Zum Hauptinhalt springen
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Phase formation, thermal stability and crystallization behavior of Cu47Ti33Zr11Ni8X1 (X = Fe, Si, Sn, Pb) bulk glassy alloys

  • , , , und EMAIL logo
Veröffentlicht/Copyright: 26. Januar 2022
Veröffentlichen auch Sie bei De Gruyter Brill
Manuskript einreichen Informationen für Autor*innen
International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 95 Heft 11

Abstract

Cu47Ti33Zr11Ni8X1 (X = Fe, Si, Sn, Pb) glass-forming alloys are investigated concerning their phase formation, as-cast microstructure, thermal stability and crystallization behavior. The supercooled liquid region ΔTx has a maximum value of 57 K for Cu47Ti33Zr11Ni8Si1, which is thermally more stable than the other alloys. The reduced glass transition temperature Trg reaches the highest values for the Cu47Ti33Zr11Ni8Si1 and Cu47Ti33Zr11Ni8Fe1 glassy alloys. X-ray diffraction experiments using synchrotron radiation reveal that the first phase formed upon crystallization of fully glassy material has a γ-CuTi-type structure. The final microstructure stable before melting contains a mixture of CuTi, Cu51Zr14, Ti2Cu and Cu2TiZr intermetallic compounds.

Abstract

Glasbildende Cu47Ti33Zr11Ni8X1 (X = Fe, Si, Sn, Pb) Legierungen wurden hinsichtlich der Phasenbildung, der sich ausbildenden Mikrostruktur, der thermischen Stabilität und ihres Kristallisationsverhaltens untersucht. Die Ausdehnung des Bereichs der unterkühlten Schmelze vor der Kristallisation ΔTx erreicht einen Maximalwert von 57 K für Cu47Ti33Zr11Ni8Si1. Dieses Glas besitzt eine höhere thermische Stabilität als die anderen Legierungen. Die reduzierte Glasübergangstemperatur Trg ist für die Cu47Ti33Zr11Ni8Si1 und Cu47Ti33Zr11Ni8Fe1 Gläser am höchsten. Röntgenbeugungsexperimente mittels Synchrotronstrahlung zeigen, dass die in der ersten Kristallisationsstufe ursprünglich vollständig amorpher Proben primär gebildete Phase eine γ-CuTi-Typ Struktur besitzt. Die vor dem Schmelzen stabile Mikrostuktur besteht aus einer Mischung von CuTi, Cu51Zr14, Ti2Cu and Cu2TiZr intermetallischen Phasen.

Keywords: Bulk metallic glasses; Casting; Phase formation; Crystallization; Synchrotron radiation
Prof. Dr. L. Schultz IFW Dresden, Institut für Metallische Werkstoffe P. O. Box 27 00 16, D-01171 Dresden, Germany Tel.: +49 351 4659 460 Fax: +49 351 4659 541

  1. The authors thank B. Bartusch, M. Frey, M. Gründlich, A. Güth, G. Heunen, K. Khlopkov, S. Kuszinski, E. Mohn, and R. Pietzsch for technical assistance. Stimulating discussions with M. D. Baró, A. Concustell, and Å. Kvick are gratefully acknowledged. This work was supported by the Alexander-von-Humboldt Foundation and by the EU within the framework of the RTN-networks on bulk metallic glasses (HPRN-CT-2000-00033) and ductile BMG composites (MRTN-CT-2003-504692).

References

[1] A. Inoue, T. Zhang, T. Masumoto: Mater. Trans. JIM 31 (1990) 177.10.2320/matertrans1989.31.177Suche in Google Scholar

[2] A. Peker, W.L. Johnson: Appl. Phys. Lett. 63 (1993) 2342.10.1063/1.110520Suche in Google Scholar

[3] R. W. Cahn, A. L. Greer: “Metastable state of alloys” in Physical Metallurgy, R.W. Cahn, P. Haasen (Eds.), North-Holland, Vol. 1 (1996) 1723.Suche in Google Scholar

[4] G. He, W. Loeser, J. Eckert, L. Schultz: Mater. Sci. Eng. A 352 (2003) 179.10.1016/S0921-5093(02)00866-3Suche in Google Scholar

[5] J. Das, A. Gueth, H.-J. Klauss, C. Mickel, W. Loeser, J. Eckert, S.K. Roy, L. Schultz: Scripta Mater 49 (2003) 1189.10.1016/j.scriptamat.2003.08.015Suche in Google Scholar

[6] Z.G. Sun, W. Loeser, J. Eckert, K.-H. Mueller, L. Schultz: J. Magn. Magn. Mat. 261 (2003) 122.10.1016/S0304-8853(02)01460-9Suche in Google Scholar

[7] N. Mattern, U. Kühn, H. Hermann, H. Ehrenberg, J. Neuefeind, J. Eckert: Acta Mater. 50 (2002) 305.10.1016/S1359-6454(01)00341-XSuche in Google Scholar

[8] J. Saida, A. Inoue: J. Non-Cryst. Solids 312–314 (2002) 502.10.1016/S0022-3093(02)01726-XSuche in Google Scholar

[9] A. Inoue: Bulk Amorphous Alloys, Trans. Tech. Publ. Ltd. (1998).10.1007/s11661-998-0001-9Suche in Google Scholar

[10] J. Schroers, Y. Wu, R. Busch, W.L. Johnson: Acta Mater. 49 (2001) 2773.10.1016/S1359-6454(01)00159-8Suche in Google Scholar

[11] S. Schneider, W.L. Johnson, P. Thiyagarajan: Appl. Phys. Lett. 68 (1996) 493.10.1063/1.116377Suche in Google Scholar

[12] C.J. Gilbert, R.O. Ritchie,W.L. Johnson: Appl. Phys. Lett. 71 (1997) 476.10.1063/1.119610Suche in Google Scholar

[13] A. Leonhard, L.Q. Xing, M. Heilmaier, A. Gebert, J. Eckert, L. Schultz: Nano Structured Materials 10 (1998) 805.10.1016/S0965-9773(98)00117-2Suche in Google Scholar

[14] R. Doglio, S. Spriano, L. Battezzati: Nano Structured Materials 8 (1997) 447.10.1016/S0965-9773(97)00188-8Suche in Google Scholar

[15] G. He, Z.F. Zhang, W. Loeser, J. Eckert, L. Schultz: Acta Mater. 51 (2003) 2383.10.1016/S1359-6454(03)00045-4Suche in Google Scholar

[16] G. He, W. Löser, J. Eckert: Scripta Mater. 50 (2004) 7.10.1016/j.scriptamat.2003.09.049Suche in Google Scholar

[17] M.W. Chen, I. Dutta, T. Zhang, A. Inoue, T. Sakurai: Appl. Phys. Lett. 79 (2001) 42.10.1063/1.1383060Suche in Google Scholar

[18] A. Inoue: Acta Mater. 48 (2000) 279.10.1016/S1359-6454(99)00300-6Suche in Google Scholar

[19] Y.K. Kim, R. Busch, W.L. Johnson, A.J. Rulison, W.K. Rhim, D. Isheim: Appl. Phys. Lett. 65 (1994) 2136.10.1063/1.112768Suche in Google Scholar

[20] R. Busch, A. Masuhr, E. Bakke, W.L. Johnson: Mater. Sci. Forum 269–272 (1998) 547.10.4028/www.scientific.net/MSF.269-272.547Suche in Google Scholar

[21] W.L. Johnson: MRS Bull. 24 (1999) 42.10.1557/S0883769400053252Suche in Google Scholar

[22] X.H. Lin, W.L. Johnson: Appl. Phys. 78 (1995) 6514.10.1063/1.360537Suche in Google Scholar

[23] K. Amiya, N. Nishiyama, A. Inoue, T. Masumoto: Mater. Sci. Eng. 179–180 (1994) 692.10.1016/0921-5093(94)90294-1Suche in Google Scholar

[24] T. Zhang, A. Inoue: Mater. Trans. JIM 40 (1999) 301.10.2320/matertrans1989.40.301Suche in Google Scholar

[25] E.S. Park, H.K. Lim, W.T. Kim, D.H. Kim: J. Non-Cryst. Solids 298 (2002) 15.10.1016/S0022-3093(01)01047-XSuche in Google Scholar

[26] A. Inoue, W. Zhang, T. Zhang, K. Kurosaka: Acta. Mater. 49 (2001) 2645.10.1016/S1359-6454(01)00181-1Suche in Google Scholar

[27] M. Calin, J. Eckert, L. Schultz: Scripta Mater. 48 (2003) 653.10.1016/S1359-6462(02)00560-2Suche in Google Scholar

[28] D. Louzguine, A. Inoue: J. Non-Cryst. Solids 325 (2003) 187.10.1016/S0022-3093(03)00338-7Suche in Google Scholar

[29] A. Concustell, A. Revesz, S. Surinach, L.K. Varga, G. Heunen, M.D. Baró: J. Mater. Res. 19 (2004) 505.10.1557/jmr.2004.19.2.505Suche in Google Scholar

[30] J. Z. Jiang, B. Yang, K. Saksl, H. Franz, N. Pryds: J. Mater. Res. 18 (2003) 895.10.1557/JMR.2003.0123Suche in Google Scholar

[31] S.C. Glade, J.F. Löffler, S. Bossuyt,W.L. Johnson: J. Appl. Phys. 89 (2002) 1573.10.1063/1.1332089Suche in Google Scholar

[32] C. Li, J. Saida, M. Kiminami, A. Inoue: J. Non-Cryst. Solids 261 (2000) 108.10.1016/S0022-3093(99)00661-4Suche in Google Scholar

[33] H. Choi-Yim, R. Busch, W.L. Johnson: J. Appl. Phys. 12 (1998) 7993.10.1063/1.367981Suche in Google Scholar

[34] Q.S. Zhang, H.F. Zhang, Y.F. Deng, B.Z. Ding, Z.Q. Hu: Scripta Mater. 49 (2003) 273.10.1016/S1359-6462(03)00285-9Suche in Google Scholar

[35] F.H. Froes, T.-L. Yan, H.G. Weidinger: “Titanium, Zirconium and Hafnium” in Materials Science and Technology, R.W. Cahn, P. Haasen, E.J. Kramer (Eds.), VCH, Vol. 8 (1996) 399.Suche in Google Scholar

[36] A.R. Yavari, J.L. Uriarte, K. Tousimi, A. Le Moulec, W.J. Botta, A. Inoue, P. Rejmankova, Å. Kvick: Mater. Sci. Forum 307 (1999) 17.10.4028/www.scientific.net/MSF.307.17Suche in Google Scholar

[37] T.B. Massalski, H. Okamoto, P.R. Subramanian, L. Kacprzak: Binary alloy phase diagrams, 2nd ed. William W. Scott, Jr. (1992).Suche in Google Scholar

[38] D. Turnbull: Contemp. Phys. 10 (1969) 473.10.1080/00107516908204405Suche in Google Scholar

[39] P. Villars, A. Prince, H. Okamoto (Eds.): Handbook of Ternary Alloy Phase Diagrams 6 ASM (1995) 7522.Suche in Google Scholar

[40] F. Spaepen, D. Turnbull: Rev. Phys. Chem. 35 (1984) 241.10.1146/annurev.pc.35.100184.001325Suche in Google Scholar

[41] A.J. Drehman, A.L. Greer: Acta Metall. 32 (1984) 32310.1016/0001-6160(84)90105-6Suche in Google Scholar

[42] M. Stoica, J. Degmova, S. Roth, J. Eckert, H. Grahl, L. Schultz, A.R. Yavari, Å. Kvick, G. Heunen: Mater. Trans. JIM 43 (2002) 1966.10.2320/matertrans.43.1966Suche in Google Scholar

[43] O. Botstein, A. Rabinkin: Mater. Sci. Eng. A 188 (1994) 305.10.1016/0921-5093(94)90386-7Suche in Google Scholar

[44] R. Arroyave, T.W. Egar, L. Kaufmann: J. Appl. Comp. 351 (2003) 158.Suche in Google Scholar

[45] D.J. Sordelet, M.J. Kramer, M.F. Besser, E. Rozhkova: J. Non-Cryst. Solids 290 (2001) 163.10.1016/S0022-3093(01)00819-5Suche in Google Scholar

[46] A. Inoue, Y. Shinohara, Y. Yokoyama, T. Masumoto: Mater. Trans. JIM 36 (1995) 1276.10.2320/matertrans1989.36.1276Suche in Google Scholar

[47] A. Gebert, J. Eckert, L. Schultz: Acta Mater. 46 (1998) 5475.10.1016/S1359-6454(98)00187-6Suche in Google Scholar

[48] C.T. Liu, M.F. Chisholm, M.L. Miller: Intermetallics 10 (2002) 1105.10.1016/S0966-9795(02)00131-0Suche in Google Scholar
Received: 2004-08-30
Accepted: 2004-10-05
Published Online: 2022-01-26

© 2004 Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Frontmatter
  2. Articles Basic
  3. Phase formation, thermal stability and crystallization behavior of Cu47Ti33Zr11Ni8X1 (X = Fe, Si, Sn, Pb) bulk glassy alloys
  4. Thermodynamic reassessment of the Al–V system
  5. Experimental investigation of the equilibrium composition of titanium carbonitride and analysis using thermodynamic modelling
  6. A model for 3-D study of rearrangement in liquid phase sintering
  7. Measurement and calculation of surface tension of undercooled liquid Fe-20 wt.% Cu alloy
  8. Phase equilibria in iron-rich Fe–Al–V ternary alloy system
  9. Articles Applied
  10. Evolution of microstructure during creep in gamma Ti–52Al at 1100 K and high applied stresses
  11. Effect of tempering on the chemical and phase composition of MxCy precipitates in low carbon chromium-molybdenum-vanadium steel
  12. Phase changes in superaustenitic steels after long-term annealing
  13. 3D and microstructural analysis of the chip formation during high speed cutting of C45E (AISI 1045)
  14. Elevated temperature friction and wear behavior of SiC-reinforced copper matrix composites
  15. On the microstructure developed in as-cast and homogenized 7010 aluminium alloy containing scandium
  16. Notifications/Mitteilungen
  17. Personal/Personelles
  18. Conferences/Konferenzen
https://doi.org/10.3139/ijmr-2004-0179
Schlagwörter für diesen Artikel
Bulk metallic glasses; Casting; Phase formation; Crystallization; Synchrotron radiation

Artikel in diesem Heft

  1. Frontmatter
  2. Articles Basic
  3. Phase formation, thermal stability and crystallization behavior of Cu47Ti33Zr11Ni8X1 (X = Fe, Si, Sn, Pb) bulk glassy alloys
  4. Thermodynamic reassessment of the Al–V system
  5. Experimental investigation of the equilibrium composition of titanium carbonitride and analysis using thermodynamic modelling
  6. A model for 3-D study of rearrangement in liquid phase sintering
  7. Measurement and calculation of surface tension of undercooled liquid Fe-20 wt.% Cu alloy
  8. Phase equilibria in iron-rich Fe–Al–V ternary alloy system
  9. Articles Applied
  10. Evolution of microstructure during creep in gamma Ti–52Al at 1100 K and high applied stresses
  11. Effect of tempering on the chemical and phase composition of MxCy precipitates in low carbon chromium-molybdenum-vanadium steel
  12. Phase changes in superaustenitic steels after long-term annealing
  13. 3D and microstructural analysis of the chip formation during high speed cutting of C45E (AISI 1045)
  14. Elevated temperature friction and wear behavior of SiC-reinforced copper matrix composites
  15. On the microstructure developed in as-cast and homogenized 7010 aluminium alloy containing scandium
  16. Notifications/Mitteilungen
  17. Personal/Personelles
  18. Conferences/Konferenzen
Heruntergeladen am 22.4.2026 von https://www.degruyterbrill.com/document/doi/10.3139/ijmr-2004-0179/html
Button zum nach oben scrollen