Band 10, Heft 4

The advent of resonant dielectric nanomaterials has provided a new path for concentrating and manipulating light on the nanoscale. Such high-refractive-index materials support a diverse set of low-loss optical resonances, including Mie resonances, anapole states, and bound states in the continuum. Through these resonances, high-refractive-index materials can be used to engineer the optical near field, both inside and outside the nanostructures, which opens up new opportunities for Raman spectroscopy. In this review, we discuss the impact of high-refractive-index nano-optics on Raman spectroscopy. In particular, we consider the intrinsic Raman enhancement produced by different dielectric resonances and their theoretical description. Using the optical reciprocity theorem, we derive an expression which links the Raman enhancement to the enhancement of the stored electric energy. We also address recent results on surface-enhanced Raman spectroscopy based on high-refractive-index dielectric materials along with applications in stimulated Raman scattering and nanothermometry. Finally, we discuss the potential of Raman spectroscopy as a tool for detecting the optical near-fields produced by dielectric resonances, complementing reflection and transmission measurements.

Ultrafast laser 3D lithography based on non-linear light–matter interactions, widely known as multi-photon lithography (MPL), offers unrivaled precision rapid prototyping and flexible additive manufacturing options. 3D printing equipment based on MPL is already commercially available, yet there is still no comprehensive understanding of factors determining spatial resolution, accuracy, fabrication throughput, repeatability, and standardized metrology methods for the accurate characterization of the produced 3D objects and their functionalities. The photoexcitation mechanisms, spatial-control or photo-modified volumes, and the variety of processable materials are topics actively investigated. The complexity of the research field is underlined by a limited understanding and fragmented knowledge of light-excitation and material response. Research to date has only provided case-specific findings on photoexcitation, chemical modification, and material characterization of the experimental data. In this review, we aim to provide a consistent and comprehensive summary of the existing literature on photopolymerization mechanisms under highly confined spatial and temporal conditions, where, besides the excitation and cross-linking, parameters such as diffusion, temperature accumulation, and the finite amount of monomer molecules start to become of critical importance. Key parameters such as photoexcitation, polymerization kinetics, and the properties of the additively manufactured materials at the nanoscale in 3D are examined, whereas, the perspectives for future research and as well as emerging applications are outlined.

The field of THz spintronics is a novel direction in the research field of nanomagnetism and spintronics that combines magnetism with optical physics and ultrafast photonics. The experimental scheme of the field involves the use of femtosecond laser pulses to trigger ultrafast spin and charge dynamics in thin films composed of ferromagnetic and nonmagnetic thin layers, where the nonmagnetic layer features a strong spin–orbit coupling. The technological and scientific key challenges of THz spintronic emitters are to increase their intensity and to shape the frequency bandwidth. To achieve the control of the source of the radiation, namely the transport of the ultrafast spin current is required. In this review, we address the generation, detection, efficiency and the future perspectives of THz emitters. We present the state-of-the-art of efficient emission in terms of materials, geometrical stack, interface quality and patterning. The impressive so far results hold the promise for new generation of THz physics based on spintronic emitters.

We design and fabricate ultra-broadband achromatic metalenses operating from the visible into the short-wave infrared, 450–1700 nm, with diffraction-limited performance. A hybrid 3D architecture, which combines nanoholes with a phase plate, allows realization in low refractive index materials. As a result, two-photon lithography can be used for prototyping while molding can be used for mass production. Experimentally, a 0.27 numerical aperture (NA) metalens exhibits 60% average focusing efficiency and 6% maximum focal length error over the entire bandwidth. In addition, a 200 μm diameter, 0.04 NA metalens was used to demonstrate achromatic imaging over the same broad spectral range. These results show that 3D metalens architectures yield excellent performance even using low-refractive index materials, and that two-photon lithography can produce metalenses operating at visible wavelengths.

Ring resonator is an essential element in silicon integrated circuit, it is widely used as filter, wavelength multiplexer and switch in single-mode operation regime. As the rapid development of mode division multiplexing (MDM) technique, ring resonator that can process multi-mode signals simultaneously and uniformly is highly desired. However, the severe modal dispersion makes identical transmission for different modes very hard. In this paper, by breaking through the limitation of conventional multi-mode manipulation design with evanescent coupling or mode interference, we propose and demonstrate a multi-mode ring resonator (MMRR) inspired by the free space geometric optics. Arbitrary number of supporting modes can be achieved by simply widening the waveguide width. For proof-of-concept demonstration, an MMRR supporting four modes is fabricated with uniform transmittance. Furthermore, architecture of cascaded four MMRRs are also demonstrated experimentally.

In this study, we report the formation of laser-induced periodic surface nanometric concentric ring structures on silicon surfaces through single-spot irradiation with orthogonally polarized femtosecond laser double-pulse sequences (OP pulses). The period of the ring structures is marginally smaller than the irradiated laser’s wavelength, which indicates that the structures are a type of low-spatial-frequency laser-induced periodic surface structures. Regular nanometric concentric ring structures can be formed when the time delay between two subpulses is approximately 1 ps (roughly from 500 fs to 1.5 ps) and the number of laser bursts is approximately 4. The formation mechanism of the concentric ring structures is attributed to the surface wave (i.e., cylindrical wave) stimulated by OP pulses through single-spot irradiation is radially distributed. Large area of concentric ring structures eliminating anisotropy in the generation of structural colors was shown in this paper.

Nanophotonic engineering of light–matter interaction at subwavelength scale allows thermal radiation that is fundamentally different from that of traditional thermal emitters and provides exciting opportunities for various thermal-photonic applications. We propose a new kind of integrated and electrically controlled thermal emitter that exploits layered metamaterials with lithography-free and dielectric/metallic nanolayers. We demonstrate both theoretically and experimentally that the proposed concept can create a strong photonic bandgap in the visible regime and allow small impedance mismatch at the infrared wavelengths, which gives rise to optical features of significantly enhanced emissivity at the broad infrared wavelengths of 1.4–14 μm as well as effectively suppressed emissivity in the visible region. The electrically driven metamaterial devices are optically and thermally stable at temperatures up to ∼800 K with electro-optical conversion efficiency reaching ∼30%. We believe that the proposed high-efficiency thermal emitters will pave the way toward integrated infrared light source platforms for various thermal-photonic applications and particularly provide a novel alternative for cost-effective, compact, low glare, and energy-efficient infrared heating.

Toroidal dipole (TD) with weak coupling to the electromagnetic fields offers tremendous potential for advanced design of photonic devices. However, the excitation of high quality ( Q ) factor TD resonances in these devices is challenging. Here, we investigate ultrahigh- Q factor TD resonances at terahertz frequencies arising from a distortion of symmetry-protected bound states in the continuum (BIC) in all-dielectric metasurface consisting of an array of high-index tetramer clusters. By elaborately arranging the cylinders forming an asymmetric cluster, two distinct TD resonances governed by BIC are excited and identified. One is distinguished as intracluster TD mode that occurs in the interior of tetramer cluster, and the other one is intercluster TD mode that arises from the two neighboring clusters. Such TD resonances can be turned into ultrahigh- Q leaky resonances by controlling the asymmetry of cluster. The low-loss TD resonances with extremely narrow linewidth are very sensitive to the change in the refractive index of the surrounding media, achieving ultrahigh sensitivity level of 489 GHz/RIU. These findings will open up an avenue to develop ultrasensitive photonic sensor in the terahertz regime.

The new paradigm of parity-time symmetry in quantum mechanics has readily been applied in the field of optics with numerous demonstrations of exotic properties in photonic systems. In this work, we report on the implementation of single frequency electrically injected distributed feedback (DFB) laser diodes based on parity-time symmetric dual gratings in a standard ridge waveguide configuration. We demonstrate enhanced modal discrimination for these devices as compared with index or gain coupled ones, fabricated in the same technology run. Optical transmission probing experiments further show asymmetric amplification in the light propagation confirming the parity-time symmetry signature of unidirectional light behavior. Another asset of these complex coupled devices is further highlighted in terms of robustness to optical feedback.

Spontaneous locking of the phase of a coherent phonon source to an external reference is demonstrated in a deeply sideband-unresolved optomechanical system. The high-amplitude mechanical oscillations are driven by the anharmonic modulation of the radiation pressure force that result from an absorption-mediated free-carrier/temperature limit cycle, i.e., self-pulsing. Synchronization is observed when the pump laser driving the mechanical oscillator to a self-sustained state is modulated by a radiofrequency tone. We employ a pump-probe phonon detection scheme based on an independent optical cavity to observe only the mechanical oscillator dynamics. The lock range of the oscillation frequency, i.e., the Arnold tongue, is experimentally determined over a range of external reference strengths, evidencing the possibility to tune the oscillator frequency for a range up to 350 kHz. The stability of the coherent phonon source is evaluated via its phase noise, with a maximum achieved suppression of 44 dBc/Hz at 1 kHz offset for a 100 MHz mechanical resonator. Introducing a weak modulation in the excitation laser reveals as a further knob to trigger, control and stabilize the dynamical solutions of self-pulsing based optomechanical oscillators, thus enhancing their potential as acoustic wave sources in a single-layer silicon platform.

Optical excitation of metallic nanostructures induces strong intraband transitions, leaving transient depletion below the Fermi level, which allows transient interband transition to this depletion band. This is equivalent to the lowering of the threshold for interband transitions and pushes the plasmonic band to the red. As a result, localized surface plasmon resonance (LSPR) is “extinguished” or “quenched” around the bandedge, in contrast, the interband optical absorption becomes enhanced and redshifted. The corresponding transient absorption (TA) signals have equal lifetimes and opposite signs. Moreover, the TA spectrum is found to be a second-order differential of the steady-state optical extinction spectrum over the studied band. This is a commonly existing mechanism for metallic nanostructures and verified with gold in this work. Such a discovery is completely different from the optical-excitation-induced redshift of LSPR through enhanced electronic scattering and is important for understanding the ultrafast spectroscopic response of plasmonic nanostructures with clear photophysical insights, supplying solid basis for exploring optical logic device and optical data processing techniques.

Cointegration and coupling a perfect metamaterial absorber (PMA) together with a film bulk acoustic wave resonator (FBAR) in a monolithic fashion is introduced for the purpose of producing ultracompact uncooled infrared sensors of high sensitivity. An optimized ultrathin multilayer stack was implemented to realize the proposed device. It is experimentally demonstrated that the resonance frequency of the FBAR can be used efficiently as a sensor output as it downshifts linearly with the intensity of the incident infrared irradiation. The resulting sensor also achieves a high absorption of 88% for an infrared spectrum centered at a wavelength of 8.2 μm. The structure is compact and can be easily integrated on a CMOS-compatible chip since both the FBAR and PMA utilize and share the same stack of metal and dielectric layers.

Metamaterials can achieve superior electromagnetic properties over natural materials by adjusting the structure of the meta-atoms. Chiral metamaterials have been widely used in circular dichroism (CD) spectra, polarization imaging, and optical sensing. Here we propose a kind of all-silicon coding metasurfaces to achieve the function similar to chirality by spin decoupling. One of the two circularly polarized (CP) channels is scattered randomly, and the desired function is only designed in the other opposite CP channel. Three kinds of coding metasurfaces are designed to verify the reliability of such approach: one simultaneously possessing dual function of transmitting directly and scattering randomly, one capable of generating the superposition state of vortex beam, and the other generating the Bessel vortex beam, respectively. And some experimental verifications are carried out. This scheme is simpler and more versatile than previous schemes which require elaborate designed structure of the meta-atoms. Our novel approach provides a new option for implementing tunable chirality.

Parity-Time (PT$\mathcal{P}\mathcal{T}$) symmetry has become an important concept in the design of synthetic optical materials, with exotic functionalities such as unidirectional transport and nonreciprocal reflection. At exceptional points, this symmetry is spontaneously broken, and solutions transition from those with conserved intensity to exponential growth or decay. Here, we analyze a quantum-photonic surface formed by a single layer of atoms in an array with light mediating strong cooperative many-body interactions. We show how delocalized collective excitation eigenmodes can exhibit an effective PT$\mathcal{P}\mathcal{T}$ symmetry and nonexponential decay. This effective symmetry is achieved in a passive system without gain by balancing the scattering of a bright mode with the loss from a subradiant dark mode. These modes coalesce at exceptional points, evidenced by the emergence of coherent perfect absorption where coherent incoming light is perfectly absorbed and scattered only incoherently. We also show how PT$\mathcal{P}\mathcal{T}$ symmetry can be generated in total reflection and by balancing scattering and loss between different polarizations of collective modes.