Role of microalloying elements in the microstructure of hot rolled steels
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and
Abstract
A comparative study of some of the most important effects of the diverse microalloying elements on austenite and ferrite microstructure of hot rolled microalloyed steels is carried out. The values of different aspects such as pinning and driving forces, size of precipitates, activation energies or diffusion coefficients are discussed. Titanium is the most effective element to control grain growth at high reheating temperatures and a weight Ti/N ratio close to 2 is recommended. Aluminum can help to control grain growth at medium temperatures, but its addition to Ti steels can promote abnormal grain growth. Niobium is the most effective element to inhibit static recrystallization of austenite, due to the adequate precipitation temperature range at deformation temperatures and the strong pinning effect of Nb carbonitrides. Finally, the preferential nucleation of intragranular ferrite on particles such as vanadium carbonitrides enhances the ferrite grain refinement.
References
[1] J.J.Jonas, M.G.Akben: Metals Forum4 (1981) 92.Search in Google Scholar
[2] S.F.Medina, A.Quispe: ISIJ Int.41 (2001) 774. 10.2355/isijinternational.41.774Search in Google Scholar
[3] M.Hillert: Acta Mater.52 (2004) 5289. 10.1016/j.actamat.2004.07.032Search in Google Scholar
[4] S.G.Kim, Y.B.Park: Acta Mater.56 (2008) 3739. 10.1016/j.actamat.2008.04.007Search in Google Scholar
[5] L.Bäcke: ISIJ Int.50 (2010) 239. 10.2355/isijinternational.50.239Search in Google Scholar
[6] S.F.Medina, A.Quispe, M.Gómez: Mater. Sci. Technol.19 (2003) 99. 10.1179/026708303225008662Search in Google Scholar
[7] C.S.Smith: Trans. Metall. Soc. AIME175 (1948) 15.Search in Google Scholar
[8] P.A.Manohar, M.Ferry, T.Chandra: ISIJ Int.38 (1998) 913. 10.2355/isijinternational.38.913Search in Google Scholar
[9] M.Hillert: Acta Metall.13 (1965) 227. 10.1016/0001-6160(65)90200-2Search in Google Scholar
[10] T.Gladman: Proc. R. Soc. London294 (1966) 298. 10.1098/rspa.1966.0208Search in Google Scholar
[11] T.Gladman, F.B.Pickering: J. Iron Steel Inst.205 (1967) 653.Search in Google Scholar
[12] M.F.Ashby, J.Harper, J.Lewis: Trans. Metall. Soc. AIME245 (1969) 413.Search in Google Scholar
[13] V.Randle, B.Ralph: Acta Metall.35 (1986) 891. 10.1016/0001-6160(86)90062-3Search in Google Scholar
[14] T.Gladman: Mater. Sci. Forum94–96 (1992) 113.10.4028/www.scientific.net/MSF.94-96.113Search in Google Scholar
[15] H.Adrian, F.B.Pickering: Mater. Sci. Technol.7 (1991) 1762.Search in Google Scholar
[16] M.Toloui, M.Militzer: Int. J. Mat. Res.101 (2010) 542. 10.3139/146.110308Search in Google Scholar
[17] P.Schaffnit, C.Stallybrass, J.Konrad, A.Kulgemeyer, H.Meuser: Int. J. Mat. Res.101 (2010) 549. 10.3139/146.110309Search in Google Scholar
[18] S. S.Hansen, J.B.Van der Sande, M.Cohen: Metall. Trans. A11 (1980) 387. 10.1007/BF02654563Search in Google Scholar
[19] L.J.Cuddy, in: A.J. DeArdo, G.A. Ratz, P.J. Wray (Eds.), Proc. Int. Conf. Thermomechanical Processing of Microalloyed Austenite, The Metallurgical Society of AIME, Pittsburgh, PA, USA (1982) 129.Search in Google Scholar
[20] H.Réglé: Int. J. Mat. Res.101 (2010) 326. 10.3139/146.110291Search in Google Scholar
[21] D.Helm: Int. J. Mat. Res.101 (2010) 972. 10.3139/146.110369Search in Google Scholar
[22] A.Faessel: Rev. Métall. Cah. Inf. Tech.33 (1976) 875.10.1139/f76-111Search in Google Scholar
[23] H.L.Andrade, M.G.Akben, J.J.Jonas: Metall. Trans. A14 (1983) 1967. 10.1007/BF02662364Search in Google Scholar
[24] M.Gómez, L.Rancel, S.F.Medina: Met. Mater. Int.15 (2009) 689. 10.1007/s12540-009-0689-0Search in Google Scholar
[25] J.S.Perttula, L.P.Karjalainen: Mater. Sci. Technol.14 (1998) 626.Search in Google Scholar
[26] K.Narita: Trans. ISIJ15 (1975) 145.10.2355/isijinternational1966.15.145Search in Google Scholar
[27] E.T.Turkdogan: Iron Steelmaker 1661 (1989).Search in Google Scholar
[28] K.Inoue, I.Ohnuma, H.Ohtani, K.Ishida, T.Nishizawa: ISIJ Int.38 (1998) 991. 10.2355/isijinternational.38.991Search in Google Scholar
[29] F.B.Pickering, in: T.N.Baker (Ed.), Titanium Technology in Microalloyed Steels, The Institute of Materials, London, UK (1997) 10.Search in Google Scholar
[30] S.Shanmugam, N.K.Ramisetti, R.D.K.Misra, J.Hartmann, S.G.Jansto: Mater. Sci. Eng. A478 (2008) 26. 10.1016/j.msea.2007.06.003Search in Google Scholar
[31] K.Banerjee, M.Militzer, M.Perez, X.Wang: Metall. Mater. Trans. A41 (2010) 3161. 10.1007/s11661-010-0376-2Search in Google Scholar
[32] R.Wang, C.I.Garcia, M.Hua, K.Cho, H.Zhang, A.J.DeArdo: ISIJ Int.46 (2006) 1345. 10.2355/isijinternational.46.1345Search in Google Scholar
[33] M.I.Vega, S.F.Medina, A.Quispe, M.Gómez, P.P.Gómez: ISIJ Int.45 (2005) 1878. 10.2355/isijinternational.45.1878Search in Google Scholar
[34] J.I.Chaves, S.F.Medina, M.Gómez, L.Rancel, P.Valles: Mater. Sci. Forum550 (2007) 405. 10.4028/0-87849-434-0.405Search in Google Scholar
[35] I.M.Lifshitz, V.V.Slyozov: J. Phys. Chem. Solids19 (1961) 35. 10.1016/0022-3697(61)90054-3Search in Google Scholar
[36] J.Kunze, C.Mickel, G.Backmann, B.Beyer, M.Reibold, C.Klinkenberg: Steel Res.68 (1997) 441.Search in Google Scholar
[37] S.F.Medina, M.Chapa, P.Valles, A.Quispe, M.I.Vega: ISIJ Int.39 (1999) 930. 10.2355/isijinternational.39.930Search in Google Scholar
[38] T.Gladman: The Physical Metallurgy of Microalloyed Steels, The Institute of Materials, London, UK (1997).Search in Google Scholar
[39] J.-R.Yim, A.-R.Min, Y.-C.Joo: Met. Mater. Int.15 (2009) 113. 10.1007/s12540-009-0113-9Search in Google Scholar
[40] S.F.Medina, M.I.Vega, M.Gómez, P.P.Gómez: ISIJ Int.45 (2005) 1307. 10.2355/isijinternational.45.1307Search in Google Scholar
[41] J.H.Beynon, C.M.Sellars: ISIJ Int.32 (1992) 359. 10.2355/isijinternational.32.359Search in Google Scholar
[42] C.M.Sellars, in: C.M. Sellars, C.J. Davies (Eds.), Proc. Int. Conf. on Hot Working and Forming Processes, The Metal Society, London, UK (1980) 3.Search in Google Scholar
[43] D.Q.Bai, S.Yue, W.P.Sun, J.J.Jonas: Metall. Trans A24 (1993) 2151. 10.1007/BF02648589Search in Google Scholar
[44] M.I.Vega, S.F.Medina, A.Quispe, M.Gómez, P.P.Gómez: Mater. Sci. Eng. A423 (2006) 253. 10.1016/j.msea.2006.02.037Search in Google Scholar
[45] M.Gómez, L.Rancel, P.P.Gómez, J.I.Robla, S.F.Medina: ISIJ Int.50 (2010) 868. 10.2355/isijinternational.50.868Search in Google Scholar
[46] M.Gómez, L.Rancel, B.J.Fernandez, S.F.Medina: Mater. Sci. Eng. A501 (2009) 188. 10.1016/j.msea.2008.09.074Search in Google Scholar
[47] M.J.Balart, C.L.Davis, M.Strangwood: Mater. Sci. Eng. A328 (2002) 48. 10.1016/S0921-5093(01)01679-3.Search in Google Scholar
[48] A.Echeverria, J.M.Rodriguez-Ibabe: Scripta Mater.50 (2004) 307. 10.1016/j.scriptamat.2003.09.003.Search in Google Scholar
[49] H.Bomas, M.Bacher-Hoechst, R.Kienzler, S.Kunow, G.Loewisch, F.Muehleder, R.Schroeder: Fatigue Fract. Eng. Mater. Struct.33 (2010) 126. 10.1111/j.1460-2695.2009.01423.x.Search in Google Scholar
[50] V.Ollilainen, H.Pöntinen, M.Paju: European Patent EP 0265402B1 (1991).Search in Google Scholar
[51] B.Mintz, J.M.Arrowsmith, in: C.M. Sellars, C.J. Davies (Eds.), Proc. Int. Conf. on Hot Working and Forming Processes, The Metal Society, London, UK (1980) 99.Search in Google Scholar
[52] G.D.Funnell, in: C.M. Sellars, C.J. Davies (Eds.), Proc. Int. Conf. on Hot Working and Forming Processes, The Metal Society, London, UK (1980) 104.Search in Google Scholar
[53] J.M.Cabrera, A.Al Omar, J.M.Prado: Z. Metallkd.89 (1998) 47.Search in Google Scholar
[54] S.F.Medina, M.Chapa, M.Gómez, A.Quispe, V.López, B.Fernández: Rev. Metal. Madrid39 (2003) 408. 10.3989/revmetalm.2003.v39.i6.355Search in Google Scholar
[55] M.Gómez, L.Rancel, S.F.Medina: Mater. Sci. Eng. A506 (2009) 165. 10.1016/j.msea.2008.11.049Search in Google Scholar
[56] M.Gómez, L.Rancel, S.F.Medina: Mater. Sci. Forum638–642 (2010) 3388. 10.4028/www.scientific.net/MSF.638-642.3388Search in Google Scholar
[57] H.Oikawa, Tetsu-to-Hagane68 (1982) 1489.10.2355/tetsutohagane1955.68.10_1489Search in Google Scholar
[58] S.Okaguchi, T.Hashimoto: ISIJ Int.32 (1992) 283. 10.2355/isijinternational.32.283Search in Google Scholar
[59] A.Vignes, J.Philebert, J.Badía, J.Lavasseur, in: Proc. 2nd Natl. Conf. Microprobe Analysis, Boston, USA (1967) Paper 20.Search in Google Scholar
[60] J.D.Fast: Interaction of Metals and Gases, Macmillan New York, London, UK (1976) 221.Search in Google Scholar
[61] S.F.Medina, M.Gómez, P.P.Gómez: J. Mater. Sci.45 (2010) 5553. 10.1007/s10853-010-4616-zSearch in Google Scholar
[62] S.F.Medina, A.Quispe, P.Valles, J.L.Ba∼nos: ISIJ Int.39 (1999) 913. 10.2355/isijinternational.39.913Search in Google Scholar
[63] M.Gómez, S.F.Medina, A.Ouispe, P.Valles: ISIJ Int.42 (2002) 423. 10.2355/isijinternational.42.423Search in Google Scholar
[64] M.Gómez, S.F.Medina, G.Caruana: ISIJ Int.43 (2003) 1228. 10.2355/isijinternational.43.1228Search in Google Scholar
[65] M.Gómez, O.Hernanz, S.F.Medina, P.Tarin: Steel Res.73 (2002) 446.Search in Google Scholar
[66] M.Umemoto, A.Hiramatsu, A.Moriya, T.Watanabe, S.Nanba, N.Nakajima, G.Anan, Y.Higo: ISIJ Int.32 (1992) 306. 10.2355/isijinternational.32.306Search in Google Scholar
[67] Q.Yu, Z.Wang, X.Liu, G.Wang: ISIJ Int.44 (2004) 710. 10.2355/isijinternational.44.710Search in Google Scholar
[68] S.F.Medina, M.Gómez, L.Rancel: Scripta Mater.58 (2008) 1110. 10.1016/j.scriptamat.2008.02.004Search in Google Scholar
[69] S.F.Medina, M.Gómez, J.I.Chaves, P.P.Gómez, P.Adeva: Mater. Sci. Forum500–501 (2005) 371. 10.4028/www.scientific.net/mSF.500-501.371Search in Google Scholar
[70] S.F.Medina, L.Rancel, M.Gómez, R.Ishak, M.De Sanctis: ISIJ Int.48 (2008) 1603. 10.2355/isijinternational.48.1603Search in Google Scholar
[71] A.Najafi-Zadeh, S.Yue, J.J.Jonas: ISIJ Int.32 (1992) 213. 10.2355/isijinternational.32.213Search in Google Scholar
[72] L.P.Karjalainen, T.M.Maccagno, J.J.Jonas: ISIJ Int.35 (1995) 1523. 10.2355/isijinternational.35.1523Search in Google Scholar
[73] F.B.Pickering: Physical Metallurgy and the Design of Steels, Science Publishers, London, UK (1978) 66.Search in Google Scholar
[74] A.J.DeArdo, M.J.Hua, K.G.Cho, C.I.Garcia: Mater. Sci. Technol.25 (2009) 1074. 10.1179/174328409X455233Search in Google Scholar
© 2011, Carl Hanser Verlag, München
Articles in the same Issue
- Contents
- Contents
- Editorial
- Laudatio für Frau Prof. Dr.-Ing. Christina Berger
- Review
- Role of microalloying elements in the microstructure of hot rolled steels
- Original Contributions
- Experimental study of phase equilibria in the “SnO2” – CaO – SiO2 system in air
- Thermodynamic modeling of the Cr – S system
- Observation of early melting stages of an Al – Cu alloy in a temperature gradient
- Knudsen effusion mass spectrometric studies of the B2 phase in the Al – Co system
- Microstructure evolution in hypereutectoid graphitic steel
- The effect of thermal treatment on the structural properties of copper-containing sol-gel silica nanocomposites
- Electrospray deposition of thin copper-indium-diselenide films
- Morphology, fibrous composition and tensile properties of drag-silk produced by two species of orb spider
- Magnetic properties of Co0.5Zn0.5Fe2O4 nanopowders prepared by means of the template-assisted hydrothermal method
- Effects of aging and sheet thickness on the room temperature deformation behavior and in-plane anisotropy of cold rolled and solution treated Nimonic C-263 alloy sheet
- Thermal expansion/contraction behavior of AA7050 alloy in the as-cast condition relevant to thermomechanical simulation of residual thermal stresses
- Obtaining high formability of IF-galvanized steel tailor welded blanks by applying optimum CO2 laser welding parameters
- Investigation of the dependence of structural and mechanical properties of cement-bonded bauxite refractories on their process conditions
- The effects of curing medium on the flexural strength and water permeability of cementitious composites containing Fe2O3 nanofillers
- DGM News
- DGM News
Articles in the same Issue
- Contents
- Contents
- Editorial
- Laudatio für Frau Prof. Dr.-Ing. Christina Berger
- Review
- Role of microalloying elements in the microstructure of hot rolled steels
- Original Contributions
- Experimental study of phase equilibria in the “SnO2” – CaO – SiO2 system in air
- Thermodynamic modeling of the Cr – S system
- Observation of early melting stages of an Al – Cu alloy in a temperature gradient
- Knudsen effusion mass spectrometric studies of the B2 phase in the Al – Co system
- Microstructure evolution in hypereutectoid graphitic steel
- The effect of thermal treatment on the structural properties of copper-containing sol-gel silica nanocomposites
- Electrospray deposition of thin copper-indium-diselenide films
- Morphology, fibrous composition and tensile properties of drag-silk produced by two species of orb spider
- Magnetic properties of Co0.5Zn0.5Fe2O4 nanopowders prepared by means of the template-assisted hydrothermal method
- Effects of aging and sheet thickness on the room temperature deformation behavior and in-plane anisotropy of cold rolled and solution treated Nimonic C-263 alloy sheet
- Thermal expansion/contraction behavior of AA7050 alloy in the as-cast condition relevant to thermomechanical simulation of residual thermal stresses
- Obtaining high formability of IF-galvanized steel tailor welded blanks by applying optimum CO2 laser welding parameters
- Investigation of the dependence of structural and mechanical properties of cement-bonded bauxite refractories on their process conditions
- The effects of curing medium on the flexural strength and water permeability of cementitious composites containing Fe2O3 nanofillers
- DGM News
- DGM News