Units for Transfusion Medicine and Immunohaematology
- Global Use of the C-NPU Concept System for Properties in Toxicology
- Definitions Relating to Stereochemically Asymmetric Polymerizations (IUPAC Recommendations 2001)
- Potentiometric Selectivity Coefficients of Ion-Selective Electrodes
- Provisional Recommendations
- The Science of Sweeteners
- Ionic Poylmerization
- Green Chemistry in Africa
- Vermeer's Camera: Uncovering the Truth Behind the Masterpieces
- Bioinformatics 2002: North-South Networking
- CHEMRAWN XIV Follows Up With Green Chemistry Activities
- Functional π-Electron Systems
- Organic Synthesis
- Solubility Phenomena–Application for Environmental Improvement
- Physical Organic Chemistry
- 11th International Conference on Polymer Characterization (POLYCHAR-11) 6-10 January 2003, Denton, Texas, USA
- 6th Annual UNESCO School & IUPAC Conference on Polymer Properties 14-17 April 2003, Mpumalanga, South Africa
- International Symposium on Ionic Polymerization 30 June-4 July 2003, Boston, USA
- 22nd Discussion Conference of P.M.M. on Spectroscopy of Partially Ordered Macromolecular Systems 21–24 July 2003, Prague, Czech Republic
- Calendar of IUPAC Sponsored Conferences
