Thermal investigation of alumina-based pastes and refractory mixturesd
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Ioanna D. Katsavou
Abstract
Alumina-based refractories are the most commonly used materials for lining electrical furnaces. Bauxite and aluminate chamotte were selected, bound with aluminate cement, and their thermal stability was studied using differential scanning calorimetry and thermogravimetry. Their loss on ignition, after firing at 1000 °C, was determined. The main changes in mass observed were attributed to the removal of moisture at temperatures up to 140 °C and to the dehydration of calcium aluminate cement at 200–300 °C. Boehmite (500 °C) and bayerite transformations (650–700 °C) were recorded for bauxite samples, while chamotte samples exhibited changes due to goethite conversion to hematite (400 °C) and spinel formation at 900 °C. Water removal was then examined in detail through differential scanning calorimetry tests. Experiments for loss on ignition showed that particle size of refractory bauxite does not affect mass changes during firing, while chamotte samples were found to show greater loss at particle sizes 200–315 μm, due to impurities and low melting point compounds.
References
[1] J.Poirier, in:Ph.Boch, J.C.Niepce (Eds.), Ceramic Materials: Processes, Properties and Applications, ISTE Ltd, USA (2007) 592Suche in Google Scholar
[2] J.M.R.Mercury, A.A.Cabral, A.E.M.Paiva, R.S.Angelica, R.F.Neves, T.Scheller: J. Thermal Anal. Calorim. 104 (2011) 635–643. 10.1007/s10973-010-1039-7Suche in Google Scholar
[3] I.Valeton: Bauxites: Development in soil science 1, Elsevier Publishing Company, Amsterdam (1972)Suche in Google Scholar
[4] R.Artir, V.Gunay, B.Bekisoglu: Key Eng. Mat. 264–268 (2004) 1807–1810. 10.4028/www.scientific.net/KEM.264-268.1807Suche in Google Scholar
[5] A.Capoglu, P.F.Messer: J. Eur. Ceram. Soc. 24 (2004) 2067–2072. 10.1016/S0955-2219(03)00359-5Suche in Google Scholar
[6] V.A.Ustichenko, G.I.Krut'ko, A.A.Mukhin, G.E.Karas, Z.M.Elisova: Refract. Ind. Ceram. 27 (1986) 107–110.10.1007/BF01398302Suche in Google Scholar
[7] I.D.Katsavou, M.K.Krokida, I.C.Ziomas: Mater. Res. Innov. 15 (2011) 47–52. 10.1179/143307511X12922272563824Suche in Google Scholar
[8] I.D.Katsavou, M.K.Krokida, I.C.Ziomas: Ceram. Int. 38 (2012) 5747–5756. 10.1016/j.ceramint.2012.04.021Suche in Google Scholar
[9] W.N.d.Santos: J. Eur. Ceram. Soc. 23 (2003) 745–755. 10.1016/S0955-2219(02)00158-9Suche in Google Scholar
[10] I.D.Katsavou, M.Krokida, I.Ziomas: Int. J. Mater. Res. 102 (2011) 1303–1311. 10.3139/146.110583Suche in Google Scholar
[11] L.K.Suk-Joong: Sintering, Elsevier, Oxford (2005)Suche in Google Scholar
[12] F.R.Feret, D.Roy: Spectrochim. Acta B. 57 (2002) 551–559. 10.1016/S0584-8547(01)00408-6Suche in Google Scholar
[13] M.Al-Amaireh: J. Appl. Sci. 6 (2006) 2605–2610. 10.3923/jas.2006.2605.2610Suche in Google Scholar
[14] C. L. RoyHagen, BjørnMyhre, HongPeng, in ALAFAR (Eds.), UNITECR'09, Curran Associates Inc, Salvador de Bahia, Brazil (2009).Suche in Google Scholar
[15] V.F.Saltykov: Lithol. Miner. Resour. 44 (2009) 339–347. 10.1134/S0024490209040038Suche in Google Scholar
[16] E.Balomenos, I.Gianopoulou, D.Panias, I.Paspaliaris, K.Perry, D.Boufounos, in: Proceedings - European Metallurgical Conference, EMC 2011, (2011) 745–758Suche in Google Scholar
[17] D.D.Dimas, I.P.Giannopoulou, D.Panias: Miner Process. Extr. M. 30 (2009) 211–239. 10.1080/08827500802498199Suche in Google Scholar
[18] K.Wefers, C.Misra: Oxides and Hydroxides of Aluminum, Alcoa Laboratories, Pennsylvania (1987)Suche in Google Scholar
[19] J.T.Kloprogge, H.D.Ruan, R.L.Frost: J. Mater. Sci. 37 (2002) 1121–1129. 10.1023/A:1014303119055Suche in Google Scholar
[20] L.Zheng, G.Zhang, D.Qu, F.Liu: Adv. Mater. Res. 291–294 (2011) 1795–1799. 10.4028/www.scientific.net/AMR.291-294.1795Suche in Google Scholar
[21] V.S.Ramachandran, R.M.Paroli, J.J.Beaudoin, A.H.Delgado: Handbook of thermal analysis of construction materials, Noyes Publications, Norwich, New York, U.S.A. (2002)10.1016/B978-081551487-9.50017-7Suche in Google Scholar
[22] R.R.Das: Effect of micron and nano MgAl2O4 spinel addition on the properties of magnesia-carbon refractories, National Institute of Technology, Rourkela (2010)Suche in Google Scholar
[23] M.L.P.Antunes, S.J.Couperthwaite, F.T.Da ConceicaoC.P.C.De Jesus, P.K.Kiyohara, A.C.V.Coelho, R.L.Frost: Ind. Eng. Chem. Res. 51 (2012) 775–779. 10.1021/ie201700kSuche in Google Scholar
[24] K.Traore, T.S.Kabre, P.Blanchart: Ceram. Int. 29 (2003) 377–383. 10.1016/S0272-8842(02)00148-7Suche in Google Scholar
[25] C.Parr, in:S.Kerneos (Eds.), IRE, Rotherham, UK (2008) 1–11Suche in Google Scholar
[26] M.Laskou, G.Margomenou-Leonidopoulou, V.Balek: J. Therm. Anal. Calorim. 84 (2006) 141–146. 10.1007/s10973-005-7126-5Suche in Google Scholar
[27] G.V.Franks, Y.Gan: J. Amer. Ceram. Soc. 90 (2007) 3373–3388. 10.1111/j.1551-2916.2007.02013.xSuche in Google Scholar
[28] E.Lodding, in:R. F.Schwenker, P.D.Gran (Eds.), Thermal Analysis, Academic Press, (1969) 123910.1016/B978-0-12-395734-4.50044-8Suche in Google Scholar
[29] T.Moroz, L.Razvorotneva, T.Grigorieva, M.Mazurov, D.Arkhipenko, V.Prugov: Appl. Clay Sci. 18 (2001) 29–36. 10.1016/S0169-1317(00)00027-2Suche in Google Scholar
[30] S.Maitra, S.Bose, N.Bandyopadhyay, A.Roychoudhury: Ceram. Int. 31 (2005) 371–374. 10.1016/j.ceramint.2004.06.002Suche in Google Scholar
[31] F.Hamer, J.Hamer: The Potter's Dictionary of Materials and Techniques, A&C Black Publishers Ltd, London (2004)Suche in Google Scholar
[32] U.Fotheringham, R.Wurth, C.Russel: Therm. Acta. 522 (2011) 144–150. 10.1016/j.tca.2011.03.023Suche in Google Scholar
[33] Murilo D.M.Innocentini, A.R.F.Pardo, V.C.Pandolfelli, B.A.Menegazzo, L.R.M.Bittencourt, R.P.Rettore: J. Amer. Ceram. Soc. 85 (2002) 1517–1521. 10.1111/j.1151-2916.2002.tb00306.xSuche in Google Scholar
[34] L.Peng, X.Xu, Z.Lv, J.Song, M.He, Q.Wang, L.Yan, Y.Li, Z.Li: J. Therm. Anal. Calorim. 110 (2012) 749–754. 10.1007/s10973-011-1962-2Suche in Google Scholar
[35] Y.Yang, S.Paital, N.Dahotre: J. Mater. Sci. - Mater. Med. 21 (2010) 2511–2521. PMid: 20549311; 10.1007/s10856-010-4000-1Suche in Google Scholar PubMed
[36] I.Ismail, M.Hashim, I.R.Ibrahim, R.Nazlan, F. MohdIdris, S.E.Shafie, M.Manap, G.Bahmanrokh, N.H.Abdullah, W.N. WanRahman: J. Magn. Magn. Mater. 333 (2013) 100–107. 10.1016/j.jmmm.2012.12.047Suche in Google Scholar
[37] D.S.Smith, S.Fayette, S.Grandjean, C.Martin, R.Telle, T.Tonnessen: J. Amer. Ceram. Soc. 86 (2003) 105–111. 10.1111/j.1151-2916.2003.tb03285.xSuche in Google Scholar
[38] B.Zhu, B.Fang, X.Li: Ceram. Int. 36 (2010) 2493–2498. 10.1016/j.ceramint.2010.07.007Suche in Google Scholar
© 2014, Carl Hanser Verlag, München
Artikel in diesem Heft
- Contents
- Contents
- Original Contributions
- Microwave absorbing materials based on polyaniline composites: a review
- Atomic mobilities in fcc Cu–Mn–Ni–Zn alloys and their characterizations of uphill diffusion and zero-flux plane phenomena
- Synthesis and characterization of nanocristalline Fe-40 at.% Si alloy prepared by high energy ball milling
- An investigation of the microstructure and hydrogenation/dehydrogenation properties of ball-milled CeMg12 alloys with Ni powders
- Nanoscratch characterization of indium nitride films
- Role of axial thrust in the formation of microstructure and fracture surface of the weld zone in friction stir welded AA6063 aluminium alloy
- Microstructures and corrosion resistance of three typical superlight Mg–Li alloys
- The effect of magnetron-deposited Al2O3 coating on the corrosion resistance of Ti–Al alloys in a 9 %O2 + 0.2 %HCl + 0.08 %SO2 + N2 atmosphere
- Homogenization of direct chill cast AlSi1MgMn billets
- Effect of rare earth Y addition on two-phase Ni53Mn22Co6Ga19 high-temperature shape memory alloy
- Thermal treatment induced transition from Zn3(OH)2(BDC)2 (MOF-69c) to Zn4O(BDC)3 (MOF-5)
- Thermal investigation of alumina-based pastes and refractory mixturesd
- Short Communications
- One-step magnetic modification of non-magnetic solid materials
- DGM News
- DGM News
Artikel in diesem Heft
- Contents
- Contents
- Original Contributions
- Microwave absorbing materials based on polyaniline composites: a review
- Atomic mobilities in fcc Cu–Mn–Ni–Zn alloys and their characterizations of uphill diffusion and zero-flux plane phenomena
- Synthesis and characterization of nanocristalline Fe-40 at.% Si alloy prepared by high energy ball milling
- An investigation of the microstructure and hydrogenation/dehydrogenation properties of ball-milled CeMg12 alloys with Ni powders
- Nanoscratch characterization of indium nitride films
- Role of axial thrust in the formation of microstructure and fracture surface of the weld zone in friction stir welded AA6063 aluminium alloy
- Microstructures and corrosion resistance of three typical superlight Mg–Li alloys
- The effect of magnetron-deposited Al2O3 coating on the corrosion resistance of Ti–Al alloys in a 9 %O2 + 0.2 %HCl + 0.08 %SO2 + N2 atmosphere
- Homogenization of direct chill cast AlSi1MgMn billets
- Effect of rare earth Y addition on two-phase Ni53Mn22Co6Ga19 high-temperature shape memory alloy
- Thermal treatment induced transition from Zn3(OH)2(BDC)2 (MOF-69c) to Zn4O(BDC)3 (MOF-5)
- Thermal investigation of alumina-based pastes and refractory mixturesd
- Short Communications
- One-step magnetic modification of non-magnetic solid materials
- DGM News
- DGM News
