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Thermodynamic Properties and Phase Equilibria in the Ca–Sb System

  • Alexander I. Zaitsev , Natalia. E. Shelkova und Boris M. Mogutnov
Veröffentlicht/Copyright: 30. November 2021
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International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 88 Heft 3

Abstract

A Knudsen effusion technique combined with mass-spectrometric analysis of the evaporated species was used to investigate the gaseous phase and to determine the thermodynamic properties of alloys of calcium with antimony in the temperature range from 933 to 1669 K. Concentration of antimony varied from 50.2 to 63.5 mol.%. The thermodynamic properties of the liquid phase were approximated by the association solution model, assuming that four types of associates Ca3Sb2, Ca3Sb, Ca2Sb and CaSb can exist in the melt. The Gibbs energies of formation of compounds from solid components were expressed by the equations:

Δ f G C a 11 S b 10 = − ( 21884442 ± 14595 ) − ( 43.47 ± 12.34 ) T ,  and   Δ f G C a 5 S b 3 = − ( 919276 ± 5110 ) + ( 34.24 ± 4.75 ) T ,   J   mo l − 1

The obtained data were used for the computation of the part of the Ca–Sb phase diagram, corresponding to the composition range studied.

Alexander I. Zaitsev, Natalia E. Shelkova and Boris M. Mogutnov Institute for Physical Metallurgy I.P. Bardin Central Research Institute for Iron and Steel Industry 9/23 2nd Baumanskaya, Moscow 107005, Russia

Literature

1 Niyazova, Z.U.; Vakhobov, A.V.; Juraev, T.D.: Izvest. AN SSSR, Neorg. Mater. 12 (1976) 1293 – 1294.Suche in Google Scholar

2 Brauer, G.; Muller, O.: Angew. Chemie 73 (1961) 169.10.1002/ange.19610730505Suche in Google Scholar

3 Klebanov, E.B.; Shibalovskaya, I.I.; Morachevskiy, A.G.; Stepanova, T.I.: Izvest. VUZov, Tsvetnaya Metallurgiya 4 (1988) 20 – 23.Suche in Google Scholar

4 Deller, K.; Eisenmann, B.: Z. anorg. allg. Chem. 425 (1976) 104 – 108.10.1002/zaac.19764250203Suche in Google Scholar

5 Deller, K.; Eisenmann, B.: Z. Naturforsch. 31b (1976) 29 – 34.10.1515/znb-1976-0105Suche in Google Scholar

6 Martinez-Ripoll, M.; Brauer, G.: Acta Cryst. 30B (1974) 1083 – 1987.10.1107/S0567740874004304Suche in Google Scholar

7 Bruzzone, G.; Franceschi, E.; Merlo, F.: J. Less-Common Metals 60 (1978) 59.10.1016/0022-5088(78)90089-9Suche in Google Scholar

8 Hurng, W.M.; Corbett, J.D.: Chemistry of Materials 1 (1989) 311 – 319.10.1021/cm00003a008Suche in Google Scholar

9 Kubaschewski, O.: Z. Elektrochem. 45 (1939) 732.Suche in Google Scholar

10 Barin, J.; Knacke, O.: Thermochemical Properties of Inorganic Substances, Springer-Verlag, Berlin (1993).Suche in Google Scholar

11 Shchukarev, S.A.; Morozova, M.P.; Myao-yu, L.: Z. Obshchey Chimii 29 (1959) 3142 – 3144.Suche in Google Scholar

12 Min, D.J.; Sano, N.: Metall. Trans. B 20B (1989) 863 – 870.10.1007/BF02670191Suche in Google Scholar

13 Gurvitch, L.V.: Vestnik AN SSSR 3 (1983) 54 – 56.Suche in Google Scholar

14 Ustinov, A.M.; Kopatch, V.G.; Smirnov, M.P.: Tsvetnaya Metallurgiya 2 (1992) 17 – 19.Suche in Google Scholar

15 Hultgren, R.; Desai, P.D.; Hawkins, D.T., Gleiser, M.; Kelley, K. K.; Wagmann, D. W.: Selected Values of the Thermodynamic Properties of the Elements, ASM, Metals Park, OH (1973) 134 – 141.Suche in Google Scholar

16 Zaitsev, A.I.; Zemchenko, M.A.; Litvina, A.D.; Mogutnov, B.M.: Z. Metallkd. 84 (1993) 178 – 184.Suche in Google Scholar

17 Zaitsev, A.I.; Dobroñhotova, Zh.V.; Litvina, A.D.; Mogutnov, B.M.: J. Chem. Soc., Faraday Trans. 91 (1995) 703 – 712.10.1039/FT9959100703Suche in Google Scholar

18 Zaitsev, A.I.; Korolyov, N.V.; Mogutnov, B.M.: J. Chem. Thermodynamics 23 (1991) 11 – 23.10.1016/S0021-9614(05)80053-9Suche in Google Scholar

19 Zaitsev, A.I.; Korolyov, N.V.; Mogutnov, B.M.: J. Chem. Thermodynamics 24 (1992) 1127 – 1134.10.1016/S0021-9614(05)80235-6Suche in Google Scholar

20 Sidorov, L.N.; Korobov, M.V.; Zhuravleva, L.V.: Mass-spectralniye Thermodyn. Issledovaniya, Moscow State Univ., Moscow (1985).Suche in Google Scholar

21 Zaitsev, A.I.; Zemchenko, M.A.; Mogutnov, B.M.: Zh. Physicheskoy Knimii 64 (1990) 1930 – 1932.Suche in Google Scholar

22 Mann, J.B.: in: T. Ogata, T. Hayakawa (eds.) Proc. Inter. Conf. Mass Spectroscopy, Nov. 1970, Univ. Park Press, Tokyo (1970) 814.Suche in Google Scholar

23 Zaitsev, A.I.; Dobrokhotova, Zh.V.; Litvina, A.D.; Shelkova, N.E.; Mogutnov, B.M.: Inorganic Mater. 32 (1996) 534–541.Suche in Google Scholar

24 Zaitsev, A.I.; Dobrokhotova, Zh.V.; Litvina, A.D.; Elisarova, T.A.; Mogutnov, B.M.: Inorganic Mater. 31 (1995) 1509 – 1519.Suche in Google Scholar
Received: 1996-07-25
Published Online: 2021-11-30

© 1997 Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Frontmatter
  2. Aufsätze
  3. Segregation and Precipitation during Solidification of Titanium and Nitrogen Containing Iron Alloys
  4. Microtexture and Orientation Relations Analysis in Surroundings of Shear Bands in Monocrystalline Copper
  5. Correlation Between Microstructure and Creep Behavior of the High-Temperature Ti Alloy IMI 834
  6. The Influence of Cold Working and Recrystallization on the Homogenization of As-cast Cu-50 wt.% Ni Alloy
  7. Casting of Particulate Al-base Composites
  8. Creep Crack Growth and Fractal Dimension of the Grain-boundary Fracture in Austenitic 21Cr–4Ni–9Mn Steel
  9. The Energy Release Rate of Nonlinear Double Cantilever Beam Specimens
  10. Thermodynamic Properties of Solid Aluminium– Iron Alloys
  11. An Assessment of Thermodynamic Equilibria in the Ag–Al–Cu–Mg Quaternary System in Relation to Precipitation Reactions
  12. Experimental Study of Phase Equilibria in the Fe–Cr –Mn System in the Temperature Range 1073 to 1373 K
  13. Thermodynamic Properties and Phase Equilibria in the Ca–Sb System
  14. Phase Equilibria in the Ti-rich Corner of the Ti –Si –Al System
  15. Mitteilungen der Deutschen Gesellschaft für Materialkunde e.V.
  16. Personen
  17. Fortbildung
  18. Terminkalender
https://doi.org/10.3139/ijmr-1997-0046

Artikel in diesem Heft

  1. Frontmatter
  2. Aufsätze
  3. Segregation and Precipitation during Solidification of Titanium and Nitrogen Containing Iron Alloys
  4. Microtexture and Orientation Relations Analysis in Surroundings of Shear Bands in Monocrystalline Copper
  5. Correlation Between Microstructure and Creep Behavior of the High-Temperature Ti Alloy IMI 834
  6. The Influence of Cold Working and Recrystallization on the Homogenization of As-cast Cu-50 wt.% Ni Alloy
  7. Casting of Particulate Al-base Composites
  8. Creep Crack Growth and Fractal Dimension of the Grain-boundary Fracture in Austenitic 21Cr–4Ni–9Mn Steel
  9. The Energy Release Rate of Nonlinear Double Cantilever Beam Specimens
  10. Thermodynamic Properties of Solid Aluminium– Iron Alloys
  11. An Assessment of Thermodynamic Equilibria in the Ag–Al–Cu–Mg Quaternary System in Relation to Precipitation Reactions
  12. Experimental Study of Phase Equilibria in the Fe–Cr –Mn System in the Temperature Range 1073 to 1373 K
  13. Thermodynamic Properties and Phase Equilibria in the Ca–Sb System
  14. Phase Equilibria in the Ti-rich Corner of the Ti –Si –Al System
  15. Mitteilungen der Deutschen Gesellschaft für Materialkunde e.V.
  16. Personen
  17. Fortbildung
  18. Terminkalender
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