Zum Hauptinhalt springen
Artikel
Lizenziert
Nicht lizenziert Erfordert eine Authentifizierung

Mullite and mullite-type crystal structures

  • , , und
Veröffentlicht/Copyright: 11. Juni 2013
Veröffentlichen auch Sie bei De Gruyter Brill
Manuskript einreichen Informationen für Autor*innen
International Journal of Materials Research
Aus der Zeitschrift International Journal of Materials Research Band 103 Heft 4

Abstract

Synthetic mullites (Al4+2xSi2–2xO10–x) belong to one of the most important groups of ceramic materials. Their crystal structure consists of chains of edge-sharing AlO6 octahedra interconnected by tetrahedral double chains of TO4 (T = Al, Si) tetrahedra. The occurrence of oxygen vacancies is associated with the formation of triclusters of TO4 groups. The distribution of oxygen vacancies and the distribution of Al and Si on the tetrahedral sites are partially ordered yielding an incommensurately modulated crystal structure with satellite reflections in diffraction patterns. The number of symmetrically independent distribution patterns of oxygen vacancies is given for a 2 × 2 × 2 and a 3 × 3 × 2 superstructure model. Many other compounds have chain structures similar to mullite. These compounds are assigned to subgroups, all derived from a hypothetical tetragonal aristotype structure.

Keywords: Mullite; Crystal structure; Crystal chemistry
* Correspondence address Prof. Dr. Reinhard X. Fischer Fachbereich Geowissenschaften (Kristallographie) Univesität Bremen Klagenfurter Straße 28359 Bremen, Germany Tel.: 04 21 218 65 160 Fax: 04 21 218 65 189 E-mail:

References

[1] H.Schneider, K.Okada, J.A.Pask (Eds.) Mullite and mullite ceramics, John Wiley and Sons (1994).Suche in Google Scholar

[2] H.Schneider, S.Komarneni, (Eds.) Mullite. Wiley-VCH, Weinheim (2005).10.1002/3527607358Suche in Google Scholar

[3] N.L.Bowen, J.W.Greig: J. Amer. Ceram. Soc.7 (1924) 238. 10.1111/j.1151-2916.1924.tb18190.xSuche in Google Scholar

[4] Web of Science. [cited 2011 September 18, 2011]; Available from: http://apps.webofknowledge.com.Suche in Google Scholar

[5] R.X.Fischer, H.Schneider, D.Voll: J. Eur. Ceram. Soc.16 (1996) 109. 10.1016/0955-2219(95)00139-5Suche in Google Scholar

[6] F.J.Klug, S.Prochazka, R.H.Doremus: J. Amer. Ceram. Soc.70 (1987) 750. 10.1111/j.1151-2916.1987.tb04875.xSuche in Google Scholar

[7] R.X.Fischer, H.Schneider, in: H.Schneider, S.Komarneni (Eds.) Mullite, Wiley-VCH, Weinheim (2005) 1.10.1002/3527607358Suche in Google Scholar

[8] M.Fisch, T.Armbruster, D.Rentsch, E.Libowitzky, T.Pettke: J. Sol. St. Chem.184 (2011) 70. 10.1016/j.jssc.2010.10.032Suche in Google Scholar

[9] R.Cong, T.Yang, K.Li, H.Li, L.You, F.Liao, Y.Wang, J.Lin: Acta Crystallogr. B66 (2010) 141. PMid: 20305347; 10.1107/S0108768110000650Suche in Google Scholar PubMed

[10] J.D.C.McConnell, V.Heine: Phys. Rev. B31 (1985) 6140. 10.1103/PhysRevB.31.6140Suche in Google Scholar

[11] R.J.Angel, C.T.Prewitt: Acta Crystallogr. B43 (1987) 116. 10.1107/S0108768187098185Suche in Google Scholar

[12] R.J.Angel, R.K.McMullan, C.T.Prewitt: Amer. Mineral.76 (1991) 332.Suche in Google Scholar

[13] S.Rahmann, S.Freimann, in: H.Schneider, S.Komarneni (Eds.) Mullite, Wiley-VCH, Weinheim (2005) 46.Suche in Google Scholar

[14] C.S.Chen, C.C.Chou, S.W.Chang, R.X.Fischer, H.Schneider: Amer. Mineral.95 (2010) 1617. 10.2138/am.2010.3454Suche in Google Scholar

[15] H.Schneider, T.Rymon-Lipinski: J. Amer. Ceram. Soc.71 (1988) C162.10.1111/j.1151-2916.1988.tb05042.xSuche in Google Scholar

[16] J.Ossaka: Nature191 (1961) 1000. 10.1038/1911000a0Suche in Google Scholar

[17] J.R.Smyth, R.M.Hazen: Amer. Mineral.58 (1973) 588.Suche in Google Scholar

[18] H.Bärnighausen: Comm. math. chem. MATCH9 (1980) 209.Suche in Google Scholar

[19] R.X.Fischer, H.Schneider: Eur. J. Mineral.20 (2008) 917. 10.1127/0935-1221/2008/0020-1831Suche in Google Scholar

[20] W.H.Baur, R.X.Fischer: Zeolite-type crystal structures and their chemistry. Subvolume B in Landolt-Börnstein, Numerical data and functional relationships in science and technology. New Series, Group IV, Microporous and other framework materials with zeolite-type structures, in: W.H.Baur, R.X.Fischer (Eds.) Springer, Berlin (2000).Suche in Google Scholar

[21] M.T.Vaughan, D.J.Weidner: Phys. Chem. Miner.3 (1978) 133. 10.1007/BF00308117Suche in Google Scholar

Received: 2011-12-1
Accepted: 2012-1-22
Published Online: 2013-06-11
Published in Print: 2012-04-01

© 2012, Carl Hanser Verlag, München

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Editorial
  4. Mullite 2011
  5. Original Contributions
  6. Mullite and mullite-type crystal structures
  7. Faradaic current in different mullite materials: single crystal, ceramic and cermets
  8. Metakaolin–nanosilver as biocide mullite precursor
  9. Sintering of mullite–β-eucryptite ceramics with very low thermal expansion
  10. Crystal chemistry and properties of mullite-type Bi2M4O9: An overview
  11. Temperature-dependent 57Fe Mössbauer spectroscopy and local structure of mullite-type Bi2(FexAl1–x)4O9 (0.1≤x≤1) solid solutions
  12. Thermal expansion and elastic properties of mullite-type Bi2Ga4O9 and Bi2Fe4O9 single crystals
  13. Single crystal growth and characterization of mullite-type Bi2Mn4O10
  14. Synthesis and electrical conductivity of mullite-type Bi2Al4O9 and (Bi,Ca)2Al4O9 ceramics
  15. New pressure induced phase transitions in mullite-type Bi2(Fe4–xMnx)O10–δ complex oxides
  16. Morphological characterization of the Al–Ag–Cu ternary eutectic
  17. Bainite: Fragmentation of crystallographically homogeneous domains
  18. Influence of grain size on the dynamic recrystallization behavior of AISI 304 stainless steel during hot deformation
  19. Li–Cr substituted nickel–zinc–copper ferrite powders: structural and magnetic properties
  20. A model to calculate the viscosity of silicate melts
  21. Lattice dynamics analysis of the thermal properties of liquid iron
  22. Evaluation of the mechanical properties of natural asphalt-modified hot mixture
  23. Prediction of the transverse Young's modulus of unidirectional triangle-section carbon fiber reinforced plastics
  24. People
  25. Prof. Dr. Bernd Stritzker – 65th birthday
  26. Professor Dr.-Ing. Rainer Schmid-Fetzer – 65 Years
  27. DGM News
  28. DGM News
https://doi.org/10.3139/146.110713
Schlagwörter für diesen Artikel
Mullite; Crystal structure; Crystal chemistry

Artikel in diesem Heft

  1. Contents
  2. Contents
  3. Editorial
  4. Mullite 2011
  5. Original Contributions
  6. Mullite and mullite-type crystal structures
  7. Faradaic current in different mullite materials: single crystal, ceramic and cermets
  8. Metakaolin–nanosilver as biocide mullite precursor
  9. Sintering of mullite–β-eucryptite ceramics with very low thermal expansion
  10. Crystal chemistry and properties of mullite-type Bi2M4O9: An overview
  11. Temperature-dependent 57Fe Mössbauer spectroscopy and local structure of mullite-type Bi2(FexAl1–x)4O9 (0.1≤x≤1) solid solutions
  12. Thermal expansion and elastic properties of mullite-type Bi2Ga4O9 and Bi2Fe4O9 single crystals
  13. Single crystal growth and characterization of mullite-type Bi2Mn4O10
  14. Synthesis and electrical conductivity of mullite-type Bi2Al4O9 and (Bi,Ca)2Al4O9 ceramics
  15. New pressure induced phase transitions in mullite-type Bi2(Fe4–xMnx)O10–δ complex oxides
  16. Morphological characterization of the Al–Ag–Cu ternary eutectic
  17. Bainite: Fragmentation of crystallographically homogeneous domains
  18. Influence of grain size on the dynamic recrystallization behavior of AISI 304 stainless steel during hot deformation
  19. Li–Cr substituted nickel–zinc–copper ferrite powders: structural and magnetic properties
  20. A model to calculate the viscosity of silicate melts
  21. Lattice dynamics analysis of the thermal properties of liquid iron
  22. Evaluation of the mechanical properties of natural asphalt-modified hot mixture
  23. Prediction of the transverse Young's modulus of unidirectional triangle-section carbon fiber reinforced plastics
  24. People
  25. Prof. Dr. Bernd Stritzker – 65th birthday
  26. Professor Dr.-Ing. Rainer Schmid-Fetzer – 65 Years
  27. DGM News
  28. DGM News
Heruntergeladen am 17.4.2026 von https://www.degruyterbrill.com/document/doi/10.3139/146.110713/html
Button zum nach oben scrollen