The Effects of Recycling and Degradation on Parison Extrusion
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R. W. DiRaddo
Abstract
Finished goods manufactured by the extrusion blow moulding process are strongly dependent on the parison formation stage, since it is the primary step in the process. The magnitude of the die swell and the degree of sag exhibited by the parison, after being extruded from an annular die, are dependent on the material's molecular structure and strongly affect the performance of the final product. Repassing or recycling of polymeric materials results in degradation reactions that modify the molecular structure, and therefore of parison swell and sag. Polyethylene simultaneously undergoes crosslinking and chain scission. Polypropylene undergoes predominately chain scission. The extent of these degradation reactions can be minimized with the use of appropriate stabilizers. This work involves the study of the effects of repassing on the parison formation stage of extrusion blow moulding. The repassing of the same material gives a representation of what occurs when recycling is undertaken. The effect of stabilizer addition is also studied. Particular emphasis is placed on parison swell and sag.
© 1994, Carl Hanser Verlag, Munich
Artikel in diesem Heft
- Contents
- Contents
- Editorial
- Tenth in a Series: Fried. Krupp: Pioneer Integrated Steel and Processing Machinery Manufacturer. Part 1. Essen, Magdeburg and Harburg (1812–1960)
- Internal Mixers
- Finite Element Modelling of Non-isothermal Viscometric Flows in Rubber Mixing
- Screw Extrusion and Mixing
- The Optimisation of Masterbatch Formulations for Use in Single Screw Machines
- Morphological Changes of a Polymer Blend into a Twin-Screw Extruder
- An In-line Melt Rheometer for Molten Plastics
- Selecting Continuous Compounding Equipment Based on Process Considerations
- Reactive Processing
- Peroxide Induced and Thermal Degradation of Polypropylene
- Reactive Blending of Polyamide 6 and Polycarbonate
- Modification of Polypropylene by Maleic Anhydride
- Fibers and Films
- Melt Strength Behaviour of Polypropylenes
- Molding
- Multilayer Injection Moulding
- Miscibility and Mechanical Properties of Poly(ether imide)/Liquid Crystalline Poly(ester imide) Blends
- The Effects of Recycling and Degradation on Parison Extrusion
- Modeling and Simulation of High Reynolds' Number Flows During Reaction Injection Mold Filling
Artikel in diesem Heft
- Contents
- Contents
- Editorial
- Tenth in a Series: Fried. Krupp: Pioneer Integrated Steel and Processing Machinery Manufacturer. Part 1. Essen, Magdeburg and Harburg (1812–1960)
- Internal Mixers
- Finite Element Modelling of Non-isothermal Viscometric Flows in Rubber Mixing
- Screw Extrusion and Mixing
- The Optimisation of Masterbatch Formulations for Use in Single Screw Machines
- Morphological Changes of a Polymer Blend into a Twin-Screw Extruder
- An In-line Melt Rheometer for Molten Plastics
- Selecting Continuous Compounding Equipment Based on Process Considerations
- Reactive Processing
- Peroxide Induced and Thermal Degradation of Polypropylene
- Reactive Blending of Polyamide 6 and Polycarbonate
- Modification of Polypropylene by Maleic Anhydride
- Fibers and Films
- Melt Strength Behaviour of Polypropylenes
- Molding
- Multilayer Injection Moulding
- Miscibility and Mechanical Properties of Poly(ether imide)/Liquid Crystalline Poly(ester imide) Blends
- The Effects of Recycling and Degradation on Parison Extrusion
- Modeling and Simulation of High Reynolds' Number Flows During Reaction Injection Mold Filling
