Band 36, Heft 7

Porous carbon materials attract great interest because of the wide range of applications in electrochemical energy systems, especially in the case of structured and porosity-tuned carbons prepared by template-assisted methods. The use of surfactant prevents the collapse of the porous structure during the air-drying stage in the sol-gel process, which is regarded as a critical stage in this method. This work offers an overview on the use of surfactants as templates for the manufacture of tunable porous carbon materials by the sol-gel method mainly using the polymerization reaction of resorcinol (R) and formaldehyde (F). The use of surfactants avoids the application of other economically disadvantaged drying techniques such as supercritical fluids and freeze-drying. The surfactant-assisted sol-gel methods reported in the literature for the fabrication of porous carbons are widely discussed, as well as the potentiality of the synthesized materials as electrodes in electrochemical systems, which greatly depends on the final porous structure. Besides, this work offers information on hybrid methods in which surfactants are used not only for the fabrication of porous carbon materials with mesoporous/microporous structure but also for the development of advanced structures and composites, including nanomaterials with enhanced properties. Finally, future prospects in the synthesis of carbon materials prepared by surfactant-assisted sol-gel method are presented.

A significant amount of oil (i.e. 60–70%) remains trapped in reservoirs after the conventional primary and secondary methods of oil recovery. Enhanced oil recovery (EOR) methods are therefore necessary to recover the major fraction of unrecovered trapped oil from reservoirs to meet the present-day energy demands. The chemical EOR method is one of the promising methods where various chemical additives, such as alkalis, surfactants, polymer, and the combination of all alkali–surfactant–polymer (ASP) or surfactant–polymer (SP) solutions, are injected into the reservoir to improve the displacement and sweep efficiency. Every oil field has different conditions, which imposes new challenges toward alternative but more effective EOR techniques. Among such attractive alternative additives are polymeric surfactants, natural surfactants, nanoparticles, and self-assembled polymer systems for EOR. In this paper, water-soluble chemical additives such as alkalis, surfactants, polymer, and ASP or SP solution for chemical EOR are highlighted. This review also discusses the concepts and techniques related to the chemical methods of EOR, and highlights the rheological properties of the chemicals involved in the efficiency of EOR methods.

In order to meet the stringent environmental and industrial legislation on fuel specifications, sulfur compounds have to be removed efficiently from fuels. The requirement to produce ultralow-sulfur fuels (S < 10 ppm) has stimulated many works in the area of conventional hydro-desulfurization (HDS) method. Oxidative desulfurization (ODS), as an alternative or complementary technology to HDS for deep desulfurization, is conducted with high selectivity and reactivity to sterically hindered S compounds under mild reaction conditions. In the ODS process, using an appropriate oxidant in the presence of a catalyst, organic sulfur compounds can be oxidized selectively to their corresponding sulfoxides and sulfones, which can be easily removed by different separation methods. Having great catalytic characteristics, polyoxometalate materials have been utilized as a vital class of catalysts for deep desulfurization of fuels. In the past few decades, ODS of fuels using polyoxometalate as catalyst has drawn much attention, and various studies have been carried out in this area. Here, we give a critical review for the removal of sulfur compounds from liquid fuels (mostly from diesel and model fuels) by ODS via homogeneous and heterogeneous polyoxometalate catalysts.

Many studies have examined metallic nanoparticles (NPs) produced according to the principles of green chemistry. Gold NPs have drawn much more attention than other metallic NPs in recent years. Moreover, among all gold NP synthesis studies, using plant-derived molecules is one of the commonly used reductants in studies on NP synthesis because of its convenience in terms of shape, size control advantage, and nontoxic specifications. The present review focused on studies of the synthesis of gold NP types, including single gold atom NPs, alloyed AU NPs, and core-shell Au NPs as well as their conditions and applications. The effect of those structures on application fields such as catalysis, antifungal action, antibacterial activities, sensors and so on are also summarized. Furthermore, the morphology and synthesis conditions of the primer and secondary NP were discussed. In addition to synthesis methods, characterization methods were analyzed in the context of the considerable diversity of the reducing agents used. As the reducing agents used in most studies, polyphenols and proteins usually play an active role. Finally, the challenges and drawbacks in plant-derived agent usage for the preparation of Au NPs at various industries were also discussed.