Startseite Technik Structural, thermal and optical studies of nanocomposite powder NiSb + Sb produced by mechanical alloying
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Structural, thermal and optical studies of nanocomposite powder NiSb + Sb produced by mechanical alloying

  • Sérgio Michielon de Souza , Gleison Adriano da Silva , Cláudio Natálio Lima , Daniela Menegon Trichês , Cláudio Michel Poffo und João Cardoso de Lima
Veröffentlicht/Copyright: 12. Mai 2015
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International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 106 Heft 5

Abstract

A nanostructured composite powder formed from 75 wt.% NiSb and 25 wt.% Sb was obtained by mechanical alloying binary mixtures of elemental Ni and Sb powders in the composition NiSb2 for 39 hours. The structural evolution was followed by X-ray diffraction measurements and Rietveld structural refinement. At the end of milling, the crystallites of Sb and NiSb reached a mean size of 17 and 15 nm, respectively. Differential scanning calorimetry measurement showed two exothermic processes at 263 °C and 309 °C. Variable temperature powder X-ray diffraction measurements at 25, 100, 200 and 300 °C showed that the sample is structurally stable until 100 °C. The beginning of the transition NiSb + Sb → NiSb2 was observed at 200 °C and the nucleation of Sb2O3 was observed at 300 °C in accordance with differential scanning calorimetry measurement. Raman spectroscopy measurements showed neither NiSb nor NiSb2 compounds produce significant Raman signals when compared with Sb and Sb2O3.

Keywords: Nickel antimonides; Mechanical alloying; Differential scanning calorimetry; X-ray diffraction; Rietveld method
* Correspondence address, Dr. Daniela Menegon Trichês, Department of Physics, Federal University of Amazonas, Av. Gen. Rodrigo Otávio Ramos, 3000, Coroado, Campus Universitário, Setor Norte Manaus, 69077-000 Amazonas, Brazil, Tel: +55 92 98127 8651, Fax: +55 92 3305 2817, E-mail:

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Received: 2014-09-16
Accepted: 2014-12-17
Published Online: 2015-05-12
Published in Print: 2015-05-13

© 2015, Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Thermodynamic description of the Ti–O system
  5. Influence of MgO on the phase equilibria in the CuOx–FeOy–MgO–SiO2 system in equilibrium with copper alloy – Part I: methodology and liquidus in the tridymite primary phase field
  6. Experimental phase diagram of the V–Si–Ho ternary system
  7. Experimental study of the phase relationships in the Al-rich corner of the Al–Si–Fe–Cr quaternary system at 700 °C
  8. Effect of quench–ageing treatment on the microstructure and properties of Zn-15Al-3Cu alloy
  9. Grain growth and thermal stability in nanocrystalline Fe–B alloys prepared by melt spinning
  10. Microatmosphere sintering of Fe-3.2Mn-1.5Si-0.5C steel in flowing technical nitrogen
  11. Structural, thermal and optical studies of nanocomposite powder NiSb + Sb produced by mechanical alloying
  12. Effect of Mo/B atomic ratio on the properties of Mo2NiB2-based cermets
  13. Improving the stoichiometry of RF-sputtered amorphous alumina thin films by thermal annealing
  14. Assessment on the contact factors of a sandwich soft finger model – An experimental investigation
  15. Reducing debinding time in thick components fabricated by powder injection molding
  16. Short Communications
  17. Rapid synthesis of Ag nanoparticles and Ag@SiO2 core–shells
  18. Electrical conductivity of bismuth doped dysprosia stabilized zirconia as an electrolyte material for SOFC
  19. People
  20. Prof. Dr.-Ing. Lorenz Singheiser on the occasion of his 65th birthday
  21. DGM News
  22. DGM News
https://doi.org/10.3139/146.111211
Schlagwörter für diesen Artikel
Nickel antimonides; Mechanical alloying; Differential scanning calorimetry; X-ray diffraction; Rietveld method

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Thermodynamic description of the Ti–O system
  5. Influence of MgO on the phase equilibria in the CuOx–FeOy–MgO–SiO2 system in equilibrium with copper alloy – Part I: methodology and liquidus in the tridymite primary phase field
  6. Experimental phase diagram of the V–Si–Ho ternary system
  7. Experimental study of the phase relationships in the Al-rich corner of the Al–Si–Fe–Cr quaternary system at 700 °C
  8. Effect of quench–ageing treatment on the microstructure and properties of Zn-15Al-3Cu alloy
  9. Grain growth and thermal stability in nanocrystalline Fe–B alloys prepared by melt spinning
  10. Microatmosphere sintering of Fe-3.2Mn-1.5Si-0.5C steel in flowing technical nitrogen
  11. Structural, thermal and optical studies of nanocomposite powder NiSb + Sb produced by mechanical alloying
  12. Effect of Mo/B atomic ratio on the properties of Mo2NiB2-based cermets
  13. Improving the stoichiometry of RF-sputtered amorphous alumina thin films by thermal annealing
  14. Assessment on the contact factors of a sandwich soft finger model – An experimental investigation
  15. Reducing debinding time in thick components fabricated by powder injection molding
  16. Short Communications
  17. Rapid synthesis of Ag nanoparticles and Ag@SiO2 core–shells
  18. Electrical conductivity of bismuth doped dysprosia stabilized zirconia as an electrolyte material for SOFC
  19. People
  20. Prof. Dr.-Ing. Lorenz Singheiser on the occasion of his 65th birthday
  21. DGM News
  22. DGM News
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