Volume 40, Issue 1

In the production of ethanol, starches are converted into reducing sugars by liquefaction and saccharification processes, which mainly use soluble amylases. These processes are considered wasteful operations as operations to recover the enzymes are not practical economically so immobilizations of amylases to perform both processes appear to be a promising way to obtain more stable and reusable enzymes, to lower costs of enzymatic conversions, and to reduce enzymes degradation/contamination. Although many reviews on enzyme immobilizations are found, they only discuss immobilizations of α-amylase immobilizations on nanoparticles, but other amylases and support types are not well informed or poorly stated. As the knowledge of the developed supports for most amylase immobilizations being used in starch hydrolysis is important, a review describing about their preparations, characteristics, and applications is herewith presented. Based on the results, two major groups were discovered in the last 20 years, which include conventional and magnetic-based supports. Furthermore, several strategies for preparation and immobilization processes, which are more advanced than the previous generation, were also revealed. Although most of the starch hydrolysis processes were conducted in batches, opportunities to develop continuous reactors are offered. However, the continuous operations are difficult to be employed by magnetic-based amylases.

Metals (Ms) and metal oxides (MOs) possess a strong tendency to coordinate and combine with organic polymers to form respective metal–polymer frameworks (MPFs) and metal oxide polymer frameworks (MOPFs). MPFs and MOPFs can be regarded as composites of organic polymers. MPFs and MOPFs are widely used for industrial and biological applications including as anticorrosive materials in the aqueous phase as well as in the coating conditions. The presence of the Ms and MOs in the polymer coatings improves the corrosion inhibition potential of MPFs and MOPFs by improving their self-healing properties. The Ms and MOs fill the micropores and cracks through which corrosive species such as water, oxygen, and corrosive ions and salts can diffuse and destroy the coating structures. Therefore, the Ms and MOs enhance the durability as well as the effectiveness of the polymer coatings. The present review article is intended to describe the corrosion inhibition potential of some MPFs and MOPFs of some most frequently utilized transition metal elements such as Ti, Si, Zn, Ce, Ag, and Au. The mechanism of corrosion inhibition of MPFs and MOPFs is also described in the presence and absence of metal and metal oxides.

Methyl orange (MO) is a highly carcinogenic and harmful contaminant, which has been extensively reported for its detrimental impact on human and aquatic life. The photodegradation of MO into less toxic products has gained much attention over the past few decades. Herein we have reviewed the recent advancement in designing of nanomaterials (NMs) stabilized on different fabricating assemblies and their application in photocatalysis of MO dye. These photocatalytic systems possess various advantages and disadvantages. Graphene-based supported materials on different NMs are highly reported photocatalysts for photocatalysis of MO dye. Recent advancement, parameters affecting photocatalytic studies, kinetics and photocatalytic mechanism of MO have been thoroughly explained in this review. Future outcomes are also provided for extending the development of scientific research in this field.

Membrane-aerated biofilm reactor (MABR) has been considered as an innovative technology to solve aeration issues in conventional bioreactors. MABR uses a membrane to supply oxygen to biofilm grown on the membrane surface. MABR can perform bubbleless aeration with high oxygen transfer rates, which can reduce energy requirements and expenses. In addition, a unique feature of counter-diffusion creates a stratified biofilm structure, allowing the simultaneous nitrification–denitrification process to take place in a single MABR. Controlling the biofilm is crucial in MABR operation, since its thickness significantly affects MABR performance. Several approaches have been proposed to control biofilm growth, such as increasing shear stress, adding chemical agents (e.g., surfactant), using biological predators to suppress microorganism growth, and introducing ultrasound cavitation to detach biofilm. Several studies also showed the important role of membrane properties and configuration in biofilm development. In addition, MABR demonstrates high removal rates of pollutants in various wastewater treatments, including in full-scale plants. This review presents the basic principles of MABR and the effect of operational conditions on its performance. Biofilm formation, methods to control its thickness, and membrane materials are also discussed. In addition, MABR performance in various applications, full-scale MBRs, and challenges is summarized.

Glucose sensing devices have experienced significant progress in the last years in response to the demand for cost-effective monitoring. Thus, research efforts have been focused on achieving reliable, selective, and sensitive sensors able to monitor the glucose level in different biofluids. The development of enzyme-based devices is challenged by poor stability, time-consuming, and complex purification procedures, facts that have given rise to the synthesis of enzyme-free sensors. Recent advances focus on the use of different components: metal-organic frameworks (MOFs), carbon nanomaterials, or metal oxides. Motivated by this topic, several reviews have been published addressing the sensor materials and synthesis methods, gathering relevant information for the development of new nanostructures. However, the abundant information has not concluded yet in commercial devices and is not useful from an engineering point of view. The dependence of the electrode response on its physico-chemical nature, which would determine the selection and optimization of the materials and synthesis method, remains an open question. Thus, this review aims to critically analyze from an engineering vision the existing information on non-enzymatic glucose electrodes; the analysis is performed linking the response in terms of sensitivity when interferences are present, stability, and response under physiological conditions to the electrode characteristics.