Structures and Properties of Injection Moldings of Glass Fiber-filled Polypropylenes
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M. Fujiyama
Abstract
Two polypropylene (PP)-glass fiber (GF) compounds were injection-molded. One was a polypropylene filled with 0, 10, 20 and 30 wt.-% of an untreated glass fiber. A second was a compound filled with 20 wt.-% of a silane-treated GF plus 5 wt.-% of a maleic anhydride-grafted PP. Flexural test specimens were injection-molded from the filled PPs at cylinder temperatures of 200 to 320 °C. Properties such as flexural modulus, flexural strength, heat distortion temperature, Izod impact strength, and mold shrinkage as well as higher-order structures such as mean fiber length, crystallinity, ß-crystal content, thickness of skin layer, a*-axis-oriented component fraction, and crystalline orientation fraction were measured and structure-property relationships were studied. A simulation of molecular orientation was carried out from the viewpoint of growth of a melt orientation at the gate and its relaxation in the mold cavity.
© 1993, Carl Hanser Verlag, Munich
Artikel in diesem Heft
- Contents
- Contents
- Mixing
- Processing-Structure-Properties Relationships in Blends with Thermotropic Liquid Crystalline Polymers
- Screw Extrusion
- Extrusion of Recycled Polymer Feedstocks
- A Unified View of Modeling Flow in Counter-rotating Twin Screw Extruders
- Experimental Study on Dewatering and Devolatilizing Operations Using Intermeshed Twin Screw Extruders
- Molding
- Simulation of Injection Molding and Comparison with Experimental Values
- On the Kinetics of Shear Induced Crystallization in Polypropylene
- Structures and Properties of Injection Moldings of Glass Fiber-filled Polypropylenes
- Detailed Investigations of Structural Layering Phenomena in Injection Molded Thermotropic Liquid Crystalline Polymers
- Material Flow During Compression Moldings of Long Fiber Reinforced Thermoplastic Composites
- Rapid Communication of Recent Advances
- Dimensional Control of Multicomponent Extrusion
Artikel in diesem Heft
- Contents
- Contents
- Mixing
- Processing-Structure-Properties Relationships in Blends with Thermotropic Liquid Crystalline Polymers
- Screw Extrusion
- Extrusion of Recycled Polymer Feedstocks
- A Unified View of Modeling Flow in Counter-rotating Twin Screw Extruders
- Experimental Study on Dewatering and Devolatilizing Operations Using Intermeshed Twin Screw Extruders
- Molding
- Simulation of Injection Molding and Comparison with Experimental Values
- On the Kinetics of Shear Induced Crystallization in Polypropylene
- Structures and Properties of Injection Moldings of Glass Fiber-filled Polypropylenes
- Detailed Investigations of Structural Layering Phenomena in Injection Molded Thermotropic Liquid Crystalline Polymers
- Material Flow During Compression Moldings of Long Fiber Reinforced Thermoplastic Composites
- Rapid Communication of Recent Advances
- Dimensional Control of Multicomponent Extrusion
