Abstract
The thermodynamics and kinetics associated with the peri-tectic transition have become greatly discussed topics. A high-temperature confocal scanning laser microscope has been used to observe the growth of γ-austenite along the pro-peritectic δ-ferrite/liquid-Fe boundary and to measure the rate at which this occurs. It was found, for Fe-18 wt.% Co, Fe-19 wt.% Co, and Fe-20 wt.% Co alloys, that the reaction rate increased with increasing undercooling over the temperature range observed and that there was no discernible difference in rate between the three alloys. The growth rate dependence on undercooling was found to be ν = (62.82 ΔT2–70.90 ΔT + 149.04) ± 15.61 μm s–1. This rate compared well with the growth model proposed by Bosze and Trivedi when the uncertainties in available phase diagram information were considered.
References
[1] M. Sumida, W. Kurz: Z. Metallkd. 93 (2002) 1154.10.3139/146.021154Suche in Google Scholar
[2] M. Sumida: J. Alloys and Compounds 349 (2003) 302.10.1016/S0925-8388(02)00900-3Suche in Google Scholar
[3] H. Shibata, Y. Arai, M. Suzuki, T. Emi: Metall. Mater. Trans. B 31 (2000) 981.10.1007/s11663-000-0074-3Suche in Google Scholar
[4] N.J. McDonald, S. Sridhar: Metall. Mater. Trans. A 34 (2003) 1931.10.1007/s11661-003-0158-1Suche in Google Scholar
[5] N.J. McDonald, S. Sridhar, in: Austenite Formation and Decomposition, Minerals Metals and Materials Society, Warrendale (2003) 381.Suche in Google Scholar
[6] H.W. Kerr, W. Kurz: Intern. Mater. Rev. 41 (1996) 129.10.1179/imr.1996.41.4.129Suche in Google Scholar
[7] B. Weisgerber, M. Hecht, K. Harste, H. Morand, M. Kandel, J.-Y. Lamant: Steel Research 73 (2002) 15.10.1002/srin.200200167Suche in Google Scholar
[8] D.H.St. John, L.M. Hogan: J. Mater. Sci. 17 (1982) 2413.10.1007/BF00543752Suche in Google Scholar
[9] H. Fredriksson, T. Nylen: Met. Sci. 16 (1982) 283.10.1179/030634582790427370Suche in Google Scholar
[10] H.W. Kerr, J. Cissé, G.F. Bolling: Acta Metall. 22 (1974) 677.10.1016/0001-6160(74)90077-7Suche in Google Scholar
[11] A.W. Cramb, C. Orrling, Y. Fang, N. Phinichka, S. Sridhar: JOM 51 (1999) 11.Suche in Google Scholar
[12] H. Shibata, T. Emi, M. Suzuki: Mater. Trans. JIM 37 (1996) 620.10.2320/matertrans1989.37.620Suche in Google Scholar
[13] D.A. Porter, K.E. Easterling: Phase Transformations in Metals and Alloys, Chapman and Hall, New York (1992).10.1007/978-1-4899-3051-4Suche in Google Scholar
[14] C. Zener: Trans. AIME 167 (1946) 550.Suche in Google Scholar
[15] M. Hillert: Jernkont. Ann. 141 (1957) 757.Suche in Google Scholar
[16] R. Trivedi: Acta Metall. 18 (1970) 287.10.1016/0001-6160(70)90143-4Suche in Google Scholar
[17] W.P. Bosze, R. Trivedi: Metall. Trans. 5 (1974) 511.10.1007/BF02644122Suche in Google Scholar
[18] W. Kurz, D.J. Fisher: Fundamentals of Solidification, Trans. Tech. Publications, Zurich (1998).10.4028/www.scientific.net/RC.35Suche in Google Scholar
[19] D.E. Temkin: Dokl. Akad. Nauk SSSR 132 (1960) 1607.Suche in Google Scholar
[20] G.R. Kotler, L.A. Tarshis: J. Cryst. Growth 5 (1969) 90.10.1016/0022-0248(69)90019-0Suche in Google Scholar
[21] N.J. McDonald, S. Sridhar: Interface Science (2004) accepted.Suche in Google Scholar
[22] M. Hillert, in: Solidification and Casting of Metals, The Metals Society, London (1979) 81.Suche in Google Scholar
[23] P.G. Boswell, G.A. Chadwick, R. Elliott, F.R. Sale, in: Solidification and Casting of Metals, The Metals Society, London (1979) 175.Suche in Google Scholar
[24] G.B. Harris, W. Hume-Rothery: J. Iron Steel Res. Soc. 174 (1953) 212.Suche in Google Scholar
[25] R. Ruer, R. Klesper: Ferrum 11 (1913 –14) 257.10.1016/S0021-9258(18)88598-2Suche in Google Scholar
[26] T. Nishizawa, K. Ishida: Bull. Alloy Phase Diagrams 5 (1984) 250.10.1007/BF02868548Suche in Google Scholar
[27] M. Hansen (Ed.): Constitution of Binary Alloys, McGraw-Hill, New York (1958) 471.10.1149/1.2428700Suche in Google Scholar
[28] Landolt–Börnstein: Phase Equilibria, Crystallographic and Ther-modynamic Data of Binary Alloys, Group IV, Vol. 5, Sub Vol. C, Springer Verlag, Berlin (1992) 280.Suche in Google Scholar
[29] T. Massalski (Ed.): Binary Alloy Phase Diagrams Vol. 2, ASM International, Materials Park (1990) 1186.Suche in Google Scholar
[30] B. Predel, R. Mohs: Arch. Eisenhüttenwesen. 41 (1970) 143.10.1002/srin.197001581Suche in Google Scholar
[31] D.R. Poirier, G.H. Geiger: Transport Phenomena in Materials Processing, Minerals Metals and Materials Society, Warrendale (1994) 450.Suche in Google Scholar
[32] R. Guthrie: Engineering in Process Metallurgy, Oxford University Press, Oxford (1989) 64.Suche in Google Scholar
© 2005 Carl Hanser Verlag, München
Artikel in diesem Heft
- Frontmatter
- Editorial
- Editorial
- Articles Basic
- Effect of substrate materials in the low-pressure synthesis of diamond: approach by theory of charged clusters
- Effect of gas nitriding in flowing ammonia on the hot-dip galvanising of the Dual-Phase steel DP500
- Nanoscaled multilayers for magnetoelectronics – characterised by analytical TEM
- Obtaining different orientation relationships for Cu films grown on (0001) α-Al2O3 substrates by magnetron sputtering
- Effect of the W–W contiguity on conductivity of W–Cu composite using the Voronoi diagram
- Current understanding of annealing texture evolution in thin films and interconnects
- Articles Applied
- The effect of zirconium on corrosion behavior of NiAl intermetallic compound in molten carbonate salt
- Effects of annealing temperature and time on the microstructural evolution and corresponding mechanical properties of 5083 Al alloy deformed at cryogenic and room temperatures
- Microstructure of MoSi2-base nanocomposite coatings formed on Mo substrates by chemical vapor deposition
- Regular Articles Applied
- In-situ hot pressing/solid-liquid reaction synthesis of bulk Cr2AlC
- Wear of conventional and experimental aluminium bearing alloys sliding under lubrication
- Observations and analysis of the peritectic reaction for Fe–Co Alloys
- Notifications/Mitteilungen
- Personal/Personelles
- News/Aktuelles
- Conferences
Artikel in diesem Heft
- Frontmatter
- Editorial
- Editorial
- Articles Basic
- Effect of substrate materials in the low-pressure synthesis of diamond: approach by theory of charged clusters
- Effect of gas nitriding in flowing ammonia on the hot-dip galvanising of the Dual-Phase steel DP500
- Nanoscaled multilayers for magnetoelectronics – characterised by analytical TEM
- Obtaining different orientation relationships for Cu films grown on (0001) α-Al2O3 substrates by magnetron sputtering
- Effect of the W–W contiguity on conductivity of W–Cu composite using the Voronoi diagram
- Current understanding of annealing texture evolution in thin films and interconnects
- Articles Applied
- The effect of zirconium on corrosion behavior of NiAl intermetallic compound in molten carbonate salt
- Effects of annealing temperature and time on the microstructural evolution and corresponding mechanical properties of 5083 Al alloy deformed at cryogenic and room temperatures
- Microstructure of MoSi2-base nanocomposite coatings formed on Mo substrates by chemical vapor deposition
- Regular Articles Applied
- In-situ hot pressing/solid-liquid reaction synthesis of bulk Cr2AlC
- Wear of conventional and experimental aluminium bearing alloys sliding under lubrication
- Observations and analysis of the peritectic reaction for Fe–Co Alloys
- Notifications/Mitteilungen
- Personal/Personelles
- News/Aktuelles
- Conferences