Zum Hauptinhalt springen
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Polysiloxane-derived ceramic foam for the reinforcement of Mg alloy

  • EMAIL logo , , , , und
Veröffentlicht/Copyright: 3. Januar 2022
Veröffentlichen auch Sie bei De Gruyter Brill
Manuskript einreichen Informationen für Autor*innen
International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 93 Heft 8

Abstract

Magnesium/ceramic composites with an interpenetrating microstructure were made by pressure infiltrating an open cellular ceramic preform. The low-density ceramic preform with a porosity of 82% was prepared by foaming a low-viscous polysiloxane/alumina suspension which formed an SiO2/Al2O3 microcomposite ceramic foam after thermal treatment in air at 1200 °C. Foaming was achieved by an in situ blowing process during curing of the polysiloxane precursor at 200 – 300 °C. The open cellular structure was characterized by a mean strut thickness of 130 μm, an average cell diameter of 800 μm and a high pore connectivity. The ceramic preforms were infiltrated with AZ 31 magnesium alloy by squeeze casting at 680 °C applying a maximum pressure of 86 MPa. Interface bonding was achieved by the formation of spinel and cordierite in a reaction layer at the metal/ceramic interface. The dense metal/ceramic composite possesses significantly higher elastic modulus, yield strength and creep resistance than the monolithic alloy at room temperature and 135 °C. The experimental results suggest that filler-loaded preceramic polymers have a high potential for optimization of lightweight metal cast components.

Keywords: Ceramic foam; Squeeze casting; Interpenetrating phase composites
Juergen Zeschky Department of Materials Science, Glass and Ceramics University of Erlangen-Nuernberg Martensstr. 5, D-91058 Erlangen, Germany Tel.: +49 9131 8527561 Fax: +49 9131 8528311

Dedicated to Professor Dr. Haël Mughrabi on the occasion of his 65th birthday

The authors are grateful to B. Kummer and F. Breutinger (General Materials Properties) for experimental assistance. Financial support from the Deutsche Forschungsgemeinschaft (DFG) is gratefully acknowledged.

References

1 Mordike, B.L.; Kainer, K.U. (eds.), Magnesium Alloys and Their Applications, Werkstoff-Informationsgesellschaft, Frankfurt (1998).Suche in Google Scholar

2 Ibrahim, I.A.; Mohamed, E.A.; Lavernia, E.J: J. Mater. Sci. 26 (1991) 1137.10.1007/BF00544448Suche in Google Scholar

3 Lloyd, D.J.: Int. Mater. Rev. 39 (1994) 1.10.1179/imr.1994.39.1.1Suche in Google Scholar

4 Körner, C.; Schäff, W.; Ottmüller, M.; Singer, R.F.: Adv. Eng. Mat. 2 (2000) 327.10.1002/1527-2648(200006)2:6<327::AID-ADEM327>3.0.CO;2-WSuche in Google Scholar

5 Chmelik, F.; Moll, F.; Kiehn, J.; Lukac, P.; Mordike, B.L.; Kainer, K.U.: Adv. Eng. Mat. 2 (2000) 600.10.1002/1527-2648(200009)2:9<600::AID-ADEM600>3.0.CO;2-DSuche in Google Scholar

6 Sklenicka, V.; Svoboda, M.; Pahutova, M.; Kucharova, K.; Lang-don, T.G.: Mat. Sci. Eng. A 319–321 (2001) 741.10.1016/S0921-5093(01)01023-1Suche in Google Scholar

7 Clarke, D.R.: J. Am. Ceram. Soc. 75 (1992) 739.10.1111/j.1151-2916.1992.tb04138.xSuche in Google Scholar

8 Ganesh, V.V.; Tan, P.K.; Gupta, M.: J. Alloys Composites 315 (2001) 203.10.1016/S0925-8388(00)01261-5Suche in Google Scholar

9 Lenke, I.; Richter, G.; Rogowski, D., in: J.G. Heinrich, F. Aldinger (eds.), Ceramic Materials and Components for Engines, Wiley-VCH, Weinheim (2001) 383.10.1002/9783527612765.ch63Suche in Google Scholar

10 Lenke, I.: Ceram. Eng. Sci. Proc. 22 (2001) 87.10.1002/9780470294680.ch10Suche in Google Scholar

11 Peng, H.X.; Fan, Z.; Evans, J.R.G.: Mat. Sci. Techn. 16 (2000) 903.10.1179/026708300101508667Suche in Google Scholar

12 Wegner, L.D.; Gibson, L.J.: Int. J. Mechanical Sci. 42 (2000) 925.10.1016/S0020-7403(99)00025-9Suche in Google Scholar

13 Claussen, N.; Urquhart, A.W., in: R.W. Cahn, M.B. Bever (eds.), Encyclopedia of Materials Science and Engineering, Supplementary Vol. 2, Pergamon Press, Oxford (1990) 1111.Suche in Google Scholar

14 Liu, W.; Köster, U.: Scripta Mater. 35 (1996) 35.10.1016/1359-6462(96)00084-XSuche in Google Scholar

15 Feng, H.J.; Moore, J.J.: Metall. Mater. Trans. B 26 (1995) 265.10.1007/BF02660968Suche in Google Scholar

16 Aghajanian, M.K.; Burke, J.T.; White, D.R.; Nagelberg, A.S.: SAMPE Quart. 20 (1989) 43.Suche in Google Scholar

17 Toy, C.; Scott, W.D.: J. Am. Ceram. Soc. 73 (1990) 97.10.1111/j.1151-2916.1990.tb05097.xSuche in Google Scholar

18 Loehman, R.E.; Ewsuk, K.; Tomsia, P.: J. Am. Ceram. Soc. 79 (1996) 27.10.1111/j.1151-2916.1996.tb07876.xSuche in Google Scholar

19 Prielipp, H.; Knechtel, M.; Claussen, N.; Streiffer, S.K.; Müllejans, H.; Rühle, H.; Rödel, J.: Mat. Sci. Eng. A 197 (1995) 19.10.1016/0921-5093(94)09771-2Suche in Google Scholar

20 Skirl, S.; Krause, R.: J. Am. Ceram. Soc. 84 (2001) 2034.10.1111/j.1151-2916.2001.tb00954.xSuche in Google Scholar

21 Lange, F.F.; Velamakanni, B.V.; Evans, A.G.: J. Am. Ceram. Soc. 73 (1990) 388.10.1111/j.1151-2916.1990.tb06523.xSuche in Google Scholar

22 Beyer, P.; Janssen, R.; Claussen, N: Adv. Eng. Mat. 2 (2000) 734.10.1002/1527-2648(200011)2:11<734::AID-ADEM734>3.0.CO;2-MSuche in Google Scholar

23 Peng, H.X.; Fan, Z.; Evans, J.R.G.: Mat. Sci. Eng. A 303 (2001) 37.10.1016/S0921-5093(00)01879-7Suche in Google Scholar

24 Colombo, P.; Modesti, M.: J. Sol-Gel Sci. Technol. 14 (1999) 103.10.1023/A:1008736100788Suche in Google Scholar

25 Colombo, P.; Modesti, M.: J. Am. Ceram. Soc. 82 (1999) 573.10.1111/j.1151-2916.1999.tb01803.xSuche in Google Scholar

26 Fitzgerald, T.J.; Michaud, V.J.; Mortensen, A.: J. Mat. Sci. 30 (1995) 1037.10.1007/BF01178442Suche in Google Scholar

27 Gambaryan-Roisman, T.; Scheffler, M.; Takahashi, T.; Buhler, P.; Greil, P., in: G. Müller (ed.), Euromat 99, Vol. 12, DGM, Frankfurt (2000) 247.Suche in Google Scholar

28 Colombo, P.; Gambaryan-Roisman, T.; Scheffler, M.; Buhler, P.; Greil, P.:, J. Am. Ceram. Soc. 84 (2001) 2265.10.1111/j.1151-2916.2001.tb01000.xSuche in Google Scholar

29 Hildebrand, T.; Rüegsegger, R.: Comp. Methods Biomech. Eng. 1 (1997) 15.10.1080/01495739708936692Suche in Google Scholar

30 Cordelair, J.; Greil, P.: J. Europ. Ceram. Soc. 20 (2000) 1947.10.1016/S0955-2219(00)00068-6Suche in Google Scholar

31 Gibson, L.J.; Ashby, M.F.: Cellular Solids, Cambridge Univ. Press, Cambridge (1997).10.1017/CBO9781139878326Suche in Google Scholar

32 Kolhe, R.; Hui, C.Y.; Ustundag, E.; Sass, S.L.: Acta Mater. 44 (1996) 279.10.1016/1359-6454(95)00161-3Suche in Google Scholar

33 Jones, R.M.: Mechanics of Composite Materials, McGraw-Hill, New York (1999).Suche in Google Scholar

34 Tuchinski, L.I.: Soviet Powder Metallurgy and Metal Ceramics 22 (1983) 588.10.1007/BF00805660Suche in Google Scholar

35 Renlund, G.M.; Prochazka, S.; Doremus, R.H.: J. Mater. Res. 6 (1991) 2723.10.1557/JMR.1991.2723Suche in Google Scholar

36 Zhang, P.; Agamennone, P.; Blum, W., in: K.U. Kainer (ed.), Magnesium Alloys and Their Applications, Wiley-VCH, Weinheim (2000) 716.Suche in Google Scholar

37 Goto, S.; McLean, M.: Acta Metall. Mater. 39 (1991) 153.10.1016/0956-7151(91)90263-ZSuche in Google Scholar

38 Zhang, P.;Watzinger, B.; Blum, W.: Phys. Stat. Sol. (a) 175 (1999) 481.10.1002/(SICI)1521-396X(199910)175:2<481::AID-PSSA481>3.0.CO;2-JSuche in Google Scholar

39 Regev, M.; Aghion, E.; Rosen, A.; Bamberger, M.: Mat. Sci. Eng. A 252 (1998) 6.10.1016/S0921-5093(98)00668-6Suche in Google Scholar

40 Spigarelli, S.; Cabibbo, M.; Evangelista, E.; Talianker, M.; Ezersky, V.: Mat. Sci. Eng. A 289 (2000) 172.10.1016/S0921-5093(00)00911-4Suche in Google Scholar

41 Hsueh, C.H. ; Evans, A.G.: J. Am. Ceram. Soc. 68 (1985) 241.10.1111/j.1151-2916.1985.tb15316.xSuche in Google Scholar
Received: 2002-02-20
Published Online: 2022-01-03
Published in Print: 2022-01-03

© 2002 Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Frontmatter
  2. Articles/Aufsätze
  3. Peierls barriers, kinks, and flow stress: Recent progress
  4. Positron annihilation spectroscopy – a non-destructive method for lifetime prediction in the field of dynamical material testing
  5. Diffusion bonding of gamma-based titanium aluminides
  6. A nanotheory of the intense slip localization causing metal fatigue
  7. Dislocation and surface structures of copper and very-low-carbon steel at low fatigue amplitudes
  8. Effect of hafnium on the castability of directionally solidified nickel-base superalloys
  9. Polysiloxane-derived ceramic foam for the reinforcement of Mg alloy
  10. Biomechanical behaviour of implant-reinforced subcapital humeral fractures
  11. Thermodynamic modeling of the Ni – In system
  12. Oxidation of metals investigated by in situ surface sensitive X-ray diffraction
  13. Embrittlement of Cu [001] symmetric tilt boundaries induced by Sb segregation
  14. The microstructure of a Mg-10 wt.% Al alloy
  15. Notifications/Mitteilungen
  16. Personal/Personelles
  17. Books/Bücher
  18. Books/DGM
  19. Conferences/Konferenzen
https://doi.org/10.3139/ijmr-2002-0136
Schlagwörter für diesen Artikel
Ceramic foam; Squeeze casting; Interpenetrating phase composites

Artikel in diesem Heft

  1. Frontmatter
  2. Articles/Aufsätze
  3. Peierls barriers, kinks, and flow stress: Recent progress
  4. Positron annihilation spectroscopy – a non-destructive method for lifetime prediction in the field of dynamical material testing
  5. Diffusion bonding of gamma-based titanium aluminides
  6. A nanotheory of the intense slip localization causing metal fatigue
  7. Dislocation and surface structures of copper and very-low-carbon steel at low fatigue amplitudes
  8. Effect of hafnium on the castability of directionally solidified nickel-base superalloys
  9. Polysiloxane-derived ceramic foam for the reinforcement of Mg alloy
  10. Biomechanical behaviour of implant-reinforced subcapital humeral fractures
  11. Thermodynamic modeling of the Ni – In system
  12. Oxidation of metals investigated by in situ surface sensitive X-ray diffraction
  13. Embrittlement of Cu [001] symmetric tilt boundaries induced by Sb segregation
  14. The microstructure of a Mg-10 wt.% Al alloy
  15. Notifications/Mitteilungen
  16. Personal/Personelles
  17. Books/Bücher
  18. Books/DGM
  19. Conferences/Konferenzen
Heruntergeladen am 19.4.2026 von https://www.degruyterbrill.com/document/doi/10.3139/ijmr-2002-0136/html
Button zum nach oben scrollen