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Thermodynamic description of the Ti–O system

  • Milan Hampl und Rainer Schmid-Fetzer
Veröffentlicht/Copyright: 12. Mai 2015
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International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 106 Heft 5

Abstract

Phase diagram and thermodynamic data of the complete binary Ti–O system are assessed using the Calphad method. The main focus is on the proper description of high temperature titanium monoxide TiOx phase using the common compound energy formalism. The structural data of this complex solid solution phase could be successfully modeled together with the phase equilibrium and thermodynamic data, embedded in the comprehensive Ti–O assessment. The presentation of all original phase equilibrium data in the entire system indicates the well or less well established regions in comparison with the calculated phase diagram.

Keywords: Ti–O; Phase diagram; Thermodynamic assessment; Titanium monoxide
* Correspondence address, Prof. Dr.-Ing. Rainer Schmid-Fetzer, Robert-Koch-Str. 42, Institute of Metallurgy, Clausthal University of Technology, D-38678, Clausthal-Zellerfeld, Germany, Tel.: +49 5323-72-2150, Fax: +49 5323-72-3120, E-mail:

References

[1] N.Saunders, L.Chandrasekaran: J. Phase Equil.13 (6) (1992) 612. 10.1007/BF02667209Suche in Google Scholar

[2] M.Pajunen, J.Kivilahti: Z. Metallkd.83 (1) (1992) 17.Suche in Google Scholar

[3] E.Fischer: J. Phase Equil.18 (1997) 338. 10.1007/s11669-997-0060-4Suche in Google Scholar

[4] B.J.Lee, N.Saunders: Z. Metallkd.88 (1997) 152.Suche in Google Scholar

[5] G.Eriksson, A.D.Pelton: Met. Trans. B24 (1994) 795. 10.1007/BF02663140Suche in Google Scholar

[6] P.Waldner, G.Eriksson: Calphad23 (2) (1999) 189. 10.1016/S0364-5916(99)00025-5Suche in Google Scholar

[7] M.Cancarevic, M.Zinkevich, F.Aldinger: Calphad31 (2007) 330. 10.1016/j.calphad.2007.01.009Suche in Google Scholar

[8] C.W.Bale, E.Bélisle, P.Chartrand, S.A.Decterov, G.Eriksson, K.Hack, I.-H.Jung, Y.-B.Kang, J.Melançon, A.D.Pelton, C.Robelin, S.Petersen: Calphad33 (2009) 295. 10.1016/j.calphad.2008.09.009Suche in Google Scholar

[9] W.Cao, S.Chen, F.Zhang, K.Wu, Y.Yang, Y.Chang, R.Schmid-Fetzer, W.A.Oates: Calphad33 (2009) 328. 10.1016/j.calphad.2008.08.004Suche in Google Scholar

[10] J.-O.Andersson, T.Helander, L.Höglund, P.Shi, B.Sundman: Calphad26 (2) (2002) 273. 10.1016/S0364-5916(02)00037-8Suche in Google Scholar

[11] M.Hillert: J. Alloys Compd.320 (2001) 161. 10.1016/S0925-8388(00)01481-XSuche in Google Scholar

[12] J.L.Murray, H.A.Wriedt: Bull. Alloy Phase Diag.8 (2) (1987) 148.10.1007/BF02873201Suche in Google Scholar

[13] E.S.Bumps, H.D.Kessler, M.Hansen: Trans. Am. Soc. Metals45 (1953) 1008.Suche in Google Scholar

[14] R.J.Wasilewski, G.L.Kehl: J. Inst. Met.83 (1954) 94.Suche in Google Scholar

[15] T.H.Schofield, A.E.Bacon: J. Inst. Met.84 (1955) 47.Suche in Google Scholar

[16] H.Nishimura, H.Kimura: J. Jpn. Inst. Met.20 (1956) 524.10.2320/jinstmet1952.20.9_524Suche in Google Scholar

[17] G.Brauer, W.Littke: J. Inorg. Nucl. Chem.16 (1960) 67. 10.1016/0022-1902(60)80089-9Suche in Google Scholar

[18] I.I.Kornilov, V.V.Glazova: Dokl. Akad. Nauk150 (2) (1963) 313.Suche in Google Scholar

[19] P.G.Wahlbeck, P.W.Gilles: J. Am. Ceram. Soc.49 (4) (1966) 180. 10.1111/j.1151-2916.1966.tb13229.xSuche in Google Scholar

[20] A.Jostsons, P.McDougall, in: R.I.Jaffe, N.E.Promisel (Eds.), Proc. Int. Conf. Sci. Technol. Appl., Titanium, London (1968) 745.Suche in Google Scholar

[21] W.O.Groves, M.Hoch, H.L.Johnston: J. Phys. Chem.59 (1955) 127. 10.1021/j150524a008Suche in Google Scholar

[22] S.M.Ariya, M.P.Morozova, E.Volf: Zh. Neorg. Khim.2 (1957) 16.Suche in Google Scholar

[23] A.D.Mah, K.K.Kelley, N.L.Gellert, E.G.King, C.J.O’Brien: Bur. Mines Rep. Invest.5316 (1957) 33.Suche in Google Scholar

[24] P.Kofstad: J. Phys. Chem. Solids23 (1962) 1579. 10.1021/j150524a008Suche in Google Scholar

[25] M.T.Hepworth, R.Schuhmann: Trans. Metall. Soc. AIME224 (1962) 928.Suche in Google Scholar

[26] R.N.Blumenthal, D.H.Whitmore: J. Electrochem. Soc.110 (1) (1963) 92. 10.1149/1.2425682Suche in Google Scholar

[27] K.S.Forland: Acta Chem. Scand.18 (1964) 1267. 10.3891/acta.chem.scand.18-1267Suche in Google Scholar

[28] J.B.Moser, R.N.Blumenthal, D.H.Whitmore: J. Am. Ceram. Soc.48 (1965) 384. 10.1111/j.1151-2916.1965.tb14769.xSuche in Google Scholar

[29] J.S.Anderson, A.S.Khan: J. Less-Common Metals22 (1970) 219. 10.1016/0022-5088(70)90022-6Suche in Google Scholar

[30] M.D.Banus, T.B.Reed, A.J.Strauss: Phys. Rev. B5 (1972) 2775. 10.1103/PhysRevB.5.2775Suche in Google Scholar

[31] R.Roy, W.B.White: J. Cryst. Growth13-14 (1972) 78. 10.1016/0022-3697(83)90088-4Suche in Google Scholar

[32] K.Suzuki, K.Sambongi: Tetsu to Hagane58 (1972) 1579.10.2355/tetsutohagane1955.58.12_1579Suche in Google Scholar

[33] R.R.Merrit, B.G.Hyde: Phil. Trans R. Soc. A, 274 (1973) 627. 10.1098/rsta.1973.0078Suche in Google Scholar

[34] V.A.Reznichenko, F.B.Khalimov: Protsessy Proizvod. Titana Ego Dvuokisi, Ed. N.V. Ageev (1973) 193.Suche in Google Scholar

[35] R.G.Sommer, E.D.Cater: J. Electrochem. Soc.122 (10) (1975) 1391. 10.1149/1.2134024Suche in Google Scholar

[36] G.Boureau, P.Gerdanian: Acta Metall.24 (1976) 717. 10.1016/0001-6160(76)90106-1Suche in Google Scholar

[37] J.F.Baumard, D.Panis, A.M.Anthony: J. Solid State Chem.20 (1977) 43. 10.1016/0022-4596(77)90049-4Suche in Google Scholar

[38] R.I.Sheldon, P.W.Gilles: J. Chem. Phys.66 (8) (1977) 3705. 10.1063/1.434407Suche in Google Scholar

[39] I.A.Vasil'eva, Ya.I.Gerassimov, E. Yu.Kushnir: Dokl. Akad. Nauk SSSR235 (1977) 839.Suche in Google Scholar

[40] R.Tetot, C.Picard, G.Boureau, P.Gerdanian: J. Chem. Phys.69 (1) (1978) 326. 10.1063/1.436356Suche in Google Scholar

[41] R.T.Dirstine, C.J.Rosa: Z. Metallkd.70 (1979) 322.Suche in Google Scholar

[42] S.A.Heideman, T.B.Reed, P.W.Gilles: High Temp. Sci.13 (1980) 79.Suche in Google Scholar

[43] J.M.Juneja, Y.J.Bhatt, S.P.Garg: J. Less-Common Met.69 (1980) 313. 10.1016/0022-5088(80)90288-XSuche in Google Scholar

[44] S.Banon, C.Chatillon, M.Allibert: High Temp. Sci.15 (1982) 105.Suche in Google Scholar

[45] G.Chattopadhyay, H.Kleykamp: Z. Metallkd.74 (3) (1983) 182.Suche in Google Scholar

[46] R.Tetot, C.Picard, P.Gerdanian: J. Phys. Chem. Solids44 (11) (1983) 1059. 10.1016/0022-3697(83)90088-4Suche in Google Scholar

[47] S.Zador, C.B.Alcock: High Temp. Sci.16 (1983) 187.Suche in Google Scholar

[48] J.F.Marucco, B.Poumellec, J.Gautron, P.Lemasson: J. Phys. Chem. Solids46 (1985) 709. 10.1016/0022-3697(85)90160-XSuche in Google Scholar

[49] K.T.Jacob, S.M.Hoque, Y.Waseda: Mater. Trans., JIM41 (6) (2000) 681. 10.2320/matertrans1989.41.681Suche in Google Scholar

[50] A.T.Dinsdale: Calphad15 (1991) 317. 10.1016/0364-5916(91)90030-NSuche in Google Scholar

[51] M.Hillert, M.Jarl: Acta Metall.25 (1) (1977) 1. 10.1016/0001-6160(77)90239-5Suche in Google Scholar

[52] F.Sommer: Z. Metallkd.73 (1982) 72.10.1515/ijmr-1982-730202Suche in Google Scholar

[53] M.E.Straumanis, H.W.Li: Z. Anorg. Allg. Chem.305 (1960) 143. 10.1002/zaac.19603050305Suche in Google Scholar

[54] A.Afir, M.Achour, N.Saoula: J. Alloys Compd.288 (1999) 124. 10.1016/S0925-8388(99)00112-7Suche in Google Scholar

[55] M.Binnewies, E.Milke: Thermochemical Data of Elements and Compounds, 2nd Ed., Viley-VCH, Weinheim (2002). 10.1002/9783527618347Suche in Google Scholar

[56] T.B.Massalski (Ed.): Binary Alloy Phase Diagram, 2nd Ed., ASM International, Metals Park, Ohio (1990).Suche in Google Scholar

[57] S.Andersson: Acta Chem. Scand.13 (1959) 415. 10.3891/acta.chem.scand.13-0415Suche in Google Scholar

[58] E.Hilti, F.Laves: Naturwissenschaften55 (3) (1968) 131. 10.1007/BF00624245Suche in Google Scholar

[59] L.A.Bursill, B.G.Hyde: Acta Crystallogr. B27 (1971) 210. 10.1107/S0567740871001912Suche in Google Scholar

[60] J.H.Binks, J.A.Duffy: J. Solid State Chem.87 (1990) 195. 10.1016/0022-4596(90)90082-9Suche in Google Scholar

[61] O.Kubaschewski, O.Kubaschewski-von Goldbeck, P.Rogl, H.F.Franzen, in: K.L.Komarek (Ed.) Atomic Energy Review, Special Issue No. 9, Vienna (1983).Suche in Google Scholar

[62] W.A.Oates, S.-L.Chen, W.Cao, F.Zhang, Y.A.Chang, L.Bencze, E.Doernberg, R.Schmid-Fetzer: Acta Mater.56 (2008) 5255. 10.1016/j.actamat.2008.07.002Suche in Google Scholar

Received: 2014-10-23
Accepted: 2014-12-17
Published Online: 2015-05-12
Published in Print: 2015-05-13

© 2015, Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Thermodynamic description of the Ti–O system
  5. Influence of MgO on the phase equilibria in the CuOx–FeOy–MgO–SiO2 system in equilibrium with copper alloy – Part I: methodology and liquidus in the tridymite primary phase field
  6. Experimental phase diagram of the V–Si–Ho ternary system
  7. Experimental study of the phase relationships in the Al-rich corner of the Al–Si–Fe–Cr quaternary system at 700 °C
  8. Effect of quench–ageing treatment on the microstructure and properties of Zn-15Al-3Cu alloy
  9. Grain growth and thermal stability in nanocrystalline Fe–B alloys prepared by melt spinning
  10. Microatmosphere sintering of Fe-3.2Mn-1.5Si-0.5C steel in flowing technical nitrogen
  11. Structural, thermal and optical studies of nanocomposite powder NiSb + Sb produced by mechanical alloying
  12. Effect of Mo/B atomic ratio on the properties of Mo2NiB2-based cermets
  13. Improving the stoichiometry of RF-sputtered amorphous alumina thin films by thermal annealing
  14. Assessment on the contact factors of a sandwich soft finger model – An experimental investigation
  15. Reducing debinding time in thick components fabricated by powder injection molding
  16. Short Communications
  17. Rapid synthesis of Ag nanoparticles and Ag@SiO2 core–shells
  18. Electrical conductivity of bismuth doped dysprosia stabilized zirconia as an electrolyte material for SOFC
  19. People
  20. Prof. Dr.-Ing. Lorenz Singheiser on the occasion of his 65th birthday
  21. DGM News
  22. DGM News
https://doi.org/10.3139/146.111210
Schlagwörter für diesen Artikel
Ti–O; Phase diagram; Thermodynamic assessment; Titanium monoxide

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Original Contributions
  4. Thermodynamic description of the Ti–O system
  5. Influence of MgO on the phase equilibria in the CuOx–FeOy–MgO–SiO2 system in equilibrium with copper alloy – Part I: methodology and liquidus in the tridymite primary phase field
  6. Experimental phase diagram of the V–Si–Ho ternary system
  7. Experimental study of the phase relationships in the Al-rich corner of the Al–Si–Fe–Cr quaternary system at 700 °C
  8. Effect of quench–ageing treatment on the microstructure and properties of Zn-15Al-3Cu alloy
  9. Grain growth and thermal stability in nanocrystalline Fe–B alloys prepared by melt spinning
  10. Microatmosphere sintering of Fe-3.2Mn-1.5Si-0.5C steel in flowing technical nitrogen
  11. Structural, thermal and optical studies of nanocomposite powder NiSb + Sb produced by mechanical alloying
  12. Effect of Mo/B atomic ratio on the properties of Mo2NiB2-based cermets
  13. Improving the stoichiometry of RF-sputtered amorphous alumina thin films by thermal annealing
  14. Assessment on the contact factors of a sandwich soft finger model – An experimental investigation
  15. Reducing debinding time in thick components fabricated by powder injection molding
  16. Short Communications
  17. Rapid synthesis of Ag nanoparticles and Ag@SiO2 core–shells
  18. Electrical conductivity of bismuth doped dysprosia stabilized zirconia as an electrolyte material for SOFC
  19. People
  20. Prof. Dr.-Ing. Lorenz Singheiser on the occasion of his 65th birthday
  21. DGM News
  22. DGM News
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