Studies of the Trans-Quinacridone Nucleation of Poly-(ethylene-b-propylene)
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T. Sterzynski
Abstract
The poly-(ethylene-b-propylene) was nucleated for a study of the structure modifications as well as the improvement of the mechanical properties, particularly the impact resistance. The nucleation was accomplished by two various red pigments: a linear trans-quinacridone dye (as ß-phase nucleator) and a dimethyl quinacridone resulting in the formation of a pure a-phase structure. Such procedure allowed the comparison of both the crystal structure and the morphology of the copolymer. For the ß-nucleated copolymer a maximum of the k-value (fraction of ß-phase) was found for a concentration of the nucleating agent of 5 × 10−4 wt.-%. By means of the WAXS measurements (in the transmission and reflection mode) an important structure gradient was detected in the cross-section of the injection moulded samples. This structure gradient was also observed by optical microscopy, where an agreement between optical observation of the spherulites and the k-value distribution on the cross-section of the samples was observed. For both nucleating agents (linear transquinacridone and dimethyl quinacridone) a dependence of the mechanical properties of the copolymer (modulus of elasticity and brittleness by impact resistance) on the pigment concentration was observed. For the ß-phase nucleated copolymer the maximum of the k-value of the hexagonal crystal structure corresponds to the highest ductility by impact test.
© 1997, Carl Hanser Verlag, Munich
Artikel in diesem Heft
- Contents
- Contents
- Editorial
- Editorial
- Screw Extrusion
- Upgrading Recycled HDPE by Rheometer-Controlled Crosslinking
- Blend Morphology of Linear Low Density Polyethylene and Polystyrene in a Non-Intermeshing Twin Screw Extruder
- Mixing
- A Study on the Reactive Compatibilization of a PBT/LCP Blend: Catalyst Effect
- Influence of Processing Temperature on the Morphological and Mechanical Properties of a PC/TLCP Blend
- Fibers
- The Effect of Drawing and Annealing Conditions on the Structure and Properties of Bacterial Poly(3-hydroxybutyrate-co-3 hydroxyvalerate) Fibers
- Numerical Analysis of Cooling Air Systems in Film Blowing
- Moulding
- On the Simulation of Thermoplastic Injection Moulding Process
- Molding
- Rheology of Layered Thermoplastic Matrix Composites during Compression Molding
- Studies of the Trans-Quinacridone Nucleation of Poly-(ethylene-b-propylene)
- The Role of Long Molecules and Nucleating Agents in Shear Induced Crystallization of Isotactic Polypropylenes**
Artikel in diesem Heft
- Contents
- Contents
- Editorial
- Editorial
- Screw Extrusion
- Upgrading Recycled HDPE by Rheometer-Controlled Crosslinking
- Blend Morphology of Linear Low Density Polyethylene and Polystyrene in a Non-Intermeshing Twin Screw Extruder
- Mixing
- A Study on the Reactive Compatibilization of a PBT/LCP Blend: Catalyst Effect
- Influence of Processing Temperature on the Morphological and Mechanical Properties of a PC/TLCP Blend
- Fibers
- The Effect of Drawing and Annealing Conditions on the Structure and Properties of Bacterial Poly(3-hydroxybutyrate-co-3 hydroxyvalerate) Fibers
- Numerical Analysis of Cooling Air Systems in Film Blowing
- Moulding
- On the Simulation of Thermoplastic Injection Moulding Process
- Molding
- Rheology of Layered Thermoplastic Matrix Composites during Compression Molding
- Studies of the Trans-Quinacridone Nucleation of Poly-(ethylene-b-propylene)
- The Role of Long Molecules and Nucleating Agents in Shear Induced Crystallization of Isotactic Polypropylenes**
