Synthesis of a Novel Ladder Poly(azomethine-ester) Based on PET Waste Bottles
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        A. M. Issam
        
Abstract
In the present investigation, a novel ladder polymer, poly(azomethine ester), was prepared via solution polycondensation polymerization between terephthalic acid and the novel monomer. Terephthalic acid was regenerated from PET waste bottles by saponification process, whereas p-phenylenediamine was obtained via Hoffmann rearrangement method. A novel monomer, namely N,N′-bis(2,5-dihydroxy benzylidene)-1,4-diaminobenzene was prepared from the reaction of 2,5-di-hydroxybenzadehyde with p-phenylenediamine in the ratio of 2:1, respectively. For the first time a solution polycondensation method has been employed for the synthesis of a ladder polymer which is otherwise prepared commonly via Diels-Alder cycloaddition reaction. The synthesized ladder polymer was characterized by Fourier transform infrared spectroscopy (FT-IR), proton nuclear magnetic resonance spectroscopy (1H NMR), carbon nuclear magnetic resonance spectroscopy (13C NMR), elemental analysis (CHN), X-ray diffraction (XRD), differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The results revealed that the ladder polymer possess highly regular ladder like framework, and that most of the ester groups have taken part in the side-by-side polymerization reaction.
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Artikel in diesem Heft
- Contents
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- Regular Contributed Articles
- Synthesis of a Novel Ladder Poly(azomethine-ester) Based on PET Waste Bottles
- Identifying Melt Processing Conditions for a Polyacrylonitrile Copolymer Plasticized with Water, Acetonitrile and their Mixtures
- Optimization of Injection Stretch Blow Molding: Part I – Defining Part Thickness Profile
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- Micro-Residual Stress Measurement in Nanocomposite Reinforced Polymers
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- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei-Kakou Abstracts
Artikel in diesem Heft
- Contents
- Contents
- Regular Contributed Articles
- Synthesis of a Novel Ladder Poly(azomethine-ester) Based on PET Waste Bottles
- Identifying Melt Processing Conditions for a Polyacrylonitrile Copolymer Plasticized with Water, Acetonitrile and their Mixtures
- Optimization of Injection Stretch Blow Molding: Part I – Defining Part Thickness Profile
- Damping, Thermal and Mechanical Analyses of Polycarbonate/Cerium Oxide Composites for Structural Applications
- On Induced Properties and Self Heating during Free Blowing of PET Preform
- Study of Rheology and Plug Assist Thermoforming of Linear and Branched PP Homopolymer and Impact Copolymer
- Micro-Residual Stress Measurement in Nanocomposite Reinforced Polymers
- Influence of Process Parameters on the Morphologies of Micro-Injection Molded Polyformaldehyde Parts
- Preparation and Characterization of Hydrophobic Flat Sheet Membranes Based on a Recycled Polymer
- PPS News
- PPS News
- Seikei Kakou Abstracts
- Seikei-Kakou Abstracts