Volume 94, Issue 11-12

Direct deoxygenative borylation is a highly enabling chemical transformation considering the attractive synthetic features of oxygenous feedstocks and organoboron compounds. Despite ranking among the synthetic ideality in different settings, such chemical space remained largely uncharted and underutilized until recent decades. This short review will summarize some key advances in the field of direct deoxy-borylation of alcohols, ethers, aldehydes, ketones, and carboxylic acids and organize these contributions based on substrate classes. In each representative, the general features, including reaction conditions, product scopes and mechanistic insights, will be highlighted and discussed.

This article is the second of three projected IUPAC Technical Reports on reference materials for phase equilibrium studies. The goal of this project was to select reference systems with critically evaluated property values for the verification of instruments and techniques used in phase equilibrium studies of mixtures. This report proposes seven systems for solid–liquid equilibrium studies, covering the four most common categories of binary mixtures: aqueous systems with organic solutes, aqueous systems with inorganic solutes, non-aqueous systems, and systems with low solubility. For each system, the available literature sources, accepted data, smoothing equations, and estimated uncertainties are given.

Stable hydrogen, carbon, nitrogen, oxygen and sulfur (HCNOS) isotope compositions expressed as isotope-delta values are typically reported relative to international standards such as Vienna Standard Mean Ocean Water (VSMOW), Vienna Peedee belemnite (VPDB) or Vienna Cañon Diablo Troilite (VCDT). These international standards are chosen by convention and the calibration methods used to realise them in practice undergo occasional changes. To ensure longevity and reusability of published data, a comprehensive description of (1) analytical procedure, (2) traceability, (3) data processing, and (4) uncertainty evaluation is required. Following earlier International Union of Pure and Applied Chemistry documents on terminology and notations, this paper proposes minimum requirements for publishing HCNOS stable-isotope delta results. Each of the requirements are presented with illustrative examples.